Loading...
Appendix D Part 3Page 100 of 194 Page 101 of 194 Page 102 of 194 Page 103 of 194 Page 104 of 194 Page 105 of 194 Page 106 of 194 Page 107 of 194 Page 108 of 194 Page 109 of 194 Page 110 of 194 Page 111 of 194 Page 112 of 194 Page 113 of 194 Page 114 of 194 Page 115 of 194 Page 116 of 194 Page 117 of 194 Page 118 of 194 Page 119 of 194 Page 120 of 194 Page 121 of 194 Page 122 of 194 Page 123 of 194 Page 124 of 194 Page 125 of 194 Page 126 of 194 Page 127 of 194 Page 128 of 194 Page 129 of 194 Page 130 of 194 Page 131 of 194 Page 132 of 194 Page 133 of 194 Page 134 of 194 Page 135 of 194 Page 136 of 194 Page 137 of 194 Page 138 of 194 Page 139 of 194 Page 140 of 194 Page 141 of 194 Page 142 of 194 Page 143 of 194 Page 144 of 194 Page 145 of 194 Page 146 of 194 Page 147 of 194 Page 148 of 194 Page 149 of 194 Page 150 of 194 Page 151 of 194 Page 152 of 194 Page 153 of 194 Page 154 of 194 Page 155 of 194 Page 156 of 194 Page 157 of 194 Page 158 of 194 Page 159 of 194 Page 160 of 194 Page 161 of 194 Page 162 of 194 Page 163 of 194 Page 164 of 194 Page 165 of 194 Page 166 of 194 Page 167 of 194 Page 168 of 194 Page 169 of 194 Page 170 of 194 Page 171 of 194 Page 172 of 194 Page 173 of 194 Page 174 of 194 Page 175 of 194 Page 176 of 194 Page 177 of 194 Page 178 of 194 Page 179 of 194 Page 180 of 194 Page 181 of 194 Page 182 of 194 Page 183 of 194 Page 184 of 194 Page 185 of 194 Page 186 of 194 Page 187 of 194 Page 188 of 194 Page 189 of 194 Page 190 of 194 Page 191 of 194 Page 192 of 194 Page 193 of 194 Page 194 of 194 ANALYTICAL REPORT Job Number: 200-41113-1 SDG Number: 200-41113-1 Job Description: 900 King Street For: AKRF Inc 440 Park Avenue South 7th Floor New York, NY 10016 Attention: Ms. Elizabeth Matamoros _____________________________________________ Approved for release. Kristine A Dusablon Project Manager II 11/30/2017 10:10 AM Kristine A Dusablon, Project Manager II 30 Community Drive, South Burlington, VT, 05403 (802)660-1990 kris.dusablon@testamericainc.com 11/30/2017 cc:Mr. Timothy McClintock The test results in this report relate only to sample(s) as received by the laboratory. These test results were derived under a quality system that adheres to the requirements of NELAC. Pursuant to NELAC, this report may not be produced in full without written approval from the laboratory TestAmerica Laboratories, Inc. TestAmerica Burlington 30 Community Drive, Suite 11, South Burlington, VT 05403 Tel (802) 660-1990 Fax (802) 660-1919 www.testamericainc.com Page 1 of 478 Table of Contents Cover Title Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1 Data Summaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4 Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4 Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5 Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6 Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9 Default Detection Limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .23 QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .26 QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .33 Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .34 Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .35 Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .36 Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .37 Detection Limit Exceptions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .38 Manual Integration Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .39 Reagent Traceability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .42 COAs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .123 Organic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .135 Air - GC/MS VOA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .135 Method TO15 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .135 Method TO15 QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .136 Method TO15 Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .143 Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .298 Method TO15 ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .298 Method TO15 CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .352 Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .366 Page 2 of 478 Table of Contents Method TO15 Tune Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .366 Method TO15 Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .374 Method TO15 LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .385 Method TO15 Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .392 Method TO15 Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .394 Clean Canister Certification . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .395 Pre-shipment Certification . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .395 LCS Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .397 Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .401 Tune Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .417 IS/RT Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .421 Clean Canister Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .425 ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .439 ICV/CCV Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .459 Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .471 Shipping and Receiving Documents . . . . . . . . . . . . . . . . . . . . . . . . . . .475 Client Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .476 Sample Receipt Checklist . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .478 Page 3 of 478 Page 4 of 478 Page 5 of 478 Page 6 of 478 Page 7 of 478 Page 8 of 478 Page 9 of 478 Page 10 of 478 Page 11 of 478 Page 12 of 478 Page 13 of 478 Page 14 of 478 Page 15 of 478 Page 16 of 478 Page 17 of 478 Page 18 of 478 Page 19 of 478 Page 20 of 478 Page 21 of 478 Page 22 of 478 Page 23 of 478 Page 24 of 478 Page 25 of 478 Page 26 of 478 Page 27 of 478 Page 28 of 478 Page 29 of 478 Page 30 of 478 Page 31 of 478 Page 32 of 478 Page 33 of 478 Page 34 of 478 Page 35 of 478 Page 36 of 478 Page 37 of 478 Page 38 of 478 Pa g e 3 9 o f 4 7 8 Pa g e 4 0 o f 4 7 8 Pa g e 4 1 o f 4 7 8 Pa g e 4 2 o f 4 7 8 Pa g e 4 3 o f 4 7 8 Pa g e 4 4 o f 4 7 8 Pa g e 4 5 o f 4 7 8 Pa g e 4 6 o f 4 7 8 Pa g e 4 7 o f 4 7 8 Pa g e 4 8 o f 4 7 8 Pa g e 4 9 o f 4 7 8 Pa g e 5 0 o f 4 7 8 Pa g e 5 1 o f 4 7 8 Pa g e 5 2 o f 4 7 8 Pa g e 5 3 o f 4 7 8 Pa g e 5 4 o f 4 7 8 Pa g e 5 5 o f 4 7 8 Pa g e 5 6 o f 4 7 8 Pa g e 5 7 o f 4 7 8 Pa g e 5 8 o f 4 7 8 Pa g e 5 9 o f 4 7 8 Pa g e 6 0 o f 4 7 8 Pa g e 6 1 o f 4 7 8 Pa g e 6 2 o f 4 7 8 Pa g e 6 3 o f 4 7 8 Pa g e 6 4 o f 4 7 8 Pa g e 6 5 o f 4 7 8 Pa g e 6 6 o f 4 7 8 Pa g e 6 7 o f 4 7 8 Pa g e 6 8 o f 4 7 8 Pa g e 6 9 o f 4 7 8 Pa g e 7 0 o f 4 7 8 Pa g e 7 1 o f 4 7 8 Pa g e 7 2 o f 4 7 8 Pa g e 7 3 o f 4 7 8 Pa g e 7 4 o f 4 7 8 Pa g e 7 5 o f 4 7 8 Pa g e 7 6 o f 4 7 8 Pa g e 7 7 o f 4 7 8 Pa g e 7 8 o f 4 7 8 Pa g e 7 9 o f 4 7 8 Pa g e 8 0 o f 4 7 8 Pa g e 8 1 o f 4 7 8 Pa g e 8 2 o f 4 7 8 Pa g e 8 3 o f 4 7 8 Pa g e 8 4 o f 4 7 8 Pa g e 8 5 o f 4 7 8 Pa g e 8 6 o f 4 7 8 Pa g e 8 7 o f 4 7 8 Pa g e 8 8 o f 4 7 8 Pa g e 8 9 o f 4 7 8 Pa g e 9 0 o f 4 7 8 Pa g e 9 1 o f 4 7 8 Pa g e 9 2 o f 4 7 8 Pa g e 9 3 o f 4 7 8 Pa g e 9 4 o f 4 7 8 Pa g e 9 5 o f 4 7 8 Pa g e 9 6 o f 4 7 8 Pa g e 9 7 o f 4 7 8 Pa g e 9 8 o f 4 7 8 Pa g e 9 9 o f 4 7 8 Pa g e 1 0 0 o f 4 7 8 Pa g e 1 0 1 o f 4 7 8 Pa g e 1 0 2 o f 4 7 8 Pa g e 1 0 3 o f 4 7 8 Pa g e 1 0 4 o f 4 7 8 Pa g e 1 0 5 o f 4 7 8 Pa g e 1 0 6 o f 4 7 8 Pa g e 1 0 7 o f 4 7 8 Pa g e 1 0 8 o f 4 7 8 Pa g e 1 0 9 o f 4 7 8 Pa g e 1 1 0 o f 4 7 8 Pa g e 1 1 1 o f 4 7 8 Pa g e 1 1 2 o f 4 7 8 Pa g e 1 1 3 o f 4 7 8 Pa g e 1 1 4 o f 4 7 8 Pa g e 1 1 5 o f 4 7 8 Pa g e 1 1 6 o f 4 7 8 Pa g e 1 1 7 o f 4 7 8 Pa g e 1 1 8 o f 4 7 8 Pa g e 1 1 9 o f 4 7 8 Pa g e 1 2 0 o f 4 7 8 Pa g e 1 2 1 o f 4 7 8 Pa g e 1 2 2 o f 4 7 8 Page 123 of 478 Page 124 of 478 Page 125 of 478 Page 126 of 478 Page 127 of 478 Page 128 of 478 Page 129 of 478 Page 130 of 478 Page 131 of 478 Page 132 of 478 Page 133 of 478 Page 134 of 478 Page 135 of 478 Page 136 of 478 Page 137 of 478 Page 138 of 478 Page 139 of 478 Page 140 of 478 Page 141 of 478 Page 142 of 478 Page 143 of 478 Page 144 of 478 Page 145 of 478 Page 146 of 478 Page 147 of 478 Page 148 of 478 Page 149 of 478 Report Date: 28-Nov-2017 09:23:16 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Lims ID:200-41113-A-1 Client ID:SV-3 Sample Type:Client Inject. Date:24-Nov-2017 15:47:30 ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Sample Info:200-0028034-008 Misc. Info.:41113-01 Operator ID:VTP Instrument ID:CHB.i Method:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:28-Nov-2017 09:23:14 Calib Date:07-Nov-2017 01:49:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal/External Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: puangmaleek Date:28-Nov-2017 09:23:14 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags 2 Dichlorodifluoromethane 85 3.193 3.193 0.000 99 30922 0.3927 3 Chlorodifluoromethane 51 3.225 3.225 0.000 97 9246 0.2065 4 1,2-Dichloro-1,1,2,2-tetra 85 3.412 3.417 0.000 81 1124 0.0136 7M 5 Chloromethane 50 3.535 3.535 0.000 81 10997 0.3916 7 6 Butane 43 3.711 3.711 0.000 95 512500 10.6 7 Vinyl chloride 62 3.748 ND 8 Butadiene 54 3.812 3.812 0.000 96 52387 2.11 10 Bromomethane 94 4.479 ND 11 Chloroethane 64 4.709 ND 13 Vinyl bromide 106 5.120 ND 14 Trichlorofluoromethane 101 5.216 5.216 0.000 96 14482 0.1724 19 1,1,2-Trichloro-1,2,2-trif 101 6.241 6.246 -0.005 47 4658 0.0660 20 1,1-Dichloroethene 96 6.315 ND 21 Acetone 43 6.465 6.465 0.000 96 655650 12.4 22 Isopropyl alcohol 45 6.683 ND 23 Carbon disulfide 76 6.748 6.748 0.000 98 354616 3.58 24 3-Chloro-1-propene 41 7.014 ND 27 Methylene Chloride 49 7.276 7.276 0.000 50 7936 0.1874 7 28 2-Methyl-2-propanol 59 7.383 ND 29 Methyl tert-butyl ether 73 7.623 ND 30 trans-1,2-Dichloroethene 61 7.687 ND 32 Hexane 57 8.013 8.012 0.001 87 82757 1.28 33 1,1-Dichloroethane 63 8.423 ND 36 2-Butanone (MEK) 72 9.320 9.315 0.005 100 52904 2.54 37 cis-1,2-Dichloroethene 96 9.331 ND * 39 Chlorobromomethane 128 9.694 9.699 -0.005 94 355479 10.0 38 Tetrahydrofuran 42 9.710 ND 40 Chloroform 83 9.768 9.774 -0.006 95 393942 5.14 S 41 1,2-Dichloroethene, Total 61 10.000 ND 42 1,1,1-Trichloroethane 97 10.030 ND 43 Cyclohexane 84 10.041 10.046 -0.005 94 20217 0.3547 Page 150 of 478 Report Date: 28-Nov-2017 09:23:16 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags 44 Carbon tetrachloride 117 10.233 10.238 -0.005 96 3700 0.0515 45 Isooctane 57 10.521 10.521 0.000 91 18666 0.0865 46 Benzene 78 10.558 10.563 -0.005 95 205276 1.54 47 1,2-Dichloroethane 62 10.659 ND 48 n-Heptane 43 10.772 10.772 0.000 95 53501 0.6485 * 50 1,4-Difluorobenzene 114 11.103 11.102 0.001 94 1809784 10.0 53 Trichloroethene 95 11.476 ND 54 1,2-Dichloropropane 63 11.839 ND 55 Methyl methacrylate 69 11.876 ND 56 1,4-Dioxane 88 11.967 ND 58 Dichlorobromomethane 83 12.197 12.202 -0.005 97 34043 0.3805 60 cis-1,3-Dichloropropene 75 12.826 ND 61 4-Methyl-2-pentanone (MIBK 43 12.976 ND 64 Toluene 92 13.259 13.259 0.000 93 565427 6.00 66 trans-1,3-Dichloropropene 75 13.621 ND 67 1,1,2-Trichloroethane 83 13.888 ND 68 Tetrachloroethene 166 14.038 14.032 0.006 91 1898 0.0254 69 2-Hexanone 43 14.150 ND 70 Chlorodibromomethane 129 14.438 14.449 -0.011 39 2826 0.0319 71 Ethylene Dibromide 107 14.646 ND * 72 Chlorobenzene-d5 117 15.212 15.212 0.000 85 1577709 10.0 73 Chlorobenzene 112 15.249 ND 74 Ethylbenzene 91 15.319 15.319 0.000 97 199455 0.9656 76 m-Xylene & p-Xylene 106 15.463 15.468 -0.005 0 225968 2.78 78 o-Xylene 106 15.975 15.975 0.000 99 79771 0.9854 S 77 Xylenes, Total 106 0 3.76 79 Styrene 104 16.002 16.002 0.000 88 14649 0.1201 80 Bromoform 173 16.295 ND 81 Isopropylbenzene 105 16.391 ND 83 1,1,2,2-Tetrachloroethane 83 16.797 ND 84 N-Propylbenzene 91 16.866 16.866 0.000 99 73722 0.2615 87 4-Ethyltoluene 105 16.989 16.994 -0.005 96 80199 0.3575 88 2-Chlorotoluene 91 17.037 ND 89 1,3,5-Trimethylbenzene 105 17.059 17.058 0.001 92 58642 0.3162 91 tert-Butylbenzene 119 17.437 ND 92 1,2,4-Trimethylbenzene 105 17.507 17.507 0.000 98 206477 1.13 93 sec-Butylbenzene 105 17.694 ND 94 4-Isopropyltoluene 119 17.848 17.848 0.005 45 15619 0.0682 7 95 1,3-Dichlorobenzene 146 17.923 ND 96 1,4-Dichlorobenzene 146 18.035 ND 97 Benzyl chloride 91 18.185 ND 99 n-Butylbenzene 91 18.350 18.350 0.000 91 19136 0.0910 100 1,2-Dichlorobenzene 146 18.521 ND 103 1,2,4-Trichlorobenzene 180 20.880 ND 104 Hexachlorobutadiene 225 21.045 ND 105 Naphthalene 128 21.360 21.360 0.000 68 8974 0.0597 7 Page 151 of 478 Report Date: 28-Nov-2017 09:23:16 Chrom Revision: 2.2 13-Nov-2017 17:19:06 QC Flag Legend Processing Flags 7 - Failed Limit of Detection Review Flags M - Manually Integrated Reagents: ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 152 of 478 Report Date: 28-Nov-2017 09:23:16 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Tentatively Identified Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Lims ID:200-41113-A-1 Client ID:SV-3 Sample Type:Client Inject. Date:24-Nov-2017 15:47:30 ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Sample Info:200-0028034-008 Misc. Info.:41113-01 Operator ID:VTP Instrument ID:CHB.i Method:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:28-Nov-2017 09:23:14 Calib Date:07-Nov-2017 01:49:30 Tic RT Window:0.000 -0.000 Response:area Quant By:Nearest ISTD Quant LOD:10.00000 MS Library:\\ChromNA\Burlington\Database\NIST14.L Min. Match:1 Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: puangmaleek Date:28-Nov-2017 09:23:14 Tentative Identified Compound Results RT Area Amount ppb v/v Quant Cpnd Qual Lib Entry Molecular Formula Mol. Weight Flags 115-07-1 Propene 3.135 3395030 15.3 39 86 57 C3H6 42 Unknown 14.673 2706411 5.96 72 0 0 0 2216-33-3 Octane, 3-methyl- 14.838 2133910 4.70 72 91 12944 C9H20 128 Unknown 15.671 1553146 3.42 72 0 0 0 15869-93-9 Octane, 3,5-dimethyl- 15.794 2338437 5.15 72 87 19687 C10H22 142 Unknown 15.847 1986337 4.38 72 0 0 0 Unknown 16.077 2142347 4.72 72 0 0 0 871-83-0 Nonane, 2-methyl- 16.413 5134482 11.3 72 91 19660 C10H22 142 5911-04-6 Nonane, 3-methyl- 16.541 4928301 10.9 72 94 19659 C10H22 142 124-18-5 Decane 16.936 7023548 15.5 72 90 19650 C10H22 142 Page 153 of 478 Report Date: 28-Nov-2017 09:23:16 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Quantitation Compounds Compound RT Area Amount ppb v/v * 39 Chlorobromomethane 9.694 2216713 10.0 * 72 Chlorobenzene-d5 15.212 4537980 10.0 QC Flag Legend Processing Flags Reagents: ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 154 of 478 Y ( X 1 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 9 . 6 9 4 ) * 1 , 4 - D i f l u o r o b e n z e n e ( 1 1 . 1 0 3 ) * C h l o r o b e n z e n e - d 5 ( 1 5 . 2 1 2 ) Report Date: 28-Nov-2017 09:23:16 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 6 Butane, CAS: 106-97-8 30 50 70 90 110 130 150 170 190 210m/z 0 4 8 12 16 20 24 Raw Spec:Scan 137(3.71) 43 41 58 30 50 70 90 110 130 150 170 190 210m/z 0 4 8 12 16 20 24 Enhanced Spec:Scan 137(3.71),Qvalue=95 43 41 58 30 50 70 90 110 130 150 170 190 210m/z 0 2 4 6 8 10 Ref Spec: 6 Butane (DATA) 43 41 58 30 50 70 90 110 130 150 170 190 210m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 137 @ 3.711 min.(Qvalue: 95) 41 42 58 3.2 3.5 3.8 4.1Min 0 4 8 12 16 20 24 m/z 43.0 3.1 3.4 3.7 4.0Min 0 5 10 15 20 25 30 35 m/z 41.0 3.2 3.5 3.8 4.1Min 0 5 10 15 20 25 30 35 m/z 58.0 3.1 3.4 3.7 4.0 4.3Min 0 6 12 18 24 30 36 m/z 43.0 m/z 41.0 m/z 58.0 Page 156 of 478 Report Date: 28-Nov-2017 09:23:16 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 8 Butadiene, CAS: 106-99-0 36 40 44 48 52 56m/z 0 4 8 12 16 20 24 28 Raw Spec:Scan 156(3.81) 5439 53 50 5751 4441 4938 55 36 40 44 48 52 56m/z 0 4 8 12 16 20 24 28 Enhanced Spec:Scan 156(3.81),Qvalue=96 5439 53 50 5751 4441 4938 55 36 40 44 48 52 56m/z 0 2 4 6 8 10 Ref Spec: 8 Butadiene (DATA) 39 54 53 50 51 4938 36 40 44 48 52 56m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 156 @ 3.812 min.(Qvalue: 96) 574441545051 3.3 3.6 3.9 4.2Min 0 4 8 12 16 20 24 28 m/z 54.0 Page 157 of 478 Report Date: 28-Nov-2017 09:23:16 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 21 Acetone, CAS: 67-64-1 30 50 70 90 110 130 150 170 190 210m/z 0 3 6 9 12 15 18 21 24 Raw Spec:Scan 653(6.46) 43 44 58 42 30 50 70 90 110 130 150 170 190 210m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 653(6.46),Qvalue=96 43 58 42 30 50 70 90 110 130 150 170 190 210m/z 0 2 4 6 8 10 Ref Spec: 21 Acetone (NIST) 43 58 42 30 50 70 90 110 130 150 170 190 210m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 6.470 min.(Qvalue: 96) 5844 5.9 6.2 6.5 6.8Min 0 3 6 9 12 15 18 21 24 m/z 43.0 5.9 6.2 6.5 6.8Min 0 11 22 33 44 55 66 77 m/z 58.0 5.9 6.2 6.5 6.8Min 0 4 8 12 16 20 24 m/z 43.0 m/z 58.0 Page 158 of 478 Report Date: 28-Nov-2017 09:23:16 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 23 Carbon disulfide, CAS: 75-15-0 38 42 46 50 54 58 62 66 70 74 78m/z 0 2 4 6 8 10 12 14 Raw Spec:Scan 706(6.75) 76 44 38 42 46 50 54 58 62 66 70 74 78m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 706(6.75),Qvalue=98 76 44 38 42 46 50 54 58 62 66 70 74 78m/z 0 2 4 6 8 10 Ref Spec: 23 Carbon disulfide (NIST) 76 44 38 42 46 50 54 58 62 66 70 74 78m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 6.750 min.(Qvalue: 98) 78 6.2 6.5 6.8 7.1Min 0 2 4 6 8 10 12 14 m/z 76.0 Page 159 of 478 Report Date: 28-Nov-2017 09:23:16 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 32 Hexane, CAS: 110-54-3 37 41 45 49 53 57 61 65 69 73 77 81 85m/z 0 5 10 15 20 25 30 35 Raw Spec:Scan 943(8.01) 43 57 56 72 86557144 37 41 45 49 53 57 61 65 69 73 77 81 85m/z 0 2 4 6 8 10 12 Amdis Enhanced Spec: Scan 943(8.01),Qvalue=87 43 5741 56 72 865571 37 41 45 49 53 57 61 65 69 73 77 81 85m/z 0 2 4 6 8 10 Ref Spec: 32 Hexane (NIST) 57 43 56 86 55 37 41 45 49 53 57 61 65 69 73 77 81 85m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 8.020 min.(Qvalue: 87) 7243 7.5 7.8 8.1 8.4Min 0 4 8 12 16 20 24 28 m/z 57.0 7.5 7.8 8.1 8.4Min 0 7 14 21 28 35 42 49 m/z 86.0 7.5 7.8 8.1 8.4Min 0 5 10 15 20 25 30 m/z 57.0 m/z 86.0 Page 160 of 478 Report Date: 28-Nov-2017 09:23:16 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 36 2-Butanone (MEK), CAS: 78-93-3 30 50 70 90 110 130 150m/z 0 10 20 30 40 50 60 70 80 Raw Spec:Scan 1188(9.32) 43 72 57 30 50 70 90 110 130 150m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 1188(9.32),Qvalue=100 43 72 57 30 50 70 90 110 130 150m/z 0 2 4 6 8 10 Ref Spec: 36 2-Butanone (MEK)(DATA) 43 72 57 30 50 70 90 110 130 150m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 9.320 min.(Qvalue:100) 7242 8.8 9.1 9.4 9.7Min 0 3 6 9 12 15 18 21 m/z 72.0 8.8 9.1 9.4 9.7Min 0 11 22 33 44 55 66 77 m/z 43.0 8.8 9.1 9.4 9.7Min 0 12 24 36 48 60 72 m/z 72.0 m/z 43.0 Page 161 of 478 Report Date: 28-Nov-2017 09:23:17 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 40 Chloroform, CAS: 67-66-3 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119123127m/z 0 3 6 9 12 15 Raw Spec:Scan 1272(9.77) 83 85 47 8748 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119123127m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 1272(9.77),Qvalue=95 83 85 47 8748 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119123127m/z 0 13 26 39 52 65 78 91 Ref Spec: 40 Chloroform (NIST) 83 85 47 48 8782 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119123127m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 9.770 min.(Qvalue: 95) 9.2 9.5 9.8 10.1Min 0 3 6 9 12 15 m/z 83.0 9.2 9.5 9.8 10.1Min 0 2 4 6 8 10 m/z 85.0 9.2 9.5 9.8 10.1Min 0 3 6 9 12 15 m/z 83.0 m/z 85.0 Page 162 of 478 Report Date: 28-Nov-2017 09:23:17 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 43 Cyclohexane, CAS: 110-82-7 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97m/z 0 2 4 6 8 10 12 Raw Spec:Scan 1323(10.04) 56 41 84 55 694357 67 7154 82 85 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97m/z 0 2 4 6 8 10 12 14 Amdis Enhanced Spec: Scan 1323(10.04),Qvalue=94 56 84 41 55 6943 67 8254 85 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97m/z 0 2 4 6 8 10 Ref Spec: 43 Cyclohexane (NIST) 56 84 41 55 69 42 54 8583 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 10.050 min.(Qvalue: 94) 43 8267 9.5 9.8 10.1 10.4Min 0 9 18 27 36 45 54 63 m/z 84.0 9.5 9.8 10.1 10.4Min 0 2 4 6 8 10 12 m/z 56.0 9.5 9.8 10.1 10.4Min 0 2 4 6 8 10 12 m/z 84.0 m/z 56.0 Page 163 of 478 Report Date: 28-Nov-2017 09:23:17 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 44 Carbon tetrachloride, CAS: 56-23-5 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119 123m/z 0 2 4 6 8 10 12 14 16 Raw Spec:Scan 1359(10.23) 117 40 8244 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119 123m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 1359(10.23),Qvalue=96 117 82 47 84 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119 123m/z 0 13 26 39 52 65 78 91 Ref Spec: 44 Carbon tetrachloride (NIST) 117 8247 84 49 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119 123m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 10.230 min.(Qvalue: 96) 119 9.7 10.0 10.3 10.6Min 0 3 6 9 12 15 18 21 m/z 117.0 9.7 10.0 10.3 10.6Min 0 3 6 9 12 15 18 21 m/z 119.0 9.7 10.0 10.3 10.6Min 0 3 6 9 12 15 18 21 m/z 117.0 m/z 119.0 Page 164 of 478 Report Date: 28-Nov-2017 09:23:17 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 46 Benzene, CAS: 71-43-2 36 40 44 48 52 56 60 64 68 72 76 80m/z 0 11 22 33 44 55 66 77 Raw Spec:Scan 1420(10.56) 78 775239 79 36 40 44 48 52 56 60 64 68 72 76 80m/z 0 11 22 33 44 55 66 77 Enhanced Spec:Scan 1420(10.56),Qvalue=95 78 77 5239 79 36 40 44 48 52 56 60 64 68 72 76 80m/z 0 2 4 6 8 10 Ref Spec: 46 Benzene (DATA) 78 77515239 7974 36 40 44 48 52 56 60 64 68 72 76 80m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1420 @ 10.558 min.(Qvalue: 95) 10.0 10.3 10.6 10.9Min 0 11 22 33 44 55 66 77 m/z 78.0 10.0 10.3 10.6 10.9Min 0 3 6 9 12 15 18 21 m/z 77.0 10.0 10.3 10.6 10.9Min 0 12 24 36 48 60 72 84 m/z 78.0 m/z 77.0 Page 165 of 478 Report Date: 28-Nov-2017 09:23:17 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 48 n-Heptane, CAS: 142-82-5 38 42 46 50 54 58 62 66 70 74 78 82 86 90 94 98m/z 0 3 6 9 12 15 18 21 Raw Spec:Scan 1460(10.77) 43 7157 56 70 44 1005558 38 42 46 50 54 58 62 66 70 74 78 82 86 90 94 98m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 1460(10.77),Qvalue=95 43 7157 56 70 100445558 38 42 46 50 54 58 62 66 70 74 78 82 86 90 94 98m/z 0 2 4 6 8 10 Ref Spec: 48 n-Heptane (NIST) 43 57 71 56 70 10055 38 42 46 50 54 58 62 66 70 74 78 82 86 90 94 98m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 10.770 min.(Qvalue: 95) 44 71 10057 10.2 10.5 10.8 11.1Min 0 3 6 9 12 15 18 21 m/z 43.0 10.2 10.5 10.8 11.1Min 0 2 4 6 8 10 12 m/z 71.0 10.2 10.5 10.8 11.1Min 0 3 6 9 12 15 18 21 m/z 43.0 m/z 71.0 Page 166 of 478 Report Date: 28-Nov-2017 09:23:17 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 58 Dichlorobromomethane, CAS: 75-27-4 30 50 70 90 110 130 150 170m/z 0 2 4 6 8 10 12 14 Raw Spec:Scan 1727(12.20) 83 85 7043 8155 87 12969 30 50 70 90 110 130 150 170m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 1727(12.20),Qvalue=97 83 85 704347 71 87 12969 30 50 70 90 110 130 150 170m/z 0 13 26 39 52 65 78 91 Ref Spec: 58 Dichlorobromomethane (NIST) 83 85 47 48 1298779 30 50 70 90 110 130 150 170m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 12.200 min.(Qvalue: 97) 7043 7155 11.6 11.9 12.2 12.5Min 0 2 4 6 8 10 12 14 m/z 83.0 11.7 12.0 12.3 12.6Min 0 12 24 36 48 60 72 84 m/z 85.0 11.6 11.9 12.2 12.5 12.8Min 0 3 6 9 12 15 m/z 83.0 m/z 85.0 Page 167 of 478 Report Date: 28-Nov-2017 09:23:17 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 64 Toluene, CAS: 108-88-3 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112 116m/z 0 6 12 18 24 30 36 42 Raw Spec:Scan 1926(13.26) 91 92 43 65 8551 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112 116m/z 0 5 10 15 20 25 30 35 Amdis Enhanced Spec: Scan 1926(13.26),Qvalue=93 91 92 43 856557417151 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112 116m/z 0 2 4 6 8 10 Ref Spec: 64 Toluene (NIST) 91 92 6551 93 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112 116m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 13.250 min.(Qvalue: 93) 43 8557 12.7 13.0 13.3 13.6Min 0 4 8 12 16 20 24 m/z 92.0 12.7 13.0 13.3 13.6Min 0 6 12 18 24 30 36 42 m/z 91.0 12.7 13.0 13.3 13.6Min 0 6 12 18 24 30 36 42 m/z 92.0 m/z 91.0 Page 168 of 478 Report Date: 28-Nov-2017 09:23:17 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 74 Ethylbenzene, CAS: 100-41-4 30 50 70 90 110 130 150 170 190 210m/z 0 3 6 9 12 15 18 Raw Spec:Scan 2312(15.32) 43 57 91 41 857156 1068469 30 50 70 90 110 130 150 170 190 210m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 2312(15.32),Qvalue=97 91 106 51 7765 78 105 30 50 70 90 110 130 150 170 190 210m/z 0 2 4 6 8 10 Ref Spec: 74 Ethylbenzene (NIST) 91 106 51 65 77 78 105 30 50 70 90 110 130 150 170 190 210m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 15.320 min.(Qvalue: 97) 106 14.8 15.1 15.4 15.7Min 0 3 6 9 12 15 18 21 m/z 91.0 14.8 15.1 15.4 15.7Min 0 2 4 6 8 10 12 m/z 106.0 14.8 15.1 15.4 15.7Min 0 3 6 9 12 15 18 21 m/z 91.0 m/z 106.0 Page 169 of 478 Report Date: 28-Nov-2017 09:23:17 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 76 m-Xylene & p-Xylene, CAS: 179601-23-1 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 3 6 9 12 15 18 21 Raw Spec:Scan 2339(15.46) 91 106 55 77 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 3 6 9 12 15 18 21 Enhanced Spec:Scan 2339(15.46),Qvalue=0 91 106 55 77 14.9 15.2 15.5 15.8Min 0 2 4 6 8 10 12 m/z 106.0 14.9 15.2 15.5 15.8Min 0 3 6 9 12 15 18 21 m/z 91.0 14.9 15.2 15.5 15.8Min 0 3 6 9 12 15 18 21 m/z 106.0 m/z 91.0 Page 170 of 478 Report Date: 28-Nov-2017 09:23:17 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 78 o-Xylene, CAS: 95-47-6 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 2 4 6 8 10 12 14 16 Raw Spec:Scan 2435(15.98) 57 71 9143 106 113 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 2435(15.98),Qvalue=99 91 106 7751 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 2 4 6 8 10 Ref Spec: 78 o-Xylene (NIST) 91 106 7751 30 50 70 90 110 130 150 170 190 210 230 250m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 15.980 min.(Qvalue: 99) 97 15.4 15.7 16.0 16.3Min 0 10 20 30 40 50 60 70 m/z 106.0 15.4 15.7 16.0 16.3Min 0 2 4 6 8 10 12 14 m/z 91.0 15.4 15.7 16.0 16.3Min 0 3 6 9 12 15 m/z 106.0 m/z 91.0 Page 171 of 478 Report Date: 28-Nov-2017 09:23:17 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 84 N-Propylbenzene, CAS: 103-65-1 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 8 16 24 32 40 48 56 Raw Spec:Scan 2602(16.87) 55 91 97 69 120 140 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 2602(16.87),Qvalue=99 91 57 1207143 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 2 4 6 8 10 Ref Spec: 84 N-Propylbenzene (NIST) 91 120 9265 30 50 70 90 110 130 150 170 190 210 230 250 270m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 16.870 min.(Qvalue: 99) 57 71 111 16.3 16.6 16.9 17.2Min 0 6 12 18 24 30 36 42 m/z 91.0 16.3 16.6 16.9 17.2Min 0 4 8 12 16 20 24 28 m/z 120.0 16.3 16.6 16.9 17.2Min 0 2 4 6 8 10 12 14 m/z 92.0 16.3 16.6 16.9 17.2Min 0 7 14 21 28 35 42 m/z 91.0 m/z 120.0 m/z 92.0 Page 172 of 478 Report Date: 28-Nov-2017 09:23:17 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 87 4-Ethyltoluene, CAS: 622-96-8 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 3 6 9 12 15 18 21 Raw Spec:Scan 2625(16.99) 9755 69 105 140 120 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 2625(16.99),Qvalue=96 10557 43 71 120 83 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 2 4 6 8 10 Ref Spec: 87 4-Ethyltoluene (NIST) 105 120 91 30 50 70 90 110 130 150 170 190 210 230 250 270m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 16.990 min.(Qvalue: 96) 5743 71 98 16.4 16.7 17.0 17.3Min 0 11 22 33 44 55 66 77 m/z 105.0 16.4 16.7 17.0 17.3Min 0 6 12 18 24 30 36 42 m/z 120.0 16.4 16.7 17.0 17.3Min 0 12 24 36 48 60 72 84 m/z 105.0 m/z 120.0 Page 173 of 478 Report Date: 28-Nov-2017 09:23:17 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 89 1,3,5-Trimethylbenzene, CAS: 108-67-8 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 12 24 36 48 60 72 84 Raw Spec:Scan 2638(17.06) 55 97 105 120 140 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 2638(17.06),Qvalue=92 105 120 964377 121 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 2 4 6 8 10 Ref Spec: 89 1,3,5-Trimethylbenzene (NIST) 105 120 77 121 30 50 70 90 110 130 150 170 190 210 230 250m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 17.060 min.(Qvalue: 92) 1114391 16.5 16.8 17.1 17.4Min 0 2 4 6 8 10 12 m/z 105.0 16.5 16.8 17.1 17.4Min 0 7 14 21 28 35 42 49 m/z 120.0 16.5 16.8 17.1 17.4Min 0 2 4 6 8 10 12 m/z 105.0 m/z 120.0 Page 174 of 478 Report Date: 28-Nov-2017 09:23:17 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 92 1,2,4-Trimethylbenzene, CAS: 95-63-6 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 2 4 6 8 10 12 Raw Spec:Scan 2722(17.51) 105 120 57 71 121 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 2722(17.51),Qvalue=98 105 120 77 121 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 2 4 6 8 10 Ref Spec: 92 1,2,4-Trimethylbenzene (NIST) 105 120 77 30 50 70 90 110 130 150 170 190 210 230 250 270m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 17.510 min.(Qvalue: 98) 12091 17.0 17.3 17.6 17.9Min 0 2 4 6 8 10 12 m/z 105.0 17.0 17.3 17.6 17.9Min 0 7 14 21 28 35 42 49 m/z 120.0 17.0 17.3 17.6 17.9Min 0 2 4 6 8 10 12 m/z 105.0 m/z 120.0 Page 175 of 478 Report Date: 28-Nov-2017 09:23:16 Chrom Revision: 2.2 13-Nov-2017 17:19:06Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 4 1,2-Dichloro-1,1,2,2-tetrafluoroethane, CAS: 76-14-2Signal: 1 Processing Integration Results RT: 3.19 Area: 30922 Amount: 0.373979 Amount Units: ppb v/v 2.9 3.1 3.3 3.5 3.7Min 0 2 4 6 8 10 12 14 16 18 20 m/z 85.0 Manual Integration Results RT: 3.41 Area: 1124 Amount: 0.013594 Amount Units: ppb v/v 2.9 3.1 3.3 3.5 3.7Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 m/z 85.0 Reviewer: puangmaleek, 28-Nov-2017 09:18:37 Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID Page 176 of 478 Report Date: 28-Nov-2017 09:23:16 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 4 1,2-Dichloro-1,1,2,2-tetrafluoroethane, CAS: 76-14-2 Signal: 1 Processing Integration Results RT: 3.19 Area: 30922 Amount: 0.373979 Amount Units: ppb v/v 2.9 3.1 3.3 3.5 3.7Min 0 2 4 6 8 10 12 14 16 18 20 m/z 85.0 Manual Integration Results RT: 3.41 Area: 1124 Amount: 0.013594 Amount Units: ppb v/v 2.9 3.1 3.3 3.5 3.7Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 m/z 85.0 Reviewer: puangmaleek, 28-Nov-2017 09:18:47 Audit Action: Manually Integrated Audit Reason: Assign Peak Page 177 of 478 Report Date: 28-Nov-2017 09:23:16 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 4 1,2-Dichloro-1,1,2,2-tetrafluoroethane, CAS: 76-14-2 Signal: 2 Processing Integration Results RT: 3.41 Area: 0 Amount: 0.373979 Amount Units: ppb v/v 2.9 3.1 3.3 3.5 3.7Min 0 3 6 9 12 15 18 21 24 27 30 33 36 39 42 m/z 135.0 Manual Integration Results RT: 3.42 Area: 638 Amount: 0.013594 Amount Units: ppb v/v 2.9 3.1 3.3 3.5 3.7Min 0 3 6 9 12 15 18 21 24 27 30 33 36 39 42 m/z 135.0 Reviewer: puangmaleek, 28-Nov-2017 09:18:57 Audit Action: Manually Integrated Audit Reason: Assign Peak Page 178 of 478 Report Date: 28-Nov-2017 09:23:16 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 4 1,2-Dichloro-1,1,2,2-tetrafluoroethane, CAS: 76-14-2 Signal: 3 Processing Integration Results RT: 3.19 Area: 9942 Amount: 0.373979 Amount Units: ppb v/v 2.9 3.1 3.3 3.5 3.7Min 0 5 10 15 20 25 30 35 40 45 50 55 60 m/z 87.0 Manual Integration Results RT: 3.42 Area: 167 Amount: 0.013594 Amount Units: ppb v/v 2.9 3.1 3.3 3.5 3.7Min -1 3 7 11 15 19 23 27 31 35 39 43 47 51 55 59 m/z 87.0 Reviewer: puangmaleek, 28-Nov-2017 09:19:06 Audit Action: Manually Integrated Audit Reason: Assign Peak Page 179 of 478 Report Date: 28-Nov-2017 09:23:18 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Propene 115-07-1 NIST14.L 57 C3H6 42 86 Cyclopropane 75-19-4 NIST14.L 60 C3H6 42 10 Cyclopropene 2781-85-3 NIST14.L 50 C3H4 40 9 36 40 44 48 52 56 60 64 68 72 76m/z 0 12 24 36 48 60 Raw Spec: Scan 29(3.13) 4139 42 43 38 36 40 44 48 52 56 60 64 68 72 76m/z 0 12 24 36 48 60 28034-08[MS SCAN Spec]:Scan 29(3.13) 4139 42 43 38 36 40 44 48 52 56 60 64 68 72 76m/z 0 18 36 54 72 90 Entry #57, Propene (from NIST14.L) 41 39 42 38 36 40 44 48 52 56 60 64 68 72 76m/z 2 20 38 56 74 92 Entry #60, Cyclopropane (from NIST14.L) 42 39 38 36 40 44 48 52 56 60 64 68 72 76m/z 0 18 36 54 72 90 Entry #50, Cyclopropene (from NIST14.L) 39 40 38 41 Page 180 of 478 Report Date: 28-Nov-2017 09:23:18 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Unknown Octane,4-methyl-2216-34-4 NIST14.L 12942 C9H20 128 80 Octane,2-methyl-3221-61-2 NIST14.L 12947 C9H20 128 72 Heptane,2,4-dimethyl-2213-23-2 NIST14.L 12973 C9H20 128 64 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112 116 120 124 128m/z 0 6 12 18 24 30 Raw Spec: Scan 2191(14.67) 43 57 71 8541 56 70 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112 116 120 124 128m/z 0 6 12 18 24 30 28034-08[MS SCAN Spec]:Scan 2191(14.67) 43 57 71 8541 56 70 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112 116 120 124 128m/z 0 18 36 54 72 90 Entry #12942, Octane, 4-methyl- (from NIST14.L) 43 85714157 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112 116 120 124 128m/z 0 18 36 54 72 90 Entry #12947, Octane, 2-methyl- (from NIST14.L) 43 57 41 71 56 85 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112 116 120 124 128m/z 0 18 36 54 72 90 Entry #12973, Heptane, 2,4-dimethyl- (from NIST14.L) 43 85577141 84 Page 181 of 478 Report Date: 28-Nov-2017 09:23:18 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Octane,3-methyl-2216-33-3 NIST14.L 12944 C9H20 128 91 Heptane,2,5-dimethyl-2216-30-0 NIST14.L 12977 C9H20 128 72 Undecane,6-methyl-17302-33-9 NIST14.L 39991 C12H26 170 53 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170m/z 0 7 14 21 28 35 Raw Spec: Scan 2222(14.84) 57 43 56 98 997139 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170m/z 0 7 14 21 28 35 28034-08[MS SCAN Spec]:Scan 2222(14.84) 57 43 56 98 997139 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170m/z 0 18 36 54 72 90 Entry #12944, Octane, 3-methyl- (from NIST14.L) 57 43 56 98 9971 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170m/z 0 18 36 54 72 90 Entry #12977, Heptane, 2,5-dimethyl- (from NIST14.L) 57 43 56 71 99 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170m/z 0 18 36 54 72 90 Entry #39991,Undecane, 6-methyl- (from NIST14.L) 57 43 985671 Page 182 of 478 Report Date: 28-Nov-2017 09:23:18 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Unknown Pentane,2,2-dimethyl-590-35-2 NIST14.L 4049 C7H16 100 59 Butane,2,2,3-trimethyl-464-06-2 NIST14.L 4061 C7H16 100 53 Heptane,4-ethyl-2216-32-2 NIST14.L 12941 C9H20 128 47 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 4 8 12 16 Raw Spec: Scan 2378(15.67) 5743 8556 41 84715539 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 4 8 12 16 28034-08[MS SCAN Spec]:Scan 2378(15.67) 5743 8556 41 84715539 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #4049, Pentane, 2,2-dimethyl- (from NIST14.L) 57 43 41 56 85 39 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #4061, Butane, 2,2,3-trimethyl- (from NIST14.L) 57 43 56 85 39 55 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #12941, Heptane, 4-ethyl- (from NIST14.L) 43 57 85 41 9855 9969 Page 183 of 478 Report Date: 28-Nov-2017 09:23:18 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Octane,3,5-dimethyl-15869-93-9 NIST14.L 19687 C10H22 142 87 Octane,2,5-dimethyl-15869-89-3 NIST14.L 19672 C10H22 142 64 Undecane,5,5-dimethyl-17312-73-1 NIST14.L 51431 C13H28 184 64 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 5 10 15 20 25 Raw Spec: Scan 2401(15.79) 57 43 714155 85 996939 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 5 10 15 20 25 28034-08[MS SCAN Spec]:Scan 2401(15.79) 57 43 714155 85 996939 30 50 70 90 110 130 150 170 190 210 230 250m/z 1 19 37 55 73 91 Entry #19687, Octane, 3,5-dimethyl- (from NIST14.L) 57 43 71 7055 39 8569 99 11353 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 18 36 54 72 90 Entry #19672, Octane, 2,5-dimethyl- (from NIST14.L) 57 43 71 41 995585 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 18 36 54 72 90 Entry #51431,Undecane, 5,5-dimethyl- (from NIST14.L) 57 43 71 41 998556 12770 Page 184 of 478 Report Date: 28-Nov-2017 09:23:18 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Unknown Decane 124-18-5 NIST14.L 19648 C10H22 142 58 Octane,2,7-dimethyl-1072-16-8 NIST14.L 19680 C10H22 142 50 Hexane,2,5-dimethyl-592-13-2 NIST14.L 7788 C8H18 114 38 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 4 8 12 16 Raw Spec: Scan 2411(15.85) 5743 55 974171 998539 12696 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 4 8 12 16 28034-08[MS SCAN Spec]:Scan 2411(15.85) 5743 55 974171 998539 12696 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #19648, Decane (from NIST14.L) 5743 71 85567039 99 14253 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #19680, Octane, 2,7-dimethyl- (from NIST14.L) 43 57 41 71 9956398569 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 2 20 38 56 74 92 Entry #7788, Hexane, 2,5-dimethyl- (from NIST14.L) 5743 39 997155 112 114 Page 185 of 478 Report Date: 28-Nov-2017 09:23:18 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Unknown Nonane,3-methyl-5911-04-6 NIST14.L 19662 C10H22 142 76 Octane,3,6-dimethyl-15869-94-0 NIST14.L 19677 C10H22 142 64 Hexadecane,2,6,10,14-tetramethyl-638-36-8 NIST14.L 142261 C20H42 282 53 30 50 70 90 110 130 150 170 190 210 230 250 270 290m/z 0 3 6 9 12 Raw Spec: Scan 2454(16.08) 57 71 43 55 83 113703985 30 50 70 90 110 130 150 170 190 210 230 250 270 290m/z 0 3 6 9 12 28034-08[MS SCAN Spec]:Scan 2454(16.08) 57 71 43 55 83 113703985 30 50 70 90 110 130 150 170 190 210 230 250 270 290m/z 0 18 36 54 72 90 Entry #19662, Nonane, 3-methyl- (from NIST14.L) 57 43 71 41 56 39 11370 30 50 70 90 110 130 150 170 190 210 230 250 270 290m/z 0 18 36 54 72 90 Entry #19677, Octane, 3,6-dimethyl- (from NIST14.L) 57 7143 41 56 11339 30 50 70 90 110 130 150 170 190 210 230 250 270 290m/z 0 18 36 54 72 90 Entry #142261, Hexadecane, 2,6,10,14-tetramethyl- (from NIST14.L) 57 71 43 854155 1137099 127 Page 186 of 478 Report Date: 28-Nov-2017 09:23:19 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Nonane,2-methyl-871-83-0 NIST14.L 19660 C10H22 142 91 Tetradecane 629-59-4 NIST14.L 63624 C14H30 198 72 Silane,trichlorooctadecyl-112-04-9 NIST14.L 230698 C18H37Cl3Si 386 72 30 50 70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390m/z 0 12 24 36 48 60 Raw Spec: Scan 2517(16.41) 57 71 85 30 50 70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390m/z 0 12 24 36 48 60 28034-08[MS SCAN Spec]:Scan 2517(16.41) 57 71 85 30 50 70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390m/z 0 18 36 54 72 90 Entry #19660, Nonane, 2-methyl- (from NIST14.L) 43 57 71 98 30 50 70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390m/z 0 18 36 54 72 90 Entry #63624, Tetradecane (from NIST14.L) 5743 71 85 99 30 50 70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390m/z 0 18 36 54 72 90 Entry #230698, Silane, trichlorooctadecyl- (from NIST14.L) 57 71 85 99 135 Page 187 of 478 Report Date: 28-Nov-2017 09:23:19 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Nonane,3-methyl-5911-04-6 NIST14.L 19659 C10H22 142 94 Octane,3,6-dimethyl-15869-94-0 NIST14.L 19677 C10H22 142 90 Octane,2,6-dimethyl-2051-30-1 NIST14.L 19673 C10H22 142 78 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 12 24 36 48 60 Raw Spec: Scan 2541(16.54) 57 71 43 56 11255 113703985 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 12 24 36 48 60 28034-08[MS SCAN Spec]:Scan 2541(16.54) 57 71 43 56 11255 113703985 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 18 36 54 72 90 Entry #19659, Nonane, 3-methyl- (from NIST14.L) 57 7143 5641 112 11355398570 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 18 36 54 72 90 Entry #19677, Octane, 3,6-dimethyl- (from NIST14.L) 57 7143 41 56 11339 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 18 36 54 72 90 Entry #19673, Octane, 2,6-dimethyl- (from NIST14.L) 57 43 71 5641 113558539 Page 188 of 478 Report Date: 28-Nov-2017 09:23:19 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-08.D Injection Date:24-Nov-2017 15:47:30 Instrument ID:CHB.i Lims ID:200-41113-A-1 Lab Sample ID:200-41113-1 Client ID:SV-3 Operator ID:VTP ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Decane 124-18-5 NIST14.L 19650 C10H22 142 90 Carbonic acid,prop-1-en-2-yl tetradecyl ester 1000382-90-9 NIST14.L 157798 C18H34O3 298 78 Tetradecane 629-59-4 NIST14.L 63624 C14H30 198 72 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 16 32 48 64 80 Raw Spec: Scan 2615(16.94) 5743 7141 85567039 99 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 16 32 48 64 80 28034-08[MS SCAN Spec]:Scan 2615(16.94) 5743 7141 85567039 99 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 18 36 54 72 90 Entry #19650, Decane (from NIST14.L) 43 57 41 71 85567039 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 18 36 54 72 90 Entry #157798, Carbonic acid, prop-1-en-2-yl tetradecyl ester (from NIST14.L) 57 43 714155 85 9739 111 30 50 70 90 110 130 150 170 190 210 230 250 270m/z 0 18 36 54 72 90 Entry #63624, Tetradecane (from NIST14.L) 5743 7141 85 55 7039 9984 Page 189 of 478 Page 190 of 478 Page 191 of 478 Page 192 of 478 Page 193 of 478 Page 194 of 478 Page 195 of 478 Page 196 of 478 Report Date: 28-Nov-2017 09:30:40 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Lims ID:200-41113-A-2 Client ID:SV-2 Sample Type:Client Inject. Date:24-Nov-2017 16:40:30 ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Sample Info:200-0028034-009 Misc. Info.:41113-02 Operator ID:VTP Instrument ID:CHB.i Method:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:28-Nov-2017 09:30:39 Calib Date:07-Nov-2017 01:49:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal/External Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: puangmaleek Date:28-Nov-2017 09:30:39 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags 2 Dichlorodifluoromethane 85 3.193 3.193 0.000 98 10007 0.1252 3 Chlorodifluoromethane 51 3.225 ND 4 1,2-Dichloro-1,1,2,2-tetra 85 3.412 ND 5 Chloromethane 50 3.540 3.540 0.005 37 3533 0.1239 7 6 Butane 43 3.716 3.711 0.005 98 276844 5.62 7 Vinyl chloride 62 3.748 ND 8 Butadiene 54 3.812 3.812 0.000 96 18850 0.7488 10 Bromomethane 94 4.479 ND 11 Chloroethane 64 4.709 ND 13 Vinyl bromide 106 5.120 ND 14 Trichlorofluoromethane 101 5.221 5.221 0.005 1 4894 0.0574 7 19 1,1,2-Trichloro-1,2,2-trif 101 6.246 ND 20 1,1-Dichloroethene 96 6.315 ND 21 Acetone 43 6.464 6.465 -0.001 96 682450 12.7 22 Isopropyl alcohol 45 6.683 ND 23 Carbon disulfide 76 6.747 6.748 -0.001 98 173080 1.72 24 3-Chloro-1-propene 41 7.014 ND 27 Methylene Chloride 49 7.281 7.281 0.005 58 4448 0.1034 7 28 2-Methyl-2-propanol 59 7.409 7.409 0.026 62 10601 0.1350 7 29 Methyl tert-butyl ether 73 7.660 7.623 0.037 95 19223 0.1797 30 trans-1,2-Dichloroethene 61 7.687 ND 32 Hexane 57 8.012 8.012 0.000 80 28076 0.4285 33 1,1-Dichloroethane 63 8.423 ND 36 2-Butanone (MEK) 72 9.325 9.315 0.010 100 42511 2.01 37 cis-1,2-Dichloroethene 96 9.331 ND * 39 Chlorobromomethane 128 9.699 9.699 0.000 93 360978 10.0 38 Tetrahydrofuran 42 9.710 ND 40 Chloroform 83 9.773 9.774 -0.001 94 137759 1.77 S 41 1,2-Dichloroethene, Total 61 10.000 ND 42 1,1,1-Trichloroethane 97 10.030 ND 43 Cyclohexane 84 10.046 ND Page 197 of 478 Report Date: 28-Nov-2017 09:30:40 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags 44 Carbon tetrachloride 117 10.238 ND 45 Isooctane 57 10.515 10.521 -0.006 100 1449166 6.68 46 Benzene 78 10.563 10.563 0.000 92 60673 0.4535 47 1,2-Dichloroethane 62 10.659 ND 48 n-Heptane 43 10.771 10.771 -0.001 1 19677 0.2373 M *50 1,4-Difluorobenzene 114 11.102 11.102 0.000 94 1819209 10.0 53 Trichloroethene 95 11.476 ND 54 1,2-Dichloropropane 63 11.839 ND 55 Methyl methacrylate 69 11.876 ND 56 1,4-Dioxane 88 11.967 ND 58 Dichlorobromomethane 83 12.202 ND 60 cis-1,3-Dichloropropene 75 12.826 ND 61 4-Methyl-2-pentanone (MIBK 43 12.976 ND 64 Toluene 92 13.258 13.259 -0.001 93 154631 1.68 66 trans-1,3-Dichloropropene 75 13.621 ND 67 1,1,2-Trichloroethane 83 13.888 ND 68 Tetrachloroethene 166 14.032 ND 69 2-Hexanone 43 14.150 ND 70 Chlorodibromomethane 129 14.449 ND 71 Ethylene Dibromide 107 14.646 ND * 72 Chlorobenzene-d5 117 15.212 15.212 0.000 84 1541512 10.0 73 Chlorobenzene 112 15.249 ND 74 Ethylbenzene 91 15.318 15.319 -0.001 98 2515217 12.5 76 m-Xylene & p-Xylene 106 15.462 15.468 -0.006 0 3802772 47.8 78 o-Xylene 106 15.980 15.975 0.005 99 1232225 15.6 S 77 Xylenes, Total 106 0 63.4 79 Styrene 104 16.002 ND 80 Bromoform 173 16.295 ND 81 Isopropylbenzene 105 16.391 16.391 0.000 1 50209 0.2246 M 83 1,1,2,2-Tetrachloroethane 83 16.797 ND 84 N-Propylbenzene 91 16.871 16.871 0.005 1 29960 0.1087 M 87 4-Ethyltoluene 105 16.994 16.994 0.000 1 21393 0.0976 M 88 2-Chlorotoluene 91 17.037 ND 89 1,3,5-Trimethylbenzene 105 17.058 17.058 0.000 1 17610 0.0972 M 91 tert-Butylbenzene 119 17.437 ND 92 1,2,4-Trimethylbenzene 105 17.506 17.507 -0.001 98 45195 0.2524 93 sec-Butylbenzene 105 17.694 ND 94 4-Isopropyltoluene 119 17.848 17.848 0.005 1 2980 0.0133 7 95 1,3-Dichlorobenzene 146 17.923 ND 96 1,4-Dichlorobenzene 146 18.035 ND 97 Benzyl chloride 91 18.185 ND 99 n-Butylbenzene 91 18.350 ND 100 1,2-Dichlorobenzene 146 18.521 ND 103 1,2,4-Trichlorobenzene 180 20.880 ND 104 Hexachlorobutadiene 225 21.045 ND 105 Naphthalene 128 21.360 21.360 0.000 1 3643 0.0248 7 Page 198 of 478 Report Date: 28-Nov-2017 09:30:40 Chrom Revision: 2.2 13-Nov-2017 17:19:06 QC Flag Legend Processing Flags 7 - Failed Limit of Detection Review Flags M - Manually Integrated Reagents: ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 199 of 478 Report Date: 28-Nov-2017 09:30:40 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Tentatively Identified Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Lims ID:200-41113-A-2 Client ID:SV-2 Sample Type:Client Inject. Date:24-Nov-2017 16:40:30 ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Sample Info:200-0028034-009 Misc. Info.:41113-02 Operator ID:VTP Instrument ID:CHB.i Method:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:28-Nov-2017 09:30:39 Calib Date:07-Nov-2017 01:49:30 Tic RT Window:0.000 -0.000 Response:area Quant By:Nearest ISTD Quant LOD:10.00000 MS Library:\\ChromNA\Burlington\Database\NIST14.L Min. Match:1 Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: puangmaleek Date:28-Nov-2017 09:30:39 Tentative Identified Compound Results RT Area Amount ppb v/v Quant Cpnd Qual Lib Entry Molecular Formula Mol. Weight Flags 638-04-0 Cyclohexane, 1,3-dimethyl-, cis- 13.034 6214673 16.1 50 97 6931 C8H16 112 2207-04-7 Cyclohexane, 1,4-dimethyl-, trans- 13.717 4057895 9.00 72 97 6940 C8H16 112 1839-63-0 Cyclohexane, 1,3,5-trimethyl- 14.262 3813965 8.46 72 97 11834 C9H18 126 1678-91-7 Cyclohexane, ethyl- 14.390 4950998 11.0 72 95 6791 C8H16 112 3073-66-3 Cyclohexane, 1,1,3-trimethyl- 14.443 7728441 17.1 72 94 11835 C9H18 126 Unknown 14.678 7130703 15.8 72 0 0 0 7667-60-9 Cyclohexane, 1,2,4-trimethyl-,(1.alpha.,2.beta.,4.beta.)- 14.758 6256474 13.9 72 94 11870 C9H18 126 2216-33-3 Octane, 3-methyl- 14.843 6327568 14.0 72 90 12944 C9H20 128 2234-75-5 Cyclohexane, 1,2,4-trimethyl- 15.276 3938376 8.73 72 93 11819 C9H18 126 Unknown 15.847 3975620 8.82 72 0 0 0 Page 200 of 478 Report Date: 28-Nov-2017 09:30:40 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Quantitation Compounds Compound RT Area Amount ppb v/v *50 1,4-Difluorobenzene 11.102 3866151 10.0 * 72 Chlorobenzene-d5 15.212 4509544 10.0 QC Flag Legend Processing Flags Reagents: ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 201 of 478 Y ( X 1 0 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 9 . 6 9 9 ) * 1 , 4 - D i f l u o r o b e n z e n e ( 1 1 . 1 0 2 ) * C h l o r o b e n z e n e - d 5 ( 1 5 . 2 1 2 ) Report Date: 28-Nov-2017 09:30:40 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 6 Butane, CAS: 106-97-8 37 41 45 49 53 57m/z 0 2 4 6 8 10 12 14 Raw Spec:Scan 138(3.72) 43 41 583944 37 41 45 49 53 57m/z 0 2 4 6 8 10 12 14 Enhanced Spec:Scan 138(3.72),Qvalue=98 43 41 5839 44 37 41 45 49 53 57m/z 0 2 4 6 8 10 Ref Spec: 6 Butane (DATA) 43 41 39 58 37 41 45 49 53 57m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 138 @ 3.716 min.(Qvalue: 98) 41 5842 3.2 3.5 3.8 4.1Min 0 2 4 6 8 10 12 14 m/z 43.0 3.1 3.4 3.7 4.0Min 0 2 4 6 8 10 12 14 m/z 41.0 3.2 3.5 3.8 4.1Min 0 3 6 9 12 15 18 m/z 58.0 3.1 3.4 3.7 4.0 4.3Min 0 3 6 9 12 15 m/z 43.0 m/z 41.0 m/z 58.0 Page 203 of 478 Report Date: 28-Nov-2017 09:30:40 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 8 Butadiene, CAS: 106-99-0 36 40 44 48 52 56m/z 0 2 4 6 8 10 Raw Spec:Scan 156(3.81) 57 39 54 53 41 44 51 49 5538 36 40 44 48 52 56m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 156(3.81),Qvalue=96 5439 53 51 4938 55 36 40 44 48 52 56m/z 0 2 4 6 8 10 Ref Spec: 8 Butadiene (DATA) 39 54 53 50 51 4938 36 40 44 48 52 56m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 3.810 min.(Qvalue: 96) 51 54 3.3 3.6 3.9 4.2Min 0 12 24 36 48 60 72 84 m/z 54.0 Page 204 of 478 Report Date: 28-Nov-2017 09:30:41 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 21 Acetone, CAS: 67-64-1 36 40 44 48 52 56 60m/z 0 3 6 9 12 15 18 21 24 Raw Spec:Scan 653(6.46) 43 5844 42 36 40 44 48 52 56 60m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 653(6.46),Qvalue=96 43 58 42 36 40 44 48 52 56 60m/z 0 2 4 6 8 10 Ref Spec: 21 Acetone (NIST) 43 58 42 36 40 44 48 52 56 60m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 6.470 min.(Qvalue: 96) 58 5.9 6.2 6.5 6.8Min 0 3 6 9 12 15 18 21 24 m/z 43.0 5.9 6.2 6.5 6.8Min 0 12 24 36 48 60 72 84 m/z 58.0 5.9 6.2 6.5 6.8Min 0 4 8 12 16 20 24 m/z 43.0 m/z 58.0 Page 205 of 478 Report Date: 28-Nov-2017 09:30:41 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 23 Carbon disulfide, CAS: 75-15-0 38 42 46 50 54 58 62 66 70 74 78m/z 0 9 18 27 36 45 54 63 Raw Spec:Scan 706(6.75) 76 44 38 42 46 50 54 58 62 66 70 74 78m/z 0 2 4 6 8 10 Amdis Enhanced Spec: Scan 706(6.75),Qvalue=98 76 44 67 68 38 42 46 50 54 58 62 66 70 74 78m/z 0 2 4 6 8 10 Ref Spec: 23 Carbon disulfide (NIST) 76 44 38 42 46 50 54 58 62 66 70 74 78m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 6.730 min.(Qvalue: 98) 67 78 6.2 6.5 6.8 7.1Min 0 9 18 27 36 45 54 63 m/z 76.0 Page 206 of 478 Report Date: 28-Nov-2017 09:30:41 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 32 Hexane, CAS: 110-54-3 37 41 45 49 53 57 61 65 69 73 77 81 85m/z 0 2 4 6 8 10 12 14 16 Raw Spec:Scan 943(8.01) 43 41 57 7256 865544 37 41 45 49 53 57 61 65 69 73 77 81 85m/z 0 2 4 6 8 10 12 14 16 Amdis Enhanced Spec: Scan 943(8.01),Qvalue=80 43 41 57 56 8655 37 41 45 49 53 57 61 65 69 73 77 81 85m/z 0 2 4 6 8 10 Ref Spec: 32 Hexane (NIST) 57 43 56 86 55 37 41 45 49 53 57 61 65 69 73 77 81 85m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 8.020 min.(Qvalue: 80) 43 7.5 7.8 8.1 8.4Min 0 12 24 36 48 60 72 84 96 m/z 57.0 7.5 7.8 8.1 8.4Min 0 3 6 9 12 15 18 m/z 86.0 7.5 7.8 8.1 8.4Min 0 14 28 42 56 70 84 m/z 57.0 m/z 86.0 Page 207 of 478 Report Date: 28-Nov-2017 09:30:41 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 36 2-Butanone (MEK), CAS: 78-93-3 30 50 70 90 110 130 150m/z 0 8 16 24 32 40 48 56 Raw Spec:Scan 1189(9.32) 43 72 5742 30 50 70 90 110 130 150m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 1189(9.32),Qvalue=100 43 72 5742 30 50 70 90 110 130 150m/z 0 2 4 6 8 10 Ref Spec: 36 2-Butanone (MEK)(DATA) 43 72 57 30 50 70 90 110 130 150m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 9.320 min.(Qvalue:100) 42 72 8.8 9.1 9.4 9.7Min 0 3 6 9 12 15 m/z 72.0 8.8 9.1 9.4 9.7Min 0 8 16 24 32 40 48 56 m/z 43.0 8.8 9.1 9.4 9.7Min 0 9 18 27 36 45 54 m/z 72.0 m/z 43.0 Page 208 of 478 Report Date: 28-Nov-2017 09:30:41 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 40 Chloroform, CAS: 67-66-3 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119123127m/z 0 7 14 21 28 35 42 49 56 Raw Spec:Scan 1273(9.77) 83 85 47 8748 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119123127m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 1273(9.77),Qvalue=94 83 85 47 8748 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119123127m/z 0 13 26 39 52 65 78 91 Ref Spec: 40 Chloroform (NIST) 83 85 47 48 8782 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119123127m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 9.770 min.(Qvalue: 94) 9.2 9.5 9.8 10.1Min 0 7 14 21 28 35 42 49 56 m/z 83.0 9.2 9.5 9.8 10.1Min 0 5 10 15 20 25 30 35 m/z 85.0 9.2 9.5 9.8 10.1Min 0 8 16 24 32 40 48 56 m/z 83.0 m/z 85.0 Page 209 of 478 Report Date: 28-Nov-2017 09:30:41 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 45 Isooctane, CAS: 540-84-1 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101m/z 0 6 12 18 24 30 36 42 Raw Spec:Scan 1412(10.52) 57 56 41 43 99 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 1412(10.52),Qvalue=100 57 56 41 43 99 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101m/z 0 2 4 6 8 10 Ref Spec: 45 Isooctane (NIST) 57 56 41 43 99 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 10.520 min.(Qvalue:100) 10.0 10.3 10.6 10.9Min 0 6 12 18 24 30 36 42 m/z 57.0 10.0 10.3 10.6 10.9Min 0 12 24 36 48 60 72 84 96 m/z 41.0 10.0 10.3 10.6 10.9Min 0 10 20 30 40 50 60 70 m/z 43.0 10.0 10.3 10.6 10.9Min 0 7 14 21 28 35 42 m/z 57.0 m/z 41.0 m/z 43.0 Page 210 of 478 Report Date: 28-Nov-2017 09:30:41 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 46 Benzene, CAS: 71-43-2 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100m/z 0 7 14 21 28 35 42 49 Raw Spec:Scan 1421(10.56) 57 78 56 41 43 7752 99 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 1421(10.56),Qvalue=92 78 77 52 76 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100m/z 0 2 4 6 8 10 Ref Spec: 46 Benzene (DATA) 78 775152 7974 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 10.560 min.(Qvalue: 92) 10.0 10.3 10.6 10.9Min 0 4 8 12 16 20 24 m/z 78.0 10.0 10.3 10.6 10.9Min 0 8 16 24 32 40 48 56 m/z 77.0 10.0 10.3 10.6 10.9Min 0 4 8 12 16 20 24 m/z 78.0 m/z 77.0 Page 211 of 478 Report Date: 28-Nov-2017 09:30:41 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 48 n-Heptane, CAS: 142-82-5 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99m/z 0 10 20 30 40 50 60 70 80 Raw Spec:Scan 1460(10.77) 43 71 57 56 704455 10058 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99m/z 0 10 20 30 40 50 60 70 80 Enhanced Spec:Scan 1460(10.77),Qvalue=1 43 71 57 56 704455 10058 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99m/z 0 2 4 6 8 10 Ref Spec: 48 n-Heptane (NIST) 43 57 71 56 70 10055 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1460 @ 10.771 min.(Qvalue: 1) 714458 10.2 10.5 10.8 11.1Min -1 2 5 8 11 14 m/z 43.0 10.2 10.5 10.8 11.1Min -1 6 13 20 27 34 41 48 m/z 71.0 10.2 10.5 10.8 11.1Min 0 11 22 33 44 55 66 m/z 43.0 m/z 71.0 Page 212 of 478 Report Date: 28-Nov-2017 09:30:41 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 64 Toluene, CAS: 108-88-3 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 3 6 9 12 15 18 Raw Spec:Scan 1926(13.26) 43 9185 57 927156 8465 114 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 1926(13.26),Qvalue=93 91 92 65 8351 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 2 4 6 8 10 Ref Spec: 64 Toluene (NIST) 91 92 6551 93 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 13.260 min.(Qvalue: 93) 83 12.7 13.0 13.3 13.6Min 0 9 18 27 36 45 54 63 m/z 92.0 12.7 13.0 13.3 13.6Min 0 2 4 6 8 10 12 m/z 91.0 12.7 13.0 13.3 13.6Min 0 2 4 6 8 10 12 m/z 92.0 m/z 91.0 Page 213 of 478 Report Date: 28-Nov-2017 09:30:41 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 74 Ethylbenzene, CAS: 100-41-4 30 50 70 90 110 130 150 170 190 210m/z 0 2 4 6 8 10 12 Raw Spec:Scan 2312(15.32) 91 106 51 55 77 78 105 30 50 70 90 110 130 150 170 190 210m/z 0 2 4 6 8 10 12 Enhanced Spec:Scan 2312(15.32),Qvalue=98 91 106 51 55 77 78 105 30 50 70 90 110 130 150 170 190 210m/z 0 2 4 6 8 10 Ref Spec: 74 Ethylbenzene (NIST) 91 106 51 65 77 78 105 30 50 70 90 110 130 150 170 190 210m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 2312 @ 15.318 min.(Qvalue: 98) 5543 106 14.8 15.1 15.4 15.7Min 0 5 10 15 20 25 30 35 m/z 91.0 14.8 15.1 15.4 15.7Min 0 3 6 9 12 15 18 m/z 106.0 14.8 15.1 15.4 15.7Min 0 6 12 18 24 30 36 m/z 91.0 m/z 106.0 Page 214 of 478 Report Date: 28-Nov-2017 09:30:41 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 76 m-Xylene & p-Xylene, CAS: 179601-23-1 30 50 70 90 110 130 150 170 190 210m/z 0 5 10 15 20 25 30 35 Raw Spec:Scan 2339(15.46) 91 106 105 7751 7965 30 50 70 90 110 130 150 170 190 210m/z 0 5 10 15 20 25 30 35 Enhanced Spec:Scan 2339(15.46),Qvalue=0 91 106 105 7751 7965 14.9 15.2 15.5 15.8Min 0 3 6 9 12 15 18 m/z 106.0 14.9 15.2 15.5 15.8Min 0 5 10 15 20 25 30 35 m/z 91.0 14.9 15.2 15.5 15.8Min 0 6 12 18 24 30 36 m/z 106.0 m/z 91.0 Page 215 of 478 Report Date: 28-Nov-2017 09:30:42 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 78 o-Xylene, CAS: 95-47-6 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 2 4 6 8 10 12 14 Raw Spec:Scan 2436(15.98) 91 106 7751 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 10 20 30 40 50 60 70 Amdis Enhanced Spec: Scan 2436(15.98),Qvalue=99 91 106 57 77 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 2 4 6 8 10 Ref Spec: 78 o-Xylene (NIST) 91 106 7751 30 50 70 90 110 130 150 170 190 210 230 250m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 15.960 min.(Qvalue: 99) 57 15.4 15.7 16.0 16.3Min 0 2 4 6 8 10 m/z 106.0 15.4 15.7 16.0 16.3Min 0 3 6 9 12 15 18 21 m/z 91.0 15.4 15.7 16.0 16.3Min 0 3 6 9 12 15 18 21 m/z 106.0 m/z 91.0 Page 216 of 478 Report Date: 28-Nov-2017 09:30:42 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 81 Isopropylbenzene, CAS: 98-82-8 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 5 10 15 20 25 30 35 Raw Spec:Scan 2513(16.39) 57 10543 70 98 120 125 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 5 10 15 20 25 30 35 Enhanced Spec:Scan 2513(16.39),Qvalue=1 57 10543 70 98 120 125 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 2 4 6 8 10 Ref Spec: 81 Isopropylbenzene (NIST) 105 120777951 30 50 70 90 110 130 150 170 190 210 230 250m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 2513 @ 16.391 min.(Qvalue: 1) 57 43 70 98 15.8 16.1 16.4 16.7Min 0 7 14 21 28 35 42 49 m/z 105.0 15.8 16.1 16.4 16.7Min 0 9 18 27 36 45 54 63 72 m/z 120.0 15.8 16.1 16.4 16.7Min 0 3 6 9 12 15 m/z 77.0 15.8 16.1 16.4 16.7Min 0 5 10 15 20 25 m/z 105.0 m/z 120.0 m/z 77.0 Page 217 of 478 Report Date: 28-Nov-2017 09:30:42 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 92 1,2,4-Trimethylbenzene, CAS: 95-63-6 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 4 8 12 16 20 24 Raw Spec:Scan 2722(17.51) 105 120 57 77 121 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 2722(17.51),Qvalue=98 105 120 77 51 121 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 2 4 6 8 10 Ref Spec: 92 1,2,4-Trimethylbenzene (NIST) 105 120 77 30 50 70 90 110 130 150 170 190 210 230 250m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 17.510 min.(Qvalue: 98) 120 17.0 17.3 17.6 17.9Min 0 4 8 12 16 20 24 m/z 105.0 17.0 17.3 17.6 17.9Min 0 2 4 6 8 10 12 m/z 120.0 17.0 17.3 17.6 17.9Min 0 4 8 12 16 20 24 m/z 105.0 m/z 120.0 Page 218 of 478 Report Date: 28-Nov-2017 09:30:41 Chrom Revision: 2.2 13-Nov-2017 17:19:06Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 48 n-Heptane, CAS: 142-82-5Signal: 1 Processing Integration Results Not Detected Expected RT: 10.77 10.4 10.6 10.8 11.0Min 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 m/z 43.0 Manual Integration Results RT: 10.77 Area: 19677 Amount: 0.237259 Amount Units: ppb v/v 10.4 10.6 10.8 11.0Min -1 1 3 5 7 9 11 13 15 m/z 43.0 Reviewer: puangmaleek, 28-Nov-2017 09:26:30 Audit Action: Assigned Compound ID Audit Reason: Assign Peak Page 219 of 478 Report Date: 28-Nov-2017 09:30:41 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 48 n-Heptane, CAS: 142-82-5 Signal: 1 Processing Integration Results Not Detected Expected RT: 10.77 10.4 10.6 10.8 11.0Min 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 m/z 43.0 Manual Integration Results RT: 10.77 Area: 19677 Amount: 0.237259 Amount Units: ppb v/v 10.4 10.6 10.8 11.0Min -1 1 3 5 7 9 11 13 15 m/z 43.0 Reviewer: puangmaleek, 28-Nov-2017 09:26:43 Audit Action: Manually Integrated Audit Reason: Assign Peak Page 220 of 478 Report Date: 28-Nov-2017 09:30:41 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 48 n-Heptane, CAS: 142-82-5 Signal: 2 Processing Integration Results Not Detected Expected RT: 10.77 10.4 10.6 10.8 11.0Min 0 4 8 12 16 20 24 28 32 36 40 44 48 52 m/z 71.0 Manual Integration Results RT: 10.77 Area: 11033 Amount: 0.237259 Amount Units: ppb v/v 10.4 10.6 10.8 11.0Min -1 3 7 11 15 19 23 27 31 35 39 43 47 51 m/z 71.0 Reviewer: puangmaleek, 28-Nov-2017 09:26:56 Audit Action: Manually Integrated Audit Reason: Assign Peak Page 221 of 478 Report Date: 28-Nov-2017 09:30:42 Chrom Revision: 2.2 13-Nov-2017 17:19:06Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 81 Isopropylbenzene, CAS: 98-82-8Signal: 1 Processing Integration Results Not Detected Expected RT: 16.39 16.0 16.2 16.4 16.6Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 m/z 105.0 Manual Integration Results RT: 16.39 Area: 50209 Amount: 0.224564 Amount Units: ppb v/v 16.0 16.2 16.4 16.6Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 m/z 105.0 Reviewer: puangmaleek, 28-Nov-2017 09:27:50 Audit Action: Assigned Compound ID Audit Reason: Assign Peak Page 222 of 478 Report Date: 28-Nov-2017 09:30:42 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 81 Isopropylbenzene, CAS: 98-82-8 Signal: 1 Processing Integration Results Not Detected Expected RT: 16.39 16.0 16.2 16.4 16.6Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 m/z 105.0 Manual Integration Results RT: 16.39 Area: 50209 Amount: 0.224564 Amount Units: ppb v/v 16.0 16.2 16.4 16.6Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 m/z 105.0 Reviewer: puangmaleek, 28-Nov-2017 09:27:56 Audit Action: Manually Integrated Audit Reason: Assign Peak Page 223 of 478 Report Date: 28-Nov-2017 09:30:42 Chrom Revision: 2.2 13-Nov-2017 17:19:06Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 84 N-Propylbenzene, CAS: 103-65-1Signal: 1 Processing Integration Results Not Detected Expected RT: 16.87 16.5 16.7 16.9 17.1Min 0 2 4 6 8 10 12 14 16 m/z 91.0 Manual Integration Results RT: 16.87 Area: 29960 Amount: 0.108748 Amount Units: ppb v/v 16.5 16.7 16.9 17.1Min 0 2 4 6 8 10 12 14 16 m/z 91.0 Reviewer: puangmaleek, 28-Nov-2017 09:28:13 Audit Action: Assigned Compound ID Audit Reason: Assign Peak Page 224 of 478 Report Date: 28-Nov-2017 09:30:42 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 84 N-Propylbenzene, CAS: 103-65-1 Signal: 1 Processing Integration Results Not Detected Expected RT: 16.87 16.5 16.7 16.9 17.1Min 0 2 4 6 8 10 12 14 16 m/z 91.0 Manual Integration Results RT: 16.87 Area: 29960 Amount: 0.108748 Amount Units: ppb v/v 16.5 16.7 16.9 17.1Min 0 2 4 6 8 10 12 14 16 m/z 91.0 Reviewer: puangmaleek, 28-Nov-2017 09:28:18 Audit Action: Manually Integrated Audit Reason: Assign Peak Page 225 of 478 Report Date: 28-Nov-2017 09:30:42 Chrom Revision: 2.2 13-Nov-2017 17:19:06Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 87 4-Ethyltoluene, CAS: 622-96-8Signal: 1 Processing Integration Results Not Detected Expected RT: 16.99 16.7 16.9 17.1Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 m/z 105.0 Manual Integration Results RT: 16.99 Area: 21393 Amount: 0.097601 Amount Units: ppb v/v 16.7 16.9 17.1Min -1 1 3 5 7 9 11 13 15 17 19 21 23 25 27 m/z 105.0 Reviewer: puangmaleek, 28-Nov-2017 09:28:27 Audit Action: Assigned Compound ID Audit Reason: Assign Peak Page 226 of 478 Report Date: 28-Nov-2017 09:30:42 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 87 4-Ethyltoluene, CAS: 622-96-8 Signal: 1 Processing Integration Results Not Detected Expected RT: 16.99 16.7 16.9 17.1Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 m/z 105.0 Manual Integration Results RT: 16.99 Area: 21393 Amount: 0.097601 Amount Units: ppb v/v 16.7 16.9 17.1Min -1 1 3 5 7 9 11 13 15 17 19 21 23 25 27 m/z 105.0 Reviewer: puangmaleek, 28-Nov-2017 09:28:35 Audit Action: Manually Integrated Audit Reason: Assign Peak Page 227 of 478 Report Date: 28-Nov-2017 09:30:42 Chrom Revision: 2.2 13-Nov-2017 17:19:06Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 89 1,3,5-Trimethylbenzene, CAS: 108-67-8Signal: 1 Processing Integration Results Not Detected Expected RT: 17.06 16.7 16.9 17.1 17.3Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 m/z 105.0 Manual Integration Results RT: 17.06 Area: 17610 Amount: 0.097182 Amount Units: ppb v/v 16.7 16.9 17.1 17.3Min -1 1 3 5 7 9 11 13 15 17 19 21 23 25 27 m/z 105.0 Reviewer: puangmaleek, 28-Nov-2017 09:28:49 Audit Action: Assigned Compound ID Audit Reason: Assign Peak Page 228 of 478 Report Date: 28-Nov-2017 09:30:42 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 89 1,3,5-Trimethylbenzene, CAS: 108-67-8 Signal: 1 Processing Integration Results Not Detected Expected RT: 17.06 16.7 16.9 17.1 17.3Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 m/z 105.0 Manual Integration Results RT: 17.06 Area: 17610 Amount: 0.097182 Amount Units: ppb v/v 16.7 16.9 17.1 17.3Min -1 1 3 5 7 9 11 13 15 17 19 21 23 25 27 m/z 105.0 Reviewer: puangmaleek, 28-Nov-2017 09:28:53 Audit Action: Manually Integrated Audit Reason: Assign Peak Page 229 of 478 Report Date: 28-Nov-2017 09:30:42 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Cyclohexane,1,3-dimethyl-,cis-638-04-0 NIST14.L 6931 C8H16 112 97 Cyclohexane,1,3-dimethyl-591-21-9 NIST14.L 6866 C8H16 112 91 Cyclohexane,1,4-dimethyl-589-90-2 NIST14.L 6863 C8H16 112 91 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 10 20 30 40 50 Raw Spec: Scan 1884(13.03) 97 55 11241695642709883 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 10 20 30 40 50 28034-09[MS SCAN Spec]:Scan 1884(13.03) 97 55 11241695642709883 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 18 36 54 72 90 Entry #6931, Cyclohexane, 1,3-dimethyl-, cis- (from NIST14.L) 9755 41 112566942987053 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 18 36 54 72 90 Entry #6866, Cyclohexane, 1,3-dimethyl- (from NIST14.L) 9755 41 112695642709853 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 18 36 54 72 90 Entry #6863, Cyclohexane, 1,4-dimethyl- (from NIST14.L) 55 97 112415669427083969884 Page 230 of 478 Report Date: 28-Nov-2017 09:30:43 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Cyclohexane,1,4-dimethyl-,trans-2207-04-7 NIST14.L 6940 C8H16 112 97 Cyclohexane,1,4-dimethyl-589-90-2 NIST14.L 6869 C8H16 112 95 Cyclohexane,1,4-dimethyl-,cis-624-29-3 NIST14.L 6922 C8H16 112 94 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 6 12 18 24 Raw Spec: Scan 2012(13.72) 9755 11256416942709683988453 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 6 12 18 24 28034-09[MS SCAN Spec]:Scan 2012(13.72) 9755 11256416942709683988453 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 18 36 54 72 90 Entry #6940, Cyclohexane, 1,4-dimethyl-, trans- (from NIST14.L) 55 97 41 112 56 6942 967083 985384 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 18 36 54 72 90 Entry #6869, Cyclohexane, 1,4-dimethyl- (from NIST14.L) 55 97 41 1125669427096538398 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 18 36 54 72 90 Entry #6922, Cyclohexane, 1,4-dimethyl-, cis- (from NIST14.L) 55 97 41 112564269708396849853 Page 231 of 478 Report Date: 28-Nov-2017 09:30:43 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Cyclohexane,1,3,5-trimethyl-1839-63-0 NIST14.L 11834 C9H18 126 97 Cyclohexane,1,3,5-trimethyl-,(1.alpha.,3.alpha 1795-27-3 NIST14.L 11879 C9H18 126 94 Cyclohexane,1,3,5-trimethyl-,(1.alpha.,3.alpha 1795-26-2 NIST14.L 11876 C9H18 126 60 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125 129m/z 0 7 14 21 28 Raw Spec: Scan 2114(14.26) 69 111 55 41 126567068421128384 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125 129m/z 0 7 14 21 28 28034-09[MS SCAN Spec]:Scan 2114(14.26) 69 111 55 41 126567068421128384 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125 129m/z 0 18 36 54 72 90 Entry #11834, Cyclohexane, 1,3,5-trimethyl- (from NIST14.L) 11169 55 41 12656704311283 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125 129m/z 0 18 36 54 72 90 Entry #11879, Cyclohexane, 1,3,5-trimethyl-,(1.alpha.,3.alpha.,5.alpha.)- (from NIST14.L) 69 111 55 41 126 5642 7067 11253 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125 129m/z 0 18 36 54 72 90 Entry #11876, Cyclohexane, 1,3,5-trimethyl-,(1.alpha.,3.alpha.,5.beta.)- (from NIST14.L) 69 1115541 12642567053831126784 Page 232 of 478 Report Date: 28-Nov-2017 09:30:43 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Cyclohexane,ethyl-1678-91-7 NIST14.L 6791 C8H16 112 95 3,4-Dimethyl-2-hexene 2213-37-8 NIST14.L 6819 C8H16 112 76 Cyclohexane,propyl-1678-92-8 NIST14.L 11775 C9H18 126 64 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112 116 120 124 128m/z 0 10 20 30 40 50 Raw Spec: Scan 2138(14.39) 8355 82 41 11256676984429754 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112 116 120 124 128m/z 0 10 20 30 40 50 28034-09[MS SCAN Spec]:Scan 2138(14.39) 8355 82 41 11256676984429754 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112 116 120 124 128m/z 0 18 36 54 72 90 Entry #6791, Cyclohexane, ethyl- (from NIST14.L) 83 55 82 41 1125667426984 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112 116 120 124 128m/z 0 18 36 54 72 90 Entry #6819, 3,4-Dimethyl-2-hexene (from NIST14.L) 55 83 41 112436984565397 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112 116 120 124 128m/z 0 18 36 54 72 90 Entry #11775, Cyclohexane, propyl- (from NIST14.L) 83 55 82 41 126675669844354 Page 233 of 478 Report Date: 28-Nov-2017 09:30:44 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Cyclohexane,1,1,3-trimethyl-3073-66-3 NIST14.L 11835 C9H18 126 94 Cyclohexane,1,3,5-trimethyl-,(1.alpha.,3.alpha 1795-27-3 NIST14.L 11878 C9H18 126 64 Cyclohexane,1,2,4-trimethyl-2234-75-5 NIST14.L 11819 C9H18 126 50 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125 129m/z 0 12 24 36 48 60 Raw Spec: Scan 2148(14.44) 11169 55 41 56 837043 84 112976753 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125 129m/z 0 12 24 36 48 60 28034-09[MS SCAN Spec]:Scan 2148(14.44) 11169 55 41 56 837043 84 112976753 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125 129m/z 0 18 36 54 72 90 Entry #11835, Cyclohexane, 1,1,3-trimethyl- (from NIST14.L) 111 69 5541 83564370 1125367 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125 129m/z 0 18 36 54 72 90 Entry #11878, Cyclohexane, 1,3,5-trimethyl-,(1.alpha.,3.alpha.,5.alpha.)- (from NIST14.L) 11169 55 41 1264256701125367 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125 129m/z 0 18 36 54 72 90 Entry #11819, Cyclohexane, 1,2,4-trimethyl- (from NIST14.L) 69 111 55 41 1265670844367539711257 Page 234 of 478 Report Date: 28-Nov-2017 09:30:44 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Unknown Octane,4-methyl-2216-34-4 NIST14.L 12942 C9H20 128 72 Hexane,3-ethyl-619-99-8 NIST14.L 7761 C8H18 114 64 Octane,2-methyl-3221-61-2 NIST14.L 12950 C9H20 128 64 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 15 30 45 60 75 Raw Spec: Scan 2192(14.68) 43 57 71 8541705639 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 15 30 45 60 75 28034-09[MS SCAN Spec]:Scan 2192(14.68) 43 57 71 8541705639 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #12942, Octane, 4-methyl- (from NIST14.L) 43 85714157 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #7761, Hexane, 3-ethyl- (from NIST14.L) 43 85417157 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #12950, Octane, 2-methyl- (from NIST14.L) 43 57 71 8541 56 1133969 128 Page 235 of 478 Report Date: 28-Nov-2017 09:30:44 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Cyclohexane,1,2,4-trimethyl-,(1.alpha.,2.beta.7667-60-9 NIST14.L 11870 C9H18 126 94 Cyclohexane,1,3,5-trimethyl-,(1.alpha.,3.alpha 1795-26-2 NIST14.L 11876 C9H18 126 90 Cyclohexane,1,2,4-trimethyl-2234-75-5 NIST14.L 11829 C9H18 126 90 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 11 22 33 44 55 Raw Spec: Scan 2207(14.76) 11169 55 126415670438411297 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 11 22 33 44 55 28034-09[MS SCAN Spec]:Scan 2207(14.76) 11169 55 126415670438411297 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #11870, Cyclohexane, 1,2,4-trimethyl-,(1.alpha.,2.beta.,4.beta.)- (from NIST14.L) 69 111 55 41 126395670428411297 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #11876, Cyclohexane, 1,3,5-trimethyl-,(1.alpha.,3.alpha.,5.beta.)- (from NIST14.L) 69 1115541 39 12642567083112 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #11829, Cyclohexane, 1,2,4-trimethyl- (from NIST14.L) 6955 11141 5643 126397084976753112 Page 236 of 478 Report Date: 28-Nov-2017 09:30:44 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Octane,3-methyl-2216-33-3 NIST14.L 12944 C9H20 128 90 Heptane,2,5-dimethyl-2216-30-0 NIST14.L 12977 C9H20 128 72 Heptane,4-(1-methylethyl)-52896-87-4 NIST14.L 19714 C10H22 142 59 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 2 4 6 8 10 Raw Spec: Scan 2223(14.84) 57 43 56 98 9971 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 2 4 6 8 10 28034-09[MS SCAN Spec]:Scan 2223(14.84) 57 43 56 98 9971 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #12944, Octane, 3-methyl- (from NIST14.L) 57 43 56 98 9971 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #12977, Heptane, 2,5-dimethyl- (from NIST14.L) 57 43 56 71 99 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #19714, Heptane, 4-(1-methylethyl)- (from NIST14.L) 57 43 98563969 9970 Page 237 of 478 Report Date: 28-Nov-2017 09:30:44 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Cyclohexane,1,2,4-trimethyl-2234-75-5 NIST14.L 11819 C9H18 126 93 Cyclohexane,1,2,3-trimethyl-,(1.alpha.,2.beta.1678-81-5 NIST14.L 11873 C9H18 126 93 Cyclohexane,1,1,2-trimethyl-7094-26-0 NIST14.L 11825 C9H18 126 74 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 6 12 18 24 30 Raw Spec: Scan 2304(15.28) 69 11155 5641 70 126824339975771112 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 6 12 18 24 30 28034-09[MS SCAN Spec]:Scan 2304(15.28) 69 11155 5641 70 126824339975771112 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 18 36 54 72 90 Entry #11819, Cyclohexane, 1,2,4-trimethyl- (from NIST14.L) 69 111 55 41 12656397084436797112 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 18 36 54 72 90 Entry #11873, Cyclohexane, 1,2,3-trimethyl-,(1.alpha.,2.beta.,3.alpha.)- (from NIST14.L) 69 55 11141 56 70 126833943678297112 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 18 36 54 72 90 Entry #11825, Cyclohexane, 1,1,2-trimethyl- (from NIST14.L) 69 41 56 111 39 57 7043 126836798 Page 238 of 478 Report Date: 28-Nov-2017 09:30:45 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-09.D Injection Date:24-Nov-2017 16:40:30 Instrument ID:CHB.i Lims ID:200-41113-A-2 Lab Sample ID:200-41113-2 Client ID:SV-2 Operator ID:VTP ALS Bottle#:9 Worklist Smp#:38 Purge Vol:200.000 mL Dil. Factor:2.9800 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Unknown 2-Hexene,3,4,4-trimethyl-53941-19-8 NIST14.L 11806 C9H18 126 81 Cyclohexane,1-ethyl-2-methyl-3728-54-9 NIST14.L 11840 C9H18 126 80 1-Ethyl-4-methylcyclohexane 3728-56-1 NIST14.L 11812 C9H18 126 76 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 5 10 15 20 25 Raw Spec: Scan 2411(15.85) 9755 6941 1267043579698 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 5 10 15 20 25 28034-09[MS SCAN Spec]:Scan 2411(15.85) 9755 6941 1267043579698 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #11806, 2-Hexene, 3,4,4-trimethyl- (from NIST14.L) 9755 41 69 4339 1265798 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #11840, Cyclohexane, 1-ethyl-2-methyl- (from NIST14.L) 9755 41 69 96 126984270 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #11812, 1-Ethyl-4-methylcyclohexane (from NIST14.L) 9755 41 69 12696984381 Page 239 of 478 Page 240 of 478 Page 241 of 478 Page 242 of 478 Page 243 of 478 Page 244 of 478 Page 245 of 478 Page 246 of 478 Report Date: 28-Nov-2017 09:36:53 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Lims ID:200-41113-A-3 Client ID:SV-1 Sample Type:Client Inject. Date:24-Nov-2017 17:32:30 ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Sample Info:200-0028034-010 Misc. Info.:41113-03 Operator ID:VTP Instrument ID:CHB.i Method:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:28-Nov-2017 09:36:51 Calib Date:07-Nov-2017 01:49:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal/External Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: puangmaleek Date:28-Nov-2017 09:36:50 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags 2 Dichlorodifluoromethane 85 3.199 3.193 0.006 98 12364 0.1476 3 Chlorodifluoromethane 51 3.231 3.225 0.006 95 3964 0.0832 4 1,2-Dichloro-1,1,2,2-tetra 85 3.412 ND 5 Chloromethane 50 3.535 3.535 0.000 25 2428 0.0813 7 6 Butane 43 3.711 3.711 0.000 99 912847 17.7 7 Vinyl chloride 62 3.748 ND 8 Butadiene 54 3.812 3.812 0.000 95 34572 1.31 10 Bromomethane 94 4.479 ND 11 Chloroethane 64 4.709 ND 13 Vinyl bromide 106 5.120 ND 14 Trichlorofluoromethane 101 5.227 5.227 0.011 1 5564 0.0623 7M 19 1,1,2-Trichloro-1,2,2-trif 101 6.246 ND 20 1,1-Dichloroethene 96 6.315 ND 21 Acetone 43 6.475 6.465 0.010 96 170872 3.04 22 Isopropyl alcohol 45 6.683 ND 23 Carbon disulfide 76 6.742 6.748 -0.006 100 220512 2.09 24 3-Chloro-1-propene 41 7.014 ND 27 Methylene Chloride 49 7.271 7.271 -0.005 15 2704 0.0600 7 28 2-Methyl-2-propanol 59 7.383 ND 29 Methyl tert-butyl ether 73 7.623 ND 30 trans-1,2-Dichloroethene 61 7.687 ND 32 Hexane 57 8.018 8.012 0.006 95 41999 0.6120 33 1,1-Dichloroethane 63 8.423 ND 36 2-Butanone (MEK) 72 9.320 9.315 0.005 99 12573 0.5681 37 cis-1,2-Dichloroethene 96 9.331 ND * 39 Chlorobromomethane 128 9.694 9.699 -0.005 92 378133 10.0 38 Tetrahydrofuran 42 9.710 ND 40 Chloroform 83 9.768 9.774 -0.006 94 74318 0.9119 S 41 1,2-Dichloroethene, Total 61 10.000 ND 42 1,1,1-Trichloroethane 97 10.030 ND 43 Cyclohexane 84 10.046 10.046 0.000 96 17415 0.2926 Page 247 of 478 Report Date: 28-Nov-2017 09:36:53 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags 44 Carbon tetrachloride 117 10.227 10.227 -0.011 1 893 0.0119 7 45 Isooctane 57 10.521 ND 46 Benzene 78 10.558 10.563 -0.005 94 89132 0.6415 47 1,2-Dichloroethane 62 10.659 ND 48 n-Heptane 43 10.772 10.772 0.000 92 25642 0.2977 * 50 1,4-Difluorobenzene 114 11.103 11.102 0.001 94 1889521 10.0 53 Trichloroethene 95 11.476 ND 54 1,2-Dichloropropane 63 11.839 ND 55 Methyl methacrylate 69 11.876 ND 56 1,4-Dioxane 88 11.967 ND 58 Dichlorobromomethane 83 12.197 12.202 -0.005 63 9280 0.0994 60 cis-1,3-Dichloropropene 75 12.826 ND 61 4-Methyl-2-pentanone (MIBK 43 12.976 ND 64 Toluene 92 13.253 13.259 -0.006 93 169137 1.77 66 trans-1,3-Dichloropropene 75 13.621 ND 67 1,1,2-Trichloroethane 83 13.888 ND 68 Tetrachloroethene 166 14.032 ND 69 2-Hexanone 43 14.150 ND 70 Chlorodibromomethane 129 14.449 ND 71 Ethylene Dibromide 107 14.646 ND * 72 Chlorobenzene-d5 117 15.212 15.212 0.000 84 1601689 10.0 73 Chlorobenzene 112 15.249 ND 74 Ethylbenzene 91 15.319 15.319 0.000 98 765899 3.65 76 m-Xylene & p-Xylene 106 15.463 15.468 -0.005 0 1178281 14.3 78 o-Xylene 106 15.975 15.975 0.000 99 397596 4.84 S 77 Xylenes, Total 106 0 19.1 79 Styrene 104 16.002 ND 80 Bromoform 173 16.295 ND 81 Isopropylbenzene 105 16.386 16.391 -0.005 87 31875 0.1372 83 1,1,2,2-Tetrachloroethane 83 16.797 ND 84 N-Propylbenzene 91 16.866 16.866 0.000 1 32379 0.1131 M 87 4-Ethyltoluene 105 16.989 16.994 -0.005 76 32067 0.1408 88 2-Chlorotoluene 91 17.037 ND 89 1,3,5-Trimethylbenzene 105 17.059 17.059 0.001 65 23905 0.1270 M 91 tert-Butylbenzene 119 17.437 ND 92 1,2,4-Trimethylbenzene 105 17.502 17.507 -0.005 98 69360 0.3729 93 sec-Butylbenzene 105 17.688 17.688 -0.006 57 9362 0.0331 7 94 4-Isopropyltoluene 119 17.843 17.843 0.000 37 5701 0.0245 7 95 1,3-Dichlorobenzene 146 17.923 ND 96 1,4-Dichlorobenzene 146 18.035 ND 97 Benzyl chloride 91 18.185 ND 99 n-Butylbenzene 91 18.350 ND 100 1,2-Dichlorobenzene 146 18.521 ND 103 1,2,4-Trichlorobenzene 180 20.880 ND 104 Hexachlorobutadiene 225 21.045 ND 105 Naphthalene 128 21.365 21.365 0.005 1 4291 0.0281 7 Page 248 of 478 Report Date: 28-Nov-2017 09:36:53 Chrom Revision: 2.2 13-Nov-2017 17:19:06 QC Flag Legend Processing Flags 7 - Failed Limit of Detection Review Flags M - Manually Integrated Reagents: ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 249 of 478 Report Date: 28-Nov-2017 09:36:53 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Tentatively Identified Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Lims ID:200-41113-A-3 Client ID:SV-1 Sample Type:Client Inject. Date:24-Nov-2017 17:32:30 ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Sample Info:200-0028034-010 Misc. Info.:41113-03 Operator ID:VTP Instrument ID:CHB.i Method:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:28-Nov-2017 09:36:51 Calib Date:07-Nov-2017 01:49:30 Tic RT Window:0.000 -0.000 Response:area Quant By:Nearest ISTD Quant LOD:10.00000 MS Library:\\ChromNA\Burlington\Database\NIST14.L Min. Match:1 Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: puangmaleek Date:28-Nov-2017 09:36:50 Tentative Identified Compound Results RT Area Amount ppb v/v Quant Cpnd Qual Lib Entry Molecular Formula Mol. Weight Flags 75-28-5 Isobutane 3.439 890117 3.74 39 86 237 C4H10 58 624-29-3 Cyclohexane, 1,4-dimethyl-, cis- 13.035 2057499 5.17 50 91 6928 C8H16 112 2207-04-7 Cyclohexane, 1,4-dimethyl-, trans- 13.718 1201884 2.64 72 97 6940 C8H16 112 1678-91-7 Cyclohexane, ethyl- 14.385 1493783 3.28 72 95 6789 C8H16 112 3073-66-3 Cyclohexane, 1,1,3-trimethyl- 14.443 2172862 4.77 72 94 11835 C9H18 126 Unknown 14.673 2143465 4.70 72 0 0 0 7667-60-9 Cyclohexane, 1,2,4-trimethyl-,(1.alpha.,2.beta.,4.beta.)- 14.753 1620061 3.56 72 94 11871 C9H18 126 2216-33-3 Octane, 3-methyl- 14.838 1832983 4.02 72 90 12944 C9H20 128 1678-81-5 Cyclohexane, 1,2,3-trimethyl-,(1.alpha.,2.beta.,3.alpha.)- 15.271 1196910 2.63 72 93 11873 C9H18 126 Unknown 15.847 1445540 3.17 72 0 0 0 Page 250 of 478 Report Date: 28-Nov-2017 09:36:53 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Quantitation Compounds Compound RT Area Amount ppb v/v * 39 Chlorobromomethane 9.694 2377702 10.0 * 50 1,4-Difluorobenzene 11.097 3977074 10.0 * 72 Chlorobenzene-d5 15.212 4555972 10.0 QC Flag LegendProcessing Flags Reagents: ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 251 of 478 Y ( X 1 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 9 . 6 9 4 ) * 1 , 4 - D i f l u o r o b e n z e n e ( 1 1 . 0 9 7 ) * C h l o r o b e n z e n e - d 5 ( 1 5 . 2 1 2 ) Report Date: 28-Nov-2017 09:36:53 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 6 Butane, CAS: 106-97-8 35 39 43 47 51 55 59 63 67 71 75m/z 0 6 12 18 24 30 36 42 Raw Spec:Scan 137(3.71) 43 41 5839 35 39 43 47 51 55 59 63 67 71 75m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 137(3.71),Qvalue=99 43 41 5839 35 39 43 47 51 55 59 63 67 71 75m/z 0 2 4 6 8 10 Ref Spec: 6 Butane (DATA) 43 41 39 58 35 39 43 47 51 55 59 63 67 71 75m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 3.710 min.(Qvalue: 99) 5842 3.2 3.5 3.8 4.1Min 0 6 12 18 24 30 36 42 m/z 43.0 3.1 3.4 3.7 4.0Min 0 3 6 9 12 15 18 21 m/z 41.0 3.2 3.5 3.8 4.1Min 0 9 18 27 36 45 54 63 m/z 58.0 3.1 3.4 3.7 4.0 4.3Min 0 8 16 24 32 40 m/z 43.0 m/z 41.0 m/z 58.0 Page 253 of 478 Report Date: 28-Nov-2017 09:36:53 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 8 Butadiene, CAS: 106-99-0 30 50 70 90 110 130 150 170 190 210m/z 0 3 6 9 12 15 18 Raw Spec:Scan 156(3.81) 54 53 57 30 50 70 90 110 130 150 170 190 210m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 156(3.81),Qvalue=95 54 53 57 30 50 70 90 110 130 150 170 190 210m/z 0 2 4 6 8 10 Ref Spec: 8 Butadiene (DATA) 54 53 30 50 70 90 110 130 150 170 190 210m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 3.820 min.(Qvalue: 95) 57 54 3.3 3.6 3.9 4.2Min 0 3 6 9 12 15 18 m/z 54.0 Page 254 of 478 Report Date: 28-Nov-2017 09:36:53 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 23 Carbon disulfide, CAS: 75-15-0 30 50 70 90 110 130 150 170 190 210m/z 0 11 22 33 44 55 66 77 Raw Spec:Scan 705(6.74) 76 44 78 30 50 70 90 110 130 150 170 190 210m/z 0 11 22 33 44 55 66 77 Enhanced Spec:Scan 705(6.74),Qvalue=100 76 44 78 30 50 70 90 110 130 150 170 190 210m/z 0 2 4 6 8 10 Ref Spec: 23 Carbon disulfide (NIST) 76 44 78 30 50 70 90 110 130 150 170 190 210m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 705 @ 6.742 min.(Qvalue:100) 78 6.2 6.5 6.8 7.1Min 0 11 22 33 44 55 66 77 m/z 76.0 Page 255 of 478 Report Date: 28-Nov-2017 09:36:54 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 32 Hexane, CAS: 110-54-3 39 43 47 51 55 59 63 67 71 75 79 83 87m/z 0 2 4 6 8 10 12 14 Raw Spec:Scan 944(8.02) 57 43 56 86 55 71 72 39 43 47 51 55 59 63 67 71 75 79 83 87m/z 0 2 4 6 8 10 12 14 Enhanced Spec:Scan 944(8.02),Qvalue=95 57 43 56 86 55 71 72 39 43 47 51 55 59 63 67 71 75 79 83 87m/z 0 2 4 6 8 10 Ref Spec: 32 Hexane (NIST) 57 43 56 86 55 39 43 47 51 55 59 63 67 71 75 79 83 87m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 944 @ 8.018 min.(Qvalue: 95) 5641 86 7.5 7.8 8.1 8.4Min 0 2 4 6 8 10 12 14 m/z 57.0 7.5 7.8 8.1 8.4Min 0 4 8 12 16 20 24 m/z 86.0 7.5 7.8 8.1 8.4Min 0 3 6 9 12 15 m/z 57.0 m/z 86.0 Page 256 of 478 Report Date: 28-Nov-2017 09:36:54 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 36 2-Butanone (MEK), CAS: 78-93-3 39 43 47 51 55 59 63 67 71m/z 0 3 6 9 12 15 Raw Spec:Scan 1188(9.32) 43 72 57 39 43 47 51 55 59 63 67 71m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 1188(9.32),Qvalue=99 43 72 57 39 43 47 51 55 59 63 67 71m/z 0 2 4 6 8 10 Ref Spec: 36 2-Butanone (MEK)(DATA) 43 72 57 39 43 47 51 55 59 63 67 71m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 9.330 min.(Qvalue: 99) 7242 8.8 9.1 9.4 9.7Min 0 7 14 21 28 35 42 49 m/z 72.0 8.8 9.1 9.4 9.7Min 0 3 6 9 12 15 18 m/z 43.0 8.8 9.1 9.4 9.7Min 0 3 6 9 12 15 18 m/z 72.0 m/z 43.0 Page 257 of 478 Report Date: 28-Nov-2017 09:36:54 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 40 Chloroform, CAS: 67-66-3 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119123127m/z 0 4 8 12 16 20 24 28 Raw Spec:Scan 1272(9.77) 83 85 47 87498267 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119123127m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 1272(9.77),Qvalue=94 83 85 47 87488267 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119123127m/z 0 13 26 39 52 65 78 91 Ref Spec: 40 Chloroform (NIST) 83 85 47 48 8782 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119123127m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 9.770 min.(Qvalue: 94) 9.2 9.5 9.8 10.1Min 0 4 8 12 16 20 24 28 m/z 83.0 9.2 9.5 9.8 10.1Min 0 3 6 9 12 15 18 m/z 85.0 9.2 9.5 9.8 10.1Min 0 5 10 15 20 25 30 m/z 83.0 m/z 85.0 Page 258 of 478 Report Date: 28-Nov-2017 09:36:54 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 43 Cyclohexane, CAS: 110-82-7 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97m/z 0 13 26 39 52 65 78 91 Raw Spec:Scan 1324(10.05) 56 84 41 55 6943 57 67 83445471 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 1324(10.05),Qvalue=96 56 84 41 55 69 42 6754 83 85 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97m/z 0 2 4 6 8 10 Ref Spec: 43 Cyclohexane (NIST) 56 84 41 55 69 42 54 8583 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 10.040 min.(Qvalue: 96) 55 6942 9.5 9.8 10.1 10.4Min 0 8 16 24 32 40 48 56 m/z 84.0 9.5 9.8 10.1 10.4Min 0 13 26 39 52 65 78 91 m/z 56.0 9.5 9.8 10.1 10.4Min 0 14 28 42 56 70 84 98 m/z 84.0 m/z 56.0 Page 259 of 478 Report Date: 28-Nov-2017 09:36:55 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 46 Benzene, CAS: 71-43-2 36 40 44 48 52 56 60 64 68 72 76m/z 0 5 10 15 20 25 30 35 Raw Spec:Scan 1420(10.56) 78 77515239 36 40 44 48 52 56 60 64 68 72 76m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 1420(10.56),Qvalue=94 78 7752 39 76 36 40 44 48 52 56 60 64 68 72 76m/z 0 2 4 6 8 10 Ref Spec: 46 Benzene (DATA) 78 7751523974 36 40 44 48 52 56 60 64 68 72 76m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 10.560 min.(Qvalue: 94) 10.0 10.3 10.6 10.9Min 0 5 10 15 20 25 30 35 m/z 78.0 10.0 10.3 10.6 10.9Min 0 11 22 33 44 55 66 77 m/z 77.0 10.0 10.3 10.6 10.9Min 0 6 12 18 24 30 36 m/z 78.0 m/z 77.0 Page 260 of 478 Report Date: 28-Nov-2017 09:36:55 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 48 n-Heptane, CAS: 142-82-5 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99m/z 0 2 4 6 8 10 Raw Spec:Scan 1460(10.77) 43 71 57 56 70 1005544 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 1460(10.77),Qvalue=92 43 7157 56 70 1005544 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99m/z 0 2 4 6 8 10 Ref Spec: 48 n-Heptane (NIST) 43 57 71 56 70 10055 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 10.780 min.(Qvalue: 92) 71 10057 10.2 10.5 10.8 11.1Min 0 2 4 6 8 10 m/z 43.0 10.2 10.5 10.8 11.1Min 0 8 16 24 32 40 48 56 64 m/z 71.0 10.2 10.5 10.8 11.1Min 0 2 4 6 8 10 m/z 43.0 m/z 71.0 Page 261 of 478 Report Date: 28-Nov-2017 09:36:55 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 64 Toluene, CAS: 108-88-3 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 2 4 6 8 10 12 Raw Spec:Scan 1925(13.25) 91 43 92 855771 55 65 84 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 4 8 12 16 20 24 28 Amdis Enhanced Spec: Scan 1925(13.25),Qvalue=93 91 43 92 855771 56 65 84 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 2 4 6 8 10 Ref Spec: 64 Toluene (NIST) 91 92 6551 93 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 13.250 min.(Qvalue: 93) 43 855771 12.7 13.0 13.3 13.6Min 0 10 20 30 40 50 60 70 m/z 92.0 12.7 13.0 13.3 13.6Min 0 2 4 6 8 10 12 m/z 91.0 12.7 13.0 13.3 13.6Min 0 2 4 6 8 10 12 m/z 92.0 m/z 91.0 Page 262 of 478 Report Date: 28-Nov-2017 09:36:55 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 74 Ethylbenzene, CAS: 100-41-4 30 50 70 90 110 130 150 170 190 210m/z 0 5 10 15 20 25 30 35 40 Raw Spec:Scan 2312(15.32) 91 106 43 57 77 78 105 30 50 70 90 110 130 150 170 190 210m/z 0 5 10 15 20 25 30 35 40 Enhanced Spec:Scan 2312(15.32),Qvalue=98 91 106 43 57 77 78 105 30 50 70 90 110 130 150 170 190 210m/z 0 2 4 6 8 10 Ref Spec: 74 Ethylbenzene (NIST) 91 106 51 65 77 78 105 30 50 70 90 110 130 150 170 190 210m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 2312 @ 15.319 min.(Qvalue: 98) 43 57 106 14.8 15.1 15.4 15.7Min 0 2 4 6 8 10 12 m/z 91.0 14.8 15.1 15.4 15.7Min 0 8 16 24 32 40 48 56 m/z 106.0 14.8 15.1 15.4 15.7Min 0 2 4 6 8 10 12 m/z 91.0 m/z 106.0 Page 263 of 478 Report Date: 28-Nov-2017 09:36:55 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 76 m-Xylene & p-Xylene, CAS: 179601-23-1 30 50 70 90 110 130 150 170 190 210m/z 0 2 4 6 8 10 12 Raw Spec:Scan 2339(15.46) 91 106 105 7751 7965 30 50 70 90 110 130 150 170 190 210m/z 0 2 4 6 8 10 12 Enhanced Spec:Scan 2339(15.46),Qvalue=0 91 106 105 7751 7965 14.9 15.2 15.5 15.8Min 0 8 16 24 32 40 48 56 m/z 106.0 14.9 15.2 15.5 15.8Min 0 2 4 6 8 10 12 m/z 91.0 14.9 15.2 15.5 15.8Min 0 2 4 6 8 10 12 m/z 106.0 m/z 91.0 Page 264 of 478 Report Date: 28-Nov-2017 09:36:55 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 78 o-Xylene, CAS: 95-47-6 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 6 12 18 24 30 36 42 Raw Spec:Scan 2435(15.98) 91 106 7751 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 2435(15.98),Qvalue=99 91 106 7751 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 2 4 6 8 10 Ref Spec: 78 o-Xylene (NIST) 91 106 7751 30 50 70 90 110 130 150 170 190 210 230 250m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 15.980 min.(Qvalue: 99) 15.4 15.7 16.0 16.3Min 0 6 12 18 24 30 36 m/z 106.0 15.4 15.7 16.0 16.3Min 0 10 20 30 40 50 60 70 m/z 91.0 15.4 15.7 16.0 16.3Min 0 11 22 33 44 55 66 m/z 106.0 m/z 91.0 Page 265 of 478 Report Date: 28-Nov-2017 09:36:56 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 92 1,2,4-Trimethylbenzene, CAS: 95-63-6 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 5 10 15 20 25 30 35 40 Raw Spec:Scan 2721(17.50) 105 120 7757 121 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 2721(17.50),Qvalue=98 105 120 77 121 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 2 4 6 8 10 Ref Spec: 92 1,2,4-Trimethylbenzene (NIST) 105 120 77 30 50 70 90 110 130 150 170 190 210 230 250m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 17.500 min.(Qvalue: 98) 120 16.9 17.2 17.5 17.8 18.1Min 0 5 10 15 20 25 30 35 40 m/z 105.0 17.0 17.3 17.6 17.9Min 0 3 6 9 12 15 18 m/z 120.0 16.9 17.2 17.5 17.8 18.1Min 0 6 12 18 24 30 36 m/z 105.0 m/z 120.0 Page 266 of 478 Report Date: 28-Nov-2017 09:36:53 Chrom Revision: 2.2 13-Nov-2017 17:19:06Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 14 Trichlorofluoromethane, CAS: 75-69-4Signal: 1 Processing Integration Results RT: 5.23 Area: 2649 Amount: 0.029639 Amount Units: ppb v/v 4.9 5.1 5.3 5.5Min 0 2 4 6 8 10 12 14 16 18 m/z 101.0 Manual Integration Results RT: 5.23 Area: 5564 Amount: 0.062255 Amount Units: ppb v/v 4.9 5.1 5.3 5.5Min 0 2 4 6 8 10 12 14 16 18 m/z 101.0 Reviewer: puangmaleek, 28-Nov-2017 09:31:44 Audit Action: Assigned Compound ID Audit Reason: Assign Peak Page 267 of 478 Report Date: 28-Nov-2017 09:36:53 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 14 Trichlorofluoromethane, CAS: 75-69-4 Signal: 1 Processing Integration Results RT: 5.23 Area: 2649 Amount: 0.029639 Amount Units: ppb v/v 4.9 5.1 5.3 5.5Min 0 2 4 6 8 10 12 14 16 18 m/z 101.0 Manual Integration Results RT: 5.23 Area: 5564 Amount: 0.062255 Amount Units: ppb v/v 4.9 5.1 5.3 5.5Min 0 2 4 6 8 10 12 14 16 18 m/z 101.0 Reviewer: puangmaleek, 28-Nov-2017 09:31:54 Audit Action: Manually Integrated Audit Reason: Assign Peak Page 268 of 478 Report Date: 28-Nov-2017 09:36:55 Chrom Revision: 2.2 13-Nov-2017 17:19:06Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 84 N-Propylbenzene, CAS: 103-65-1Signal: 1 Processing Integration Results Not Detected Expected RT: 16.87 16.5 16.7 16.9 17.1Min 0 2 4 6 8 10 12 14 16 18 m/z 91.0 Manual Integration Results RT: 16.87 Area: 32379 Amount: 0.113113 Amount Units: ppb v/v 16.5 16.7 16.9 17.1Min 0 2 4 6 8 10 12 14 16 18 m/z 91.0 Reviewer: puangmaleek, 28-Nov-2017 09:34:17 Audit Action: Assigned Compound ID Audit Reason: Assign Peak Page 269 of 478 Report Date: 28-Nov-2017 09:36:55 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 84 N-Propylbenzene, CAS: 103-65-1 Signal: 1 Processing Integration Results Not Detected Expected RT: 16.87 16.5 16.7 16.9 17.1Min 0 2 4 6 8 10 12 14 16 18 m/z 91.0 Manual Integration Results RT: 16.87 Area: 32379 Amount: 0.113113 Amount Units: ppb v/v 16.5 16.7 16.9 17.1Min 0 2 4 6 8 10 12 14 16 18 m/z 91.0 Reviewer: puangmaleek, 28-Nov-2017 09:34:27 Audit Action: Manually Integrated Audit Reason: Assign Peak Page 270 of 478 Report Date: 28-Nov-2017 09:36:56 Chrom Revision: 2.2 13-Nov-2017 17:19:06Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 89 1,3,5-Trimethylbenzene, CAS: 108-67-8Signal: 1 Processing Integration Results RT: 16.99 Area: 32067 Amount: 0.170316 Amount Units: ppb v/v 16.7 16.9 17.1 17.3Min 0 3 6 9 12 15 18 21 24 27 30 33 36 m/z 105.0 Manual Integration Results RT: 17.06 Area: 23905 Amount: 0.126965 Amount Units: ppb v/v 16.7 16.9 17.1 17.3Min 0 3 6 9 12 15 18 21 24 27 30 33 36 m/z 105.0 Reviewer: puangmaleek, 28-Nov-2017 09:34:48 Audit Action: Assigned Compound ID Audit Reason: Assign Peak Page 271 of 478 Report Date: 28-Nov-2017 09:36:56 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 89 1,3,5-Trimethylbenzene, CAS: 108-67-8 Signal: 1 Processing Integration Results RT: 16.99 Area: 32067 Amount: 0.170316 Amount Units: ppb v/v 16.7 16.9 17.1 17.3Min 0 3 6 9 12 15 18 21 24 27 30 33 36 m/z 105.0 Manual Integration Results RT: 17.06 Area: 23905 Amount: 0.126965 Amount Units: ppb v/v 16.7 16.9 17.1 17.3Min 0 3 6 9 12 15 18 21 24 27 30 33 36 m/z 105.0 Reviewer: puangmaleek, 28-Nov-2017 09:34:52 Audit Action: Manually Integrated Audit Reason: Assign Peak Page 272 of 478 Report Date: 28-Nov-2017 09:36:56 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Isobutane 75-28-5 NIST14.L 237 C4H10 58 86 Isopropylsulfonyl chloride 10147-37-2 NIST14.L 19769 C3H7ClO2S 142 9 Cyclobutylamine 2516-34-9 NIST14.L 615 C4H9N 71 9 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99m/z 0 4 8 12 16 20 Raw Spec: Scan 86(3.44) 43 41 39 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99m/z 0 4 8 12 16 20 28034-10[MS SCAN Spec]:Scan 86(3.44) 43 41 39 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99m/z 0 18 36 54 72 90 Entry #237, Isobutane (from NIST14.L) 43 41 39 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99m/z 0 18 36 54 72 90 Entry #19769, Isopropylsulfonyl chloride (from NIST14.L) 43 41 39 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99m/z 0 18 36 54 72 90 Entry #615, Cyclobutylamine (from NIST14.L) 43 42 41 Page 273 of 478 Report Date: 28-Nov-2017 09:36:57 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Cyclohexane,1,4-dimethyl-,cis-624-29-3 NIST14.L 6928 C8H16 112 91 Cyclohexane,1,3-dimethyl-,cis-638-04-0 NIST14.L 6931 C8H16 112 91 Cyclohexane,1,3-dimethyl-591-21-9 NIST14.L 6866 C8H16 112 91 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112m/z 0 4 8 12 16 Raw Spec: Scan 1884(13.03) 97 55 112415669427098 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112m/z 0 4 8 12 16 28034-10[MS SCAN Spec]:Scan 1884(13.03) 97 55 112415669427098 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112m/z 0 18 36 54 72 90 Entry #6928, Cyclohexane, 1,4-dimethyl-, cis- (from NIST14.L) 55 97 11241 56 6942 96837084 9853 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112m/z 0 18 36 54 72 90 Entry #6931, Cyclohexane, 1,3-dimethyl-, cis- (from NIST14.L) 9755 41 112566942987053 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 100 104 108 112m/z 0 18 36 54 72 90 Entry #6866, Cyclohexane, 1,3-dimethyl- (from NIST14.L) 9755 41 112695642709853 Page 274 of 478 Report Date: 28-Nov-2017 09:36:57 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Cyclohexane,1,4-dimethyl-,trans-2207-04-7 NIST14.L 6940 C8H16 112 97 Cyclohexane,1,4-dimethyl-589-90-2 NIST14.L 6863 C8H16 112 97 Cyclohexane,1,4-dimethyl-,cis-624-29-3 NIST14.L 6922 C8H16 112 95 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 16 32 48 64 80 Raw Spec: Scan 2012(13.72) 9755 11256416970429683988453 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 16 32 48 64 80 28034-10[MS SCAN Spec]:Scan 2012(13.72) 9755 11256416970429683988453 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 18 36 54 72 90 Entry #6940, Cyclohexane, 1,4-dimethyl-, trans- (from NIST14.L) 55 97 41 112 56 6942 967083 985384 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 18 36 54 72 90 Entry #6863, Cyclohexane, 1,4-dimethyl- (from NIST14.L) 55 97 112415669427083969884 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113m/z 0 18 36 54 72 90 Entry #6922, Cyclohexane, 1,4-dimethyl-, cis- (from NIST14.L) 55 97 41 112564269708396849853 Page 275 of 478 Report Date: 28-Nov-2017 09:36:58 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Cyclohexane,ethyl-1678-91-7 NIST14.L 6789 C8H16 112 95 Cyclohexane,propyl-1678-92-8 NIST14.L 11775 C9H18 126 78 3,4-Dimethyl-2-hexene 2213-37-8 NIST14.L 6819 C8H16 112 76 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 3 6 9 12 15 Raw Spec: Scan 2137(14.38) 8355 82 41 1126769843942 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 3 6 9 12 15 28034-10[MS SCAN Spec]:Scan 2137(14.38) 8355 82 41 1126769843942 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #6789, Cyclohexane, ethyl- (from NIST14.L) 83 55 8241 112 56 673942 84 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #11775, Cyclohexane, propyl- (from NIST14.L) 83 55 82 41 1266739698443 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #6819, 3,4-Dimethyl-2-hexene (from NIST14.L) 55 83 41 11239436984 Page 276 of 478 Report Date: 28-Nov-2017 09:36:58 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Cyclohexane,1,1,3-trimethyl-3073-66-3 NIST14.L 11835 C9H18 126 94 Cyclohexane,1,3,5-trimethyl-,(1.alpha.,3.alpha 1795-27-3 NIST14.L 11878 C9H18 126 64 Cyclohexane,1,2,4-trimethyl-2234-75-5 NIST14.L 11819 C9H18 126 49 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125 129m/z 0 4 8 12 16 Raw Spec: Scan 2148(14.44) 111 69 55 41 835670 8443 1129767 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125 129m/z 0 4 8 12 16 28034-10[MS SCAN Spec]:Scan 2148(14.44) 11169 55 41 835670 8443 1129767 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125 129m/z 0 18 36 54 72 90 Entry #11835, Cyclohexane, 1,1,3-trimethyl- (from NIST14.L) 111 69 5541 83564370 1125367 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125 129m/z 0 18 36 54 72 90 Entry #11878, Cyclohexane, 1,3,5-trimethyl-,(1.alpha.,3.alpha.,5.alpha.)- (from NIST14.L) 11169 55 41 1264256701125367 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125 129m/z 0 18 36 54 72 90 Entry #11819, Cyclohexane, 1,2,4-trimethyl- (from NIST14.L) 69 111 55 41 1265670844367539711257 Page 277 of 478 Report Date: 28-Nov-2017 09:36:58 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Unknown Heptane,2,4-dimethyl-2213-23-2 NIST14.L 12971 C9H20 128 72 Hexane,2,3,4-trimethyl-921-47-1 NIST14.L 12982 C9H20 128 64 Octane,4-methyl-2216-34-4 NIST14.L 12942 C9H20 128 64 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 5 10 15 20 Raw Spec: Scan 2191(14.67) 43 57 71 8541705639 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 5 10 15 20 28034-10[MS SCAN Spec]:Scan 2191(14.67) 43 57 71 8541705639 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #12971, Heptane, 2,4-dimethyl- (from NIST14.L) 43 85415771 84 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #12982, Hexane, 2,3,4-trimethyl- (from NIST14.L) 43 41 7157 85 39 69 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #12942, Octane, 4-methyl- (from NIST14.L) 43 85714157 Page 278 of 478 Report Date: 28-Nov-2017 09:36:58 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Cyclohexane,1,2,4-trimethyl-,(1.alpha.,2.beta.7667-60-9 NIST14.L 11871 C9H18 126 94 Cyclohexane,1,3,5-trimethyl-,(1.alpha.,3.alpha 1795-26-2 NIST14.L 11876 C9H18 126 90 Cyclohexane,1,2,4-trimethyl-2234-75-5 NIST14.L 11819 C9H18 126 90 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125m/z 0 3 6 9 12 15 Raw Spec: Scan 2206(14.75) 11169 55 41 12656704384112679753 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125m/z 0 3 6 9 12 15 28034-10[MS SCAN Spec]:Scan 2206(14.75) 11169 55 41 12656704384112679753 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125m/z 0 18 36 54 72 90 Entry #11871, Cyclohexane, 1,2,4-trimethyl-,(1.alpha.,2.beta.,4.beta.)- (from NIST14.L) 111695541 56 12643708453112675797 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125m/z 0 18 36 54 72 90 Entry #11876, Cyclohexane, 1,3,5-trimethyl-,(1.alpha.,3.alpha.,5.beta.)- (from NIST14.L) 69 1115541 12642567053831126784 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 125m/z 0 18 36 54 72 90 Entry #11819, Cyclohexane, 1,2,4-trimethyl- (from NIST14.L) 69 111 55 41 1265670844367539711257 Page 279 of 478 Report Date: 28-Nov-2017 09:36:58 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Octane,3-methyl-2216-33-3 NIST14.L 12944 C9H20 128 90 Heptane,2,5-dimethyl-2216-30-0 NIST14.L 12977 C9H20 128 72 Decane,2,6,6-trimethyl-62108-24-1 NIST14.L 51451 C13H28 184 53 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 6 12 18 24 30 Raw Spec: Scan 2222(14.84) 57 43 56 98 997139 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 6 12 18 24 30 28034-10[MS SCAN Spec]:Scan 2222(14.84) 57 43 56 98 997139 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #12944, Octane, 3-methyl- (from NIST14.L) 57 43 56 98 9971 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #12977, Heptane, 2,5-dimethyl- (from NIST14.L) 57 43 56 71 99 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #51451, Decane, 2,6,6-trimethyl- (from NIST14.L) 57 43 714156 998570 127 Page 280 of 478 Report Date: 28-Nov-2017 09:36:58 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Cyclohexane,1,2,3-trimethyl-,(1.alpha.,2.beta.1678-81-5 NIST14.L 11873 C9H18 126 93 Cyclohexane,1,2,4-trimethyl-2234-75-5 NIST14.L 11831 C9H18 126 70 3-Heptene,2,6-dimethyl-2738-18-3 NIST14.L 11788 C9H18 126 60 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 15 30 45 60 75 Raw Spec: Scan 2303(15.27) 69 11155 5641 70 126824339975781112 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 15 30 45 60 75 28034-10[MS SCAN Spec]:Scan 2303(15.27) 69 11155 5641 70 126824339975781112 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #11873, Cyclohexane, 1,2,3-trimethyl-,(1.alpha.,2.beta.,3.alpha.)- (from NIST14.L) 69 55 11141 56 70 126833943678297112 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #11831, Cyclohexane, 1,2,4-trimethyl- (from NIST14.L) 69 11155 41 12656703997844267112 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #11788, 3-Heptene, 2,6-dimethyl- (from NIST14.L) 55 69 5641 43 70 12657833953 Page 281 of 478 Report Date: 28-Nov-2017 09:36:58 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-10.D Injection Date:24-Nov-2017 17:32:30 Instrument ID:CHB.i Lims ID:200-41113-A-3 Lab Sample ID:200-41113-3 Client ID:SV-1 Operator ID:VTP ALS Bottle#:10 Worklist Smp#:39 Purge Vol:200.000 mL Dil. Factor:2.5000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:Detector MS SCAN Library Search Compound Match CAS#Library Entry Formula Weight Q Unknown 1-Ethyl-4-methylcyclohexane 3728-56-1 NIST14.L 11812 C9H18 126 76 Cyclohexane,1-ethyl-2-methyl-,trans-4923-78-8 NIST14.L 11861 C9H18 126 68 3,5-Dimethyl-3-heptene 59643-68-4 NIST14.L 11784 C9H18 126 62 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 16 32 48 64 80 Raw Spec: Scan 2411(15.85) 9755 694143 70 1263996986753 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 16 32 48 64 80 28034-10[MS SCAN Spec]:Scan 2411(15.85) 9755 694143 70 1263996986753 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #11812, 1-Ethyl-4-methylcyclohexane (from NIST14.L) 9755 41 69 12696984381 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #11861, Cyclohexane, 1-ethyl-2-methyl-, trans- (from NIST14.L) 9755 41 69 126984281 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 18 36 54 72 90 Entry #11784, 3,5-Dimethyl-3-heptene (from NIST14.L) 9755 69 12641 984356 Page 282 of 478 Page 283 of 478 Page 284 of 478 Page 285 of 478 Page 286 of 478 Page 287 of 478 Page 288 of 478 Page 289 of 478 Report Date: 28-Nov-2017 09:42:10 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-11.D Lims ID:200-41113-A-4 Client ID:AA-1 Sample Type:Client Inject. Date:24-Nov-2017 18:24:30 ALS Bottle#:11 Worklist Smp#:40 Purge Vol:200.000 mL Dil. Factor:1.0000 Sample Info:200-0028034-011 Misc. Info.:41113-04 Operator ID:VTP Instrument ID:CHB.i Method:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:28-Nov-2017 09:42:09 Calib Date:07-Nov-2017 01:49:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal/External Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: puangmaleek Date:28-Nov-2017 09:42:09 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags 2 Dichlorodifluoromethane 85 3.193 3.193 0.000 99 31821 0.3648 3 Chlorodifluoromethane 51 3.231 3.225 0.006 97 9337 0.1882 4 1,2-Dichloro-1,1,2,2-tetra 85 3.412 ND 5 Chloromethane 50 3.540 3.540 0.005 83 12580 0.4043 7 6 Butane 43 3.711 3.711 0.000 91 17863 0.3323 7 7 Vinyl chloride 62 3.748 ND 8 Butadiene 54 3.812 ND 10 Bromomethane 94 4.479 ND 11 Chloroethane 64 4.709 ND 13 Vinyl bromide 106 5.120 ND 14 Trichlorofluoromethane 101 5.216 5.216 0.000 97 16252 0.1746 19 1,1,2-Trichloro-1,2,2-trif 101 6.246 6.246 0.000 92 4890 0.0625 20 1,1-Dichloroethene 96 6.315 ND 21 Acetone 43 6.481 6.481 0.016 92 55543 0.9500 7 22 Isopropyl alcohol 45 6.726 6.726 0.043 83 16375 0.2492 7 23 Carbon disulfide 76 6.748 ND 24 3-Chloro-1-propene 41 7.014 ND 27 Methylene Chloride 49 7.276 7.276 0.000 64 5633 0.1201 7 28 2-Methyl-2-propanol 59 7.383 ND 29 Methyl tert-butyl ether 73 7.623 ND 30 trans-1,2-Dichloroethene 61 7.687 ND 32 Hexane 57 8.018 8.012 0.006 94 6148 0.0860 33 1,1-Dichloroethane 63 8.423 ND 36 2-Butanone (MEK) 72 9.336 9.336 0.021 89 2564 0.1112 7 37 cis-1,2-Dichloroethene 96 9.331 ND * 39 Chlorobromomethane 128 9.694 9.699 -0.005 91 393822 10.0 38 Tetrahydrofuran 42 9.710 ND 40 Chloroform 83 9.774 ND S 41 1,2-Dichloroethene, Total 61 10.000 ND 42 1,1,1-Trichloroethane 97 10.030 ND 43 Cyclohexane 84 10.046 ND Page 290 of 478 Report Date: 28-Nov-2017 09:42:10 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-11.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags 44 Carbon tetrachloride 117 10.233 10.238 -0.005 94 4802 0.0615 45 Isooctane 57 10.521 ND 46 Benzene 78 10.558 10.563 -0.005 96 15384 0.1064 47 1,2-Dichloroethane 62 10.659 ND 48 n-Heptane 43 10.766 10.766 -0.006 24 1811 0.0202 7 *50 1,4-Difluorobenzene 114 11.103 11.102 0.001 94 1967074 10.0 53 Trichloroethene 95 11.476 ND 54 1,2-Dichloropropane 63 11.839 ND 55 Methyl methacrylate 69 11.876 ND 56 1,4-Dioxane 88 11.967 ND 58 Dichlorobromomethane 83 12.202 ND 60 cis-1,3-Dichloropropene 75 12.826 ND 61 4-Methyl-2-pentanone (MIBK 43 12.976 ND 64 Toluene 92 13.253 13.259 -0.006 92 8019 0.0795 66 trans-1,3-Dichloropropene 75 13.621 ND 67 1,1,2-Trichloroethane 83 13.888 ND 68 Tetrachloroethene 166 14.032 ND 69 2-Hexanone 43 14.150 ND 70 Chlorodibromomethane 129 14.449 ND 71 Ethylene Dibromide 107 14.646 ND * 72 Chlorobenzene-d5 117 15.212 15.212 0.000 84 1688199 10.0 73 Chlorobenzene 112 15.249 ND 74 Ethylbenzene 91 15.324 15.319 0.005 90 6765 0.0306 M 76 m-Xylene & p-Xylene 106 15.463 15.463 -0.005 0 4203 0.0483 7 78 o-Xylene 106 15.981 15.981 0.006 22 2475 0.0286 7 S 77 Xylenes, Total 106 0 0.0768 7 79 Styrene 104 16.002 ND 80 Bromoform 173 16.295 ND 81 Isopropylbenzene 105 16.391 ND 83 1,1,2,2-Tetrachloroethane 83 16.797 ND 84 N-Propylbenzene 91 16.866 ND 87 4-Ethyltoluene 105 16.994 ND 88 2-Chlorotoluene 91 17.037 ND 89 1,3,5-Trimethylbenzene 105 17.058 ND 91 tert-Butylbenzene 119 17.437 ND 92 1,2,4-Trimethylbenzene 105 17.507 17.507 0.000 1 2235 0.0114 7 93 sec-Butylbenzene 105 17.694 ND 94 4-Isopropyltoluene 119 17.843 ND 95 1,3-Dichlorobenzene 146 17.923 ND 96 1,4-Dichlorobenzene 146 18.035 ND 97 Benzyl chloride 91 18.185 ND 99 n-Butylbenzene 91 18.350 ND 100 1,2-Dichlorobenzene 146 18.521 ND 103 1,2,4-Trichlorobenzene 180 20.880 ND 104 Hexachlorobutadiene 225 21.045 ND 105 Naphthalene 128 21.360 ND Page 291 of 478 Report Date: 28-Nov-2017 09:42:10 Chrom Revision: 2.2 13-Nov-2017 17:19:06 QC Flag Legend Processing Flags 7 - Failed Limit of Detection Review Flags M - Manually Integrated Reagents: ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 292 of 478 Y ( X 1 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 9 . 6 9 4 ) * 1 , 4 - D i f l u o r o b e n z e n e ( 1 1 . 0 9 7 ) * C h l o r o b e n z e n e - d 5 ( 1 5 . 2 1 2 ) Report Date: 28-Nov-2017 09:42:10 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-11.D Injection Date:24-Nov-2017 18:24:30 Instrument ID:CHB.i Lims ID:200-41113-A-4 Lab Sample ID:200-41113-4 Client ID:AA-1 Operator ID:VTP ALS Bottle#:11 Worklist Smp#:40 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 44 Carbon tetrachloride, CAS: 56-23-5 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119 123m/z 0 3 6 9 12 15 18 21 Raw Spec:Scan 1359(10.23) 117 40 8247 84 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119 123m/z 0 13 26 39 52 65 78 91 Amdis Enhanced Spec: Scan 1359(10.23),Qvalue=94 117 8247 8449 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119 123m/z 0 13 26 39 52 65 78 91 Ref Spec: 44 Carbon tetrachloride (NIST) 117 8247 84 49 35 39 43 47 51 55 59 63 67 71 75 79 83 87 91 95 99 103107111115119 123m/z -100 -75 -50 -25 0 25 50 75 100 Differenc Spec:Scan 1 @ 10.240 min.(Qvalue: 94) 9.7 10.0 10.3 10.6Min 0 3 6 9 12 15 18 21 m/z 117.0 9.7 10.0 10.3 10.6Min 0 3 6 9 12 15 18 m/z 119.0 9.7 10.0 10.3 10.6Min 0 3 6 9 12 15 18 21 m/z 117.0 m/z 119.0 Page 294 of 478 Report Date: 28-Nov-2017 09:42:10 Chrom Revision: 2.2 13-Nov-2017 17:19:06Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-11.D Injection Date:24-Nov-2017 18:24:30 Instrument ID:CHB.i Lims ID:200-41113-A-4 Lab Sample ID:200-41113-4 Client ID:AA-1 Operator ID:VTP ALS Bottle#:11 Worklist Smp#:40 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 74 Ethylbenzene, CAS: 100-41-4Signal: 1 Processing Integration Results RT: 15.46 Area: 8025 Amount: 0.036307 Amount Units: ppb v/v 15.0 15.2 15.4 15.6 15.8Min 0 3 6 9 12 15 18 21 24 27 30 33 36 39 m/z 91.0 Manual Integration Results RT: 15.32 Area: 6765 Amount: 0.030607 Amount Units: ppb v/v 15.0 15.2 15.4 15.6 15.8Min 0 3 6 9 12 15 18 21 24 27 30 33 36 39 m/z 91.0 Reviewer: puangmaleek, 28-Nov-2017 09:40:20 Audit Action: Assigned Compound ID Audit Reason: Assign Peak Page 295 of 478 Report Date: 28-Nov-2017 09:42:10 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-11.D Injection Date:24-Nov-2017 18:24:30 Instrument ID:CHB.i Lims ID:200-41113-A-4 Lab Sample ID:200-41113-4 Client ID:AA-1 Operator ID:VTP ALS Bottle#:11 Worklist Smp#:40 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 74 Ethylbenzene, CAS: 100-41-4 Signal: 1 Processing Integration Results RT: 15.46 Area: 8025 Amount: 0.036307 Amount Units: ppb v/v 15.0 15.2 15.4 15.6 15.8Min 0 3 6 9 12 15 18 21 24 27 30 33 36 39 m/z 91.0 Manual Integration Results RT: 15.32 Area: 6765 Amount: 0.030607 Amount Units: ppb v/v 15.0 15.2 15.4 15.6 15.8Min 0 3 6 9 12 15 18 21 24 27 30 33 36 39 m/z 91.0 Reviewer: puangmaleek, 28-Nov-2017 09:40:35 Audit Action: Manually Integrated Audit Reason: Assign Peak Page 296 of 478 Report Date: 28-Nov-2017 09:42:10 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-11.D Injection Date:24-Nov-2017 18:24:30 Instrument ID:CHB.i Lims ID:200-41113-A-4 Lab Sample ID:200-41113-4 Client ID:AA-1 Operator ID:VTP ALS Bottle#:11 Worklist Smp#:40 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 74 Ethylbenzene, CAS: 100-41-4 Signal: 2 Processing Integration Results RT: 15.46 Area: 4203 Amount: 0.036307 Amount Units: ppb v/v 15.0 15.2 15.4 15.6 15.8Min 0 2 4 6 8 10 12 14 16 18 20 m/z 106.0 Manual Integration Results RT: 15.32 Area: 1979 Amount: 0.030607 Amount Units: ppb v/v 15.0 15.2 15.4 15.6 15.8Min 0 2 4 6 8 10 12 14 16 18 20 m/z 106.0 Reviewer: puangmaleek, 28-Nov-2017 09:40:55 Audit Action: Manually Integrated Audit Reason: Assign Peak Page 297 of 478 Pa g e 2 9 8 o f 4 7 8 Pa g e 2 9 9 o f 4 7 8 Pa g e 3 0 0 o f 4 7 8 Pa g e 3 0 1 o f 4 7 8 Pa g e 3 0 2 o f 4 7 8 Pa g e 3 0 3 o f 4 7 8 Pa g e 3 0 4 o f 4 7 8 Pa g e 3 0 5 o f 4 7 8 Pa g e 3 0 6 o f 4 7 8 Pa g e 3 0 7 o f 4 7 8 Report Date: 07-Nov-2017 13:39:37 Chrom Revision: 2.2 28-Sep-2017 09:29:16 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-04.D Lims ID:ic Client ID: Sample Type:IC Calib Level:1 Inject. Date:06-Nov-2017 17:59:30 ALS Bottle#:4 Worklist Smp#:4 Purge Vol:200.000 mL Dil. Factor:1.0000 Sample Info:200-0027754-004 Misc. Info.:ic Operator ID:vtp Instrument ID:CHB.i Sublist:chrom-TO15_LLNJ_TO3*sub5 Method:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:07-Nov-2017 13:39:36 Calib Date:07-Nov-2017 01:49:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal/External Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: daiglep Date:07-Nov-2017 08:54:08 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 1 Propene 41 3.145 3.135 0.010 60 1084 0.0351 0.0803 2 Dichlorodifluoromethane 85 3.199 3.193 0.006 96 1821 0.0351 0.0353 3 Chlorodifluoromethane 51 3.236 3.225 0.011 95 1482 0.0351 0.0506 4 1,2-Dichloro-1,1,2,2-tetra 85 3.417 3.412 0.005 90 1766 0.0351 0.0326 5 Chloromethane 50 3.540 3.535 0.005 1 824 0.0351 0.0448 6 Butane 43 3.716 3.711 0.005 93 2069 0.0351 0.0651 7 Vinyl chloride 62 3.754 3.748 0.006 86 687 0.0351 0.0310 8 Butadiene 54 3.818 3.812 0.006 1 387 0.0351 0.0238 10 Bromomethane 94 4.490 4.479 0.011 1 497 0.0351 0.0218 9 BFB 11 Chloroethane 64 4.709 ND ND 12 2-Methylbutane 43 4.794 4.789 0.005 1 1000 0.0351 0.0346 13 Vinyl bromide 106 5.120 5.120 0.000 1 539 0.0351 0.0232 14 Trichlorofluoromethane 101 5.221 5.216 0.005 1 1623 0.0351 0.0295 15 Pentane 43 5.365 5.355 0.010 94 3076 0.0351 0.0701 16 Ethanol 45 5.702 5.675 0.027 97 1504 0.0702 0.1250 17 Ethyl ether 59 5.830 ND ND 18 Acrolein 56 6.198 ND ND 19 1,1,2-Trichloro-1,2,2-trif 101 6.230 6.246 -0.016 1 1226 0.0351 0.0265 20 1,1-Dichloroethene 96 6.326 6.321 0.005 0 879 0.0351 0.0380 M 21 Acetone 43 6.507 6.470 0.037 97 6717 0.0351 0.1944 22 Isopropyl alcohol 45 6.748 6.684 0.064 63 579 0.0351 0.0149 23 Carbon disulfide 76 6.753 6.748 0.005 94 2114 0.0351 0.0326 24 3-Chloro-1-propene 41 7.025 7.020 0.005 1 1179 0.0351 0.0365 26 Acetonitrile 41 7.025 7.079 -0.054 34 1179 0.0351 0.0591 27 Methylene Chloride 49 7.287 7.276 0.011 91 1215 0.0351 0.0438 28 2-Methyl-2-propanol 59 7.436 7.388 0.048 1 1666 0.0351 0.0329 29 Methyl tert-butyl ether 73 7.687 7.628 0.059 91 1552 0.0351 0.0225 30 trans-1,2-Dichloroethene 61 7.682 7.687 -0.005 0 575 0.0351 0.0164 31 Acrylonitrile 53 7.778 7.756 0.022 1 219 0.0351 0.0118 Page 308 of 478 Report Date: 07-Nov-2017 13:39:37 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-04.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 Hexane 57 8.012 8.018 -0.006 94 2859 0.0351 0.0677 33 1,1-Dichloroethane 63 8.418 8.429 -0.011 91 1709 0.0351 0.0364 34 Vinyl acetate 43 8.455 8.434 0.021 60 1650 0.0351 0.0255 36 2-Butanone (MEK) 72 9.347 9.320 0.027 96 426 0.0351 0.0313 37 cis-1,2-Dichloroethene 96 9.331 9.331 0.000 50 838 0.0351 0.0313 M 35 Ethyl acetate 88 9.336 ND ND * 39 Chlorobromomethane 128 9.699 9.699 0.000 96 232740 10.0 10.0 38 Tetrahydrofuran 42 9.758 9.710 0.048 53 1047 0.0351 0.0336 40 Chloroform 83 9.779 9.774 0.005 70 1415 0.0351 0.0282 S 41 1,2-Dichloroethene, Total 61 0 0.0702 0.0477 42 1,1,1-Trichloroethane 97 10.035 10.035 0.000 79 1397 0.0351 0.0286 43 Cyclohexane 84 10.035 10.046 -0.011 1 326 0.0351 0.008860 44 Carbon tetrachloride 117 10.238 10.243 -0.005 83 1233 0.0351 0.0266 45 Isooctane 57 10.521 ND ND 46 Benzene 78 10.558 10.564 -0.006 94 3865 0.0351 0.0450 47 1,2-Dichloroethane 62 10.665 ND ND 48 n-Heptane 43 10.766 10.777 -0.011 88 1972 0.0351 0.0370 A 49 GRO 1 10.865 (4.779-16.951) 0 4176944 0.0351 0 * 50 1,4-Difluorobenzene 114 11.103 11.102 0.000 94 1168258 10.0 10.0 51 n-Butanol 56 11.337 11.289 0.048 83 1075 0.0351 0.0647 53 Trichloroethene 95 11.481 11.476 0.005 83 984 0.0351 0.0287 M 54 1,2-Dichloropropane 63 11.839 11.844 -0.005 90 1133 0.0351 0.0343 55 Methyl methacrylate 69 11.882 ND ND 56 1,4-Dioxane 88 12.020 11.967 0.053 45 468 0.0351 0.0287 57 Dibromomethane 174 12.036 12.031 0.005 94 1449 0.0351 0.0425 58 Dichlorobromomethane 83 12.202 12.202 0.000 87 1830 0.0351 0.0317 A 59 TVOC as Toluene 1 12.485 (3.125-21.845) 0 4497654 0.0351 0 60 cis-1,3-Dichloropropene 75 12.832 12.832 0.000 83 1344 0.0351 0.0288 61 4-Methyl-2-pentanone (MIBK 43 13.002 12.976 0.026 8 2066 0.0351 0.0316 63 n-Octane 43 13.253 13.248 0.005 89 2837 0.0351 0.0378 64 Toluene 92 13.259 13.264 -0.005 91 2668 0.0351 0.0435 66 trans-1,3-Dichloropropene 75 13.616 13.622 -0.006 1 870 0.0351 0.0195 67 1,1,2-Trichloroethane 83 13.894 ND ND 68 Tetrachloroethene 166 14.038 14.038 0.000 92 1459 0.0351 0.0300 M 69 2-Hexanone 43 14.187 14.155 0.032 82 2176 0.0351 0.0355 70 Chlorodibromomethane 129 14.454 14.449 0.005 93 1383 0.0351 0.0240 71 Ethylene Dibromide 107 14.652 14.652 0.000 90 1571 0.0351 0.0293 * 72 Chlorobenzene-d5 117 15.212 15.212 0.000 86 1027167 10.0 10.0 73 Chlorobenzene 112 15.255 15.255 0.000 82 3015 0.0351 0.0368 74 Ethylbenzene 91 15.319 15.319 0.000 96 6627 0.0351 0.0493 75 n-Nonane 57 15.340 15.340 0.000 68 2506 0.0351 0.0364 76 m-Xylene & p-Xylene 106 15.473 15.468 0.005 0 3081 0.0702 0.0582 78 o-Xylene 106 15.980 15.981 -0.001 96 2184 0.0351 0.0414 S 77 Xylenes, Total 106 0 0.1052 0.0996 79 Styrene 104 16.007 16.002 0.005 92 2006 0.0351 0.0253 80 Bromoform 173 16.295 16.295 0.000 89 1032 0.0351 0.0194 81 Isopropylbenzene 105 16.391 16.391 0.000 96 4484 0.0351 0.0301 83 1,1,2,2-Tetrachloroethane 83 16.797 16.797 0.000 90 2657 0.0351 0.0328 84 N-Propylbenzene 91 16.877 16.872 0.005 98 5752 0.0351 0.0313 85 1,2,3-Trichloropropane 75 16.648 16.647 0.001 61 325918 0.0351 5.26 86 n-Decane 57 16.941 16.941 0.000 88 2936 0.0351 0.0336 87 4-Ethyltoluene 105 17.000 16.995 0.005 96 4545 0.0351 0.0311 Page 309 of 478 Report Date: 07-Nov-2017 13:39:37 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-04.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 88 2-Chlorotoluene 91 17.037 17.037 0.000 92 4069 0.0351 0.0335 89 1,3,5-Trimethylbenzene 105 17.064 17.064 0.000 92 3821 0.0351 0.0316 90 Alpha Methyl Styrene 118 17.341 17.336 0.005 79 1387 0.0351 0.0235 91 tert-Butylbenzene 119 17.437 17.437 0.000 92 3760 0.0351 0.0322 92 1,2,4-Trimethylbenzene 105 17.507 17.507 0.000 92 3687 0.0351 0.0309 93 sec-Butylbenzene 105 17.694 17.694 0.000 97 5875 0.0351 0.0324 94 4-Isopropyltoluene 119 17.838 17.848 -0.010 96 4621 0.0351 0.0310 95 1,3-Dichlorobenzene 146 17.928 17.928 0.000 92 2242 0.0351 0.0283 96 1,4-Dichlorobenzene 146 18.040 18.035 0.005 93 2046 0.0351 0.0264 97 Benzyl chloride 91 18.185 18.185 0.000 95 1802 0.0351 0.0203 98 Undecane 57 18.318 18.318 0.000 94 3184 0.0351 0.0335 99 n-Butylbenzene 91 18.355 18.355 0.000 95 4247 0.0351 0.0310 100 1,2-Dichlorobenzene 146 18.526 18.521 0.005 91 2298 0.0351 0.0308 102 Dodecane 57 19.770 19.770 0.000 88 2769 0.0351 0.0377 103 1,2,4-Trichlorobenzene 180 20.880 20.885 -0.005 81 1045 0.0351 0.0226 104 Hexachlorobutadiene 225 21.051 21.051 -0.001 83 1834 0.0351 0.0376 105 Naphthalene 128 21.376 21.360 0.016 93 1534 0.0351 0.0157 106 1,2,3-Trichlorobenzene 180 21.851 21.835 0.016 1 1034 0.0351 0.0258 QC Flag LegendProcessing Flags ND - Not Detected or Marked ND Review Flags M - Manually Integrated Reagents: ATTO15CAL1w_00179 Amount Added: 35.00 Units: mL ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 310 of 478 Y ( X 1 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 9 . 6 9 9 ) * 1 , 4 - D i f l u o r o b e n z e n e ( 1 1 . 1 0 3 ) * C h l o r o b e n z e n e - d 5 ( 1 5 . 2 1 2 ) + Report Date: 07-Nov-2017 13:39:37 Chrom Revision: 2.2 28-Sep-2017 09:29:16Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-04.D Injection Date:06-Nov-2017 17:59:30 Instrument ID:CHB.i Lims ID:ic Client ID: Operator ID:vtp ALS Bottle#:4 Worklist Smp#:4 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 20 1,1-Dichloroethene, CAS: 75-35-4Signal: 1 Processing Integration Results Not Detected Expected RT: 6.32 6.0 6.2 6.4 6.6Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 m/z 96.0 Manual Integration Results RT: 6.33 Area: 879 Amount: 0.037980 Amount Units: ppb v/v 6.0 6.2 6.4 6.6Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 m/z 96.0 Reviewer: daiglep, 07-Nov-2017 08:53:49 Audit Action: Manually Integrated Audit Reason: Missed Peak Page 312 of 478 Report Date: 07-Nov-2017 13:39:37 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-04.D Injection Date:06-Nov-2017 17:59:30 Instrument ID:CHB.i Lims ID:ic Client ID: Operator ID:vtp ALS Bottle#:4 Worklist Smp#:4 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 20 1,1-Dichloroethene, CAS: 75-35-4 Signal: 2 Processing Integration Results Not Detected Expected RT: 6.32 6.0 6.2 6.4 6.6Min 0 4 8 12 16 20 24 28 32 36 40 44 48 52 m/z 61.0 Manual Integration Results RT: 6.33 Area: 879 Amount: 0.037980 Amount Units: ppb v/v 6.0 6.2 6.4 6.6Min 0 4 8 12 16 20 24 28 32 36 40 44 48 52 m/z 61.0 Reviewer: daiglep, 07-Nov-2017 08:55:25 Audit Action: Manually Integrated Audit Reason: Missed Peak Page 313 of 478 Report Date: 07-Nov-2017 13:39:37 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-04.D Injection Date:06-Nov-2017 17:59:30 Instrument ID:CHB.i Lims ID:ic Client ID: Operator ID:vtp ALS Bottle#:4 Worklist Smp#:4 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 20 1,1-Dichloroethene, CAS: 75-35-4 Signal: 3 Processing Integration Results Not Detected Expected RT: 6.32 6.0 6.2 6.4 6.6Min 0 2 4 6 8 10 12 14 16 18 20 22 24 m/z 63.0 Manual Integration Results RT: 6.33 Area: 152 Amount: 0.037980 Amount Units: ppb v/v 6.0 6.2 6.4 6.6Min 0 2 4 6 8 10 12 14 16 18 20 22 24 m/z 63.0 Reviewer: daiglep, 07-Nov-2017 08:55:27 Audit Action: Manually Integrated Audit Reason: Missed Peak Page 314 of 478 Report Date: 07-Nov-2017 13:39:37 Chrom Revision: 2.2 28-Sep-2017 09:29:16Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-04.D Injection Date:06-Nov-2017 17:59:30 Instrument ID:CHB.i Lims ID:ic Client ID: Operator ID:vtp ALS Bottle#:4 Worklist Smp#:4 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 37 cis-1,2-Dichloroethene, CAS: 156-59-2Signal: 1 Processing Integration Results RT: 9.34 Area: 330 Amount: 0.012152 Amount Units: ppb v/v 9.0 9.2 9.4 9.6Min 0 4 8 12 16 20 24 28 32 36 40 44 48 52 56 m/z 96.0 Manual Integration Results RT: 9.33 Area: 838 Amount: 0.031330 Amount Units: ppb v/v 9.0 9.2 9.4 9.6Min 0 4 8 12 16 20 24 28 32 36 40 44 48 52 56 m/z 96.0 Reviewer: daiglep, 07-Nov-2017 08:55:46 Audit Action: Manually Integrated Audit Reason: Incomplete Integration Page 315 of 478 Report Date: 07-Nov-2017 13:39:37 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-04.D Injection Date:06-Nov-2017 17:59:30 Instrument ID:CHB.i Lims ID:ic Client ID: Operator ID:vtp ALS Bottle#:4 Worklist Smp#:4 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 37 cis-1,2-Dichloroethene, CAS: 156-59-2 Signal: 2 Processing Integration Results RT: 9.34 Area: 296 Amount: 0.012152 Amount Units: ppb v/v 9.0 9.2 9.4 9.6Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 m/z 98.0 Manual Integration Results RT: 9.35 Area: 380 Amount: 0.031330 Amount Units: ppb v/v 9.0 9.2 9.4 9.6Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 m/z 98.0 Reviewer: daiglep, 07-Nov-2017 08:55:48 Audit Action: Manually Integrated Audit Reason: Incomplete Integration Page 316 of 478 Report Date: 07-Nov-2017 13:39:37 Chrom Revision: 2.2 28-Sep-2017 09:29:16Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-04.D Injection Date:06-Nov-2017 17:59:30 Instrument ID:CHB.i Lims ID:ic Client ID: Operator ID:vtp ALS Bottle#:4 Worklist Smp#:4 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 53 Trichloroethene, CAS: 79-01-6Signal: 1 Processing Integration Results RT: 11.48 Area: 795 Amount: 0.023646 Amount Units: ppb v/v 11.1 11.3 11.5 11.7Min 0 4 8 12 16 20 24 28 32 36 40 44 48 52 56 m/z 95.0 Manual Integration Results RT: 11.48 Area: 984 Amount: 0.028693 Amount Units: ppb v/v 11.1 11.3 11.5 11.7Min 0 4 8 12 16 20 24 28 32 36 40 44 48 52 56 m/z 95.0 Reviewer: daiglep, 07-Nov-2017 08:56:01 Audit Action: Manually Integrated Audit Reason: Incomplete Integration Page 317 of 478 Report Date: 07-Nov-2017 13:39:37 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-04.D Injection Date:06-Nov-2017 17:59:30 Instrument ID:CHB.i Lims ID:ic Client ID: Operator ID:vtp ALS Bottle#:4 Worklist Smp#:4 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 53 Trichloroethene, CAS: 79-01-6 Signal: 2 Processing Integration Results RT: 11.48 Area: 0 Amount: 0.023646 Amount Units: ppb v/v 2.9 3.9 4.9 5.9 6.9 7.9 8.9 9.9 10.9Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 m/z 130.0 Manual Integration Results RT: 11.48 Area: 1071 Amount: 0.028693 Amount Units: ppb v/v 2.9 3.9 4.9 5.9 6.9 7.9 8.9 9.9 10.9Min 0 1 2 3 4 5 6 7 8 9 10 11 m/z 130.0 Reviewer: daiglep, 07-Nov-2017 08:56:03 Audit Action: Manually Integrated Audit Reason: Incomplete Integration Page 318 of 478 Report Date: 07-Nov-2017 13:39:37 Chrom Revision: 2.2 28-Sep-2017 09:29:16Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-04.D Injection Date:06-Nov-2017 17:59:30 Instrument ID:CHB.i Lims ID:ic Client ID: Operator ID:vtp ALS Bottle#:4 Worklist Smp#:4 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 68 Tetrachloroethene, CAS: 127-18-4Signal: 1 Processing Integration Results RT: 14.04 Area: 1169 Amount: 0.024559 Amount Units: ppb v/v 13.7 13.9 14.1 14.3Min 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 m/z 166.0 Manual Integration Results RT: 14.04 Area: 1459 Amount: 0.030000 Amount Units: ppb v/v 13.7 13.9 14.1 14.3Min 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 m/z 166.0 Reviewer: daiglep, 07-Nov-2017 08:56:12 Audit Action: Manually Integrated Audit Reason: Incomplete Integration Page 319 of 478 Report Date: 07-Nov-2017 13:39:37 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-04.D Injection Date:06-Nov-2017 17:59:30 Instrument ID:CHB.i Lims ID:ic Client ID: Operator ID:vtp ALS Bottle#:4 Worklist Smp#:4 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 68 Tetrachloroethene, CAS: 127-18-4 Signal: 2 Processing Integration Results RT: 14.04 Area: 599 Amount: 0.024559 Amount Units: ppb v/v 13.7 13.9 14.1 14.3Min 0 3 6 9 12 15 18 21 24 27 30 33 36 39 42 m/z 168.0 Manual Integration Results RT: 14.04 Area: 703 Amount: 0.030000 Amount Units: ppb v/v 13.7 13.9 14.1 14.3Min 0 3 6 9 12 15 18 21 24 27 30 33 36 39 42 m/z 168.0 Reviewer: daiglep, 07-Nov-2017 08:56:14 Audit Action: Manually Integrated Audit Reason: Incomplete Integration Page 320 of 478 Report Date: 07-Nov-2017 13:39:39 Chrom Revision: 2.2 28-Sep-2017 09:29:16 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-05.D Lims ID:ic Client ID: Sample Type:IC Calib Level:2 Inject. Date:06-Nov-2017 18:52:30 ALS Bottle#:5 Worklist Smp#:5 Purge Vol:200.000 mL Dil. Factor:1.0000 Sample Info:200-0027754-005 Misc. Info.:ic Operator ID:vtp Instrument ID:CHB.i Sublist:chrom-TO15_LLNJ_TO3*sub5 Method:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:07-Nov-2017 13:39:39 Calib Date:07-Nov-2017 01:49:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal/External Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: daiglep Date:07-Nov-2017 08:57:46 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 1 Propene 41 3.140 3.135 0.005 50 4736 0.2004 0.3379 2 Dichlorodifluoromethane 85 3.193 3.193 0.000 99 11681 0.2004 0.2183 3 Chlorodifluoromethane 51 3.230 3.225 0.005 96 8186 0.2004 0.2690 4 1,2-Dichloro-1,1,2,2-tetra 85 3.412 3.412 0.000 88 11568 0.2004 0.2058 5 Chloromethane 50 3.540 3.535 0.005 99 4805 0.2004 0.2517 6 Butane 43 3.716 3.711 0.005 98 9877 0.2004 0.2995 7 Vinyl chloride 62 3.748 3.748 0.000 96 4597 0.2004 0.1998 8 Butadiene 54 3.817 3.812 0.005 96 3780 0.2004 0.2243 9 BFB 10 Bromomethane 94 4.485 4.479 0.006 98 4677 0.2004 0.1975 11 Chloroethane 64 4.703 4.709 -0.006 43 2778 0.2004 0.1952 12 2-Methylbutane 43 4.799 4.789 0.010 97 6818 0.2004 0.2274 13 Vinyl bromide 106 5.125 5.120 0.005 98 4437 0.2004 0.1837 14 Trichlorofluoromethane 101 5.216 5.216 0.000 98 11662 0.2004 0.2042 15 Pentane 43 5.360 5.355 0.005 97 12480 0.2004 0.2738 16 Ethanol 45 5.691 5.675 0.016 100 7428 0.4009 0.5947 17 Ethyl ether 59 5.840 5.830 0.010 91 3577 0.2004 0.2037 18 Acrolein 56 6.203 6.198 0.005 52 2573 0.2004 0.3171 19 1,1,2-Trichloro-1,2,2-trif 101 6.256 6.246 0.010 95 9738 0.2004 0.2029 20 1,1-Dichloroethene 96 6.320 6.321 -0.001 96 4785 0.2004 0.1991 21 Acetone 43 6.481 6.470 0.011 97 36770 0.2004 1.02 22 Isopropyl alcohol 45 6.710 6.684 0.026 98 10339 0.2004 0.2565 23 Carbon disulfide 76 6.747 6.748 -0.001 98 13784 0.2004 0.2047 24 3-Chloro-1-propene 41 7.009 7.020 -0.011 92 6237 0.2004 0.1860 26 Acetonitrile 41 7.084 7.079 0.005 98 5436 0.2004 0.2625 27 Methylene Chloride 49 7.276 7.276 0.000 92 6991 0.2004 0.2429 28 2-Methyl-2-propanol 59 7.409 7.388 0.021 94 11135 0.2004 0.2119 29 Methyl tert-butyl ether 73 7.665 7.628 0.037 97 14248 0.2004 0.1990 30 trans-1,2-Dichloroethene 61 7.687 7.687 0.000 97 7228 0.2004 0.1983 31 Acrylonitrile 53 7.761 7.756 0.005 87 3821 0.2004 0.1986 Page 321 of 478 Report Date: 07-Nov-2017 13:39:39 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-05.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 Hexane 57 8.012 8.018 -0.006 93 10775 0.2004 0.2457 33 1,1-Dichloroethane 63 8.423 8.429 -0.006 98 10340 0.2004 0.2121 34 Vinyl acetate 43 8.445 8.434 0.011 100 12490 0.2004 0.1861 36 2-Butanone (MEK) 72 9.336 9.320 0.016 97 4450 0.2004 0.3146 37 cis-1,2-Dichloroethene 96 9.325 9.331 -0.006 54 5366 0.2004 0.1932 35 Ethyl acetate 88 9.336 ND ND * 39 Chlorobromomethane 128 9.699 9.699 0.000 96 241645 10.0 10.0 38 Tetrahydrofuran 42 9.725 9.710 0.015 95 7217 0.2004 0.2211 40 Chloroform 83 9.773 9.774 -0.001 92 10821 0.2004 0.2078 S 41 1,2-Dichloroethene, Total 61 0 0.4009 0.3915 42 1,1,1-Trichloroethane 97 10.030 10.035 -0.005 94 10372 0.2004 0.2025 43 Cyclohexane 84 10.046 10.046 0.000 98 7379 0.2004 0.1916 44 Carbon tetrachloride 117 10.232 10.243 -0.011 94 9225 0.2004 0.1900 45 Isooctane 57 10.521 10.521 0.000 98 28967 0.2004 0.1986 46 Benzene 78 10.558 10.564 -0.006 95 20758 0.2004 0.2308 47 1,2-Dichloroethane 62 10.665 10.665 0.000 97 6582 0.2004 0.2054 48 n-Heptane 43 10.771 10.777 -0.006 93 12675 0.2004 0.2273 A 49 GRO 1 10.865 (4.779-16.951) 0 6852122 0.2004 0 * 50 1,4-Difluorobenzene 114 11.102 11.102 0.000 94 1223095 10.0 10.0 51 n-Butanol 56 11.321 11.289 0.032 89 7643 0.2004 0.4391 53 Trichloroethene 95 11.476 11.476 0.000 97 7346 0.2004 0.2046 54 1,2-Dichloropropane 63 11.844 11.844 0.000 83 6587 0.2004 0.1903 55 Methyl methacrylate 69 11.892 11.882 0.010 94 5690 0.2004 0.1765 56 1,4-Dioxane 88 11.988 11.967 0.021 91 3786 0.2004 0.2216 57 Dibromomethane 174 12.026 12.031 -0.005 97 7303 0.2004 0.2045 58 Dichlorobromomethane 83 12.196 12.202 -0.006 95 11957 0.2004 0.1978 A 59 TVOC as Toluene 1 12.485 (3.125-21.845) 0 8365975 0.2004 0 60 cis-1,3-Dichloropropene 75 12.831 12.832 -0.001 92 8775 0.2004 0.1796 61 4-Methyl-2-pentanone (MIBK 43 12.992 12.976 0.016 97 13433 0.2004 0.1963 63 n-Octane 43 13.242 13.248 -0.006 92 17287 0.2004 0.2200 64 Toluene 92 13.258 13.264 -0.006 94 13793 0.2004 0.2126 66 trans-1,3-Dichloropropene 75 13.621 13.622 -0.001 98 8203 0.2004 0.1757 67 1,1,2-Trichloroethane 83 13.899 13.894 0.005 57 6233 0.2004 0.1949 M 68 Tetrachloroethene 166 14.032 14.038 -0.006 97 10565 0.2004 0.2056 69 2-Hexanone 43 14.171 14.155 0.016 94 15208 0.2004 0.2349 70 Chlorodibromomethane 129 14.449 14.449 0.000 96 10638 0.2004 0.1744 71 Ethylene Dibromide 107 14.646 14.652 -0.006 99 10271 0.2004 0.1812 * 72 Chlorobenzene-d5 117 15.212 15.212 0.000 85 1085526 10.0 10.0 73 Chlorobenzene 112 15.254 15.255 -0.001 91 16678 0.2004 0.1928 74 Ethylbenzene 91 15.318 15.319 -0.001 98 28583 0.2004 0.2011 75 n-Nonane 57 15.340 15.340 0.000 94 15416 0.2004 0.2118 76 m-Xylene & p-Xylene 106 15.468 15.468 0.000 0 20444 0.4009 0.3652 78 o-Xylene 106 15.980 15.981 -0.001 97 10945 0.2004 0.1965 S 77 Xylenes, Total 106 0 0.6013 0.5617 79 Styrene 104 16.002 16.002 0.000 98 13830 0.2004 0.1648 80 Bromoform 173 16.290 16.295 -0.005 95 7840 0.2004 0.1393 81 Isopropylbenzene 105 16.386 16.391 -0.005 96 30035 0.2004 0.1908 85 1,2,3-Trichloropropane 75 16.877 16.647 0.230 98 12655 0.2004 0.1933 83 1,1,2,2-Tetrachloroethane 83 16.797 16.797 0.000 97 16418 0.2004 0.1918 84 N-Propylbenzene 91 16.872 16.872 0.000 99 36449 0.2004 0.1879 86 n-Decane 57 16.936 16.941 -0.005 89 19233 0.2004 0.2085 87 4-Ethyltoluene 105 16.994 16.995 -0.001 99 28872 0.2004 0.1871 Page 322 of 478 Report Date: 07-Nov-2017 13:39:39 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-05.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 88 2-Chlorotoluene 91 17.037 17.037 0.000 97 24918 0.2004 0.1939 89 1,3,5-Trimethylbenzene 105 17.058 17.064 -0.006 93 24147 0.2004 0.1892 90 Alpha Methyl Styrene 118 17.330 17.336 -0.006 88 9891 0.2004 0.1583 91 tert-Butylbenzene 119 17.432 17.437 -0.005 94 23910 0.2004 0.1937 92 1,2,4-Trimethylbenzene 105 17.507 17.507 0.000 97 23191 0.2004 0.1839 93 sec-Butylbenzene 105 17.693 17.694 -0.001 99 36838 0.2004 0.1923 94 4-Isopropyltoluene 119 17.848 17.848 0.000 97 29214 0.2004 0.1855 95 1,3-Dichlorobenzene 146 17.923 17.928 -0.005 97 13728 0.2004 0.1638 96 1,4-Dichlorobenzene 146 18.035 18.035 0.000 92 12436 0.2004 0.1518 97 Benzyl chloride 91 18.190 18.185 0.005 99 11257 0.2004 0.1202 98 Undecane 57 18.312 18.318 -0.006 96 20829 0.2004 0.2077 99 n-Butylbenzene 91 18.350 18.355 -0.005 98 26745 0.2004 0.1849 100 1,2-Dichlorobenzene 146 18.521 18.521 0.000 97 13609 0.2004 0.1727 102 Dodecane 57 19.769 19.770 -0.001 96 16899 0.2004 0.2179 103 1,2,4-Trichlorobenzene 180 20.885 20.885 0.000 90 5646 0.2004 0.1154 104 Hexachlorobutadiene 225 21.040 21.051 -0.011 96 9995 0.2004 0.1941 105 Naphthalene 128 21.365 21.360 0.005 99 11209 0.2004 0.1085 106 1,2,3-Trichlorobenzene 180 21.835 21.835 0.000 93 6230 0.2004 0.1469 QC Flag LegendProcessing Flags ND - Not Detected or Marked ND Review Flags M - Manually Integrated Reagents: ATTO15CAL1w_00179 Amount Added: 200.00 Units: mL ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 323 of 478 Y ( X 1 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 9 . 6 9 3 ) + * 1 , 4 - D i f l u o r o b e n z e n e ( 1 1 . 1 0 2 ) * C h l o r o b e n z e n e - d 5 ( 1 5 . 2 1 2 ) + Report Date: 07-Nov-2017 13:39:39 Chrom Revision: 2.2 28-Sep-2017 09:29:16Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-05.D Injection Date:06-Nov-2017 18:52:30 Instrument ID:CHB.i Lims ID:ic Client ID: Operator ID:vtp ALS Bottle#:5 Worklist Smp#:5 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 67 1,1,2-Trichloroethane, CAS: 79-00-5Signal: 1 Processing Integration Results RT: 13.90 Area: 3201 Amount: 0.107345 Amount Units: ppb v/v 13.6 13.8 14.0Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 m/z 83.0 Manual Integration Results RT: 13.90 Area: 6233 Amount: 0.194899 Amount Units: ppb v/v 13.6 13.8 14.0Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 m/z 83.0 Reviewer: daiglep, 07-Nov-2017 09:04:29 Audit Action: Manually Integrated Audit Reason: Incomplete Integration Page 325 of 478 Report Date: 07-Nov-2017 13:39:39 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-05.D Injection Date:06-Nov-2017 18:52:30 Instrument ID:CHB.i Lims ID:ic Client ID: Operator ID:vtp ALS Bottle#:5 Worklist Smp#:5 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 67 1,1,2-Trichloroethane, CAS: 79-00-5 Signal: 2 Processing Integration Results RT: 13.89 Area: 0 Amount: 0.107345 Amount Units: ppb v/v 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0Min 0 3 6 9 12 15 18 21 24 27 30 33 36 39 m/z 97.0 Manual Integration Results RT: 13.89 Area: 7230 Amount: 0.194899 Amount Units: ppb v/v 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0Min 0 3 6 9 12 15 18 21 24 27 30 33 36 39 m/z 97.0 Reviewer: daiglep, 07-Nov-2017 09:04:31 Audit Action: Manually Integrated Audit Reason: Incomplete Integration Page 326 of 478 Report Date: 07-Nov-2017 13:39:40 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Manual Integration/User Assign Peak Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-05.D Injection Date:06-Nov-2017 18:52:30 Instrument ID:CHB.i Lims ID:ic Client ID: Operator ID:vtp ALS Bottle#:5 Worklist Smp#:5 Purge Vol:200.000 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Column:RTX-624 ( 0.32 mm)Detector MS SCAN 67 1,1,2-Trichloroethane, CAS: 79-00-5 Signal: 3 Processing Integration Results RT: 13.90 Area: 2112 Amount: 0.107345 Amount Units: ppb v/v 13.6 13.8 14.0Min 0 2 4 6 8 10 12 14 16 18 m/z 85.0 Manual Integration Results RT: 13.90 Area: 3982 Amount: 0.194899 Amount Units: ppb v/v 13.6 13.8 14.0Min 0 2 4 6 8 10 12 14 16 18 m/z 85.0 Reviewer: daiglep, 07-Nov-2017 09:04:33 Audit Action: Manually Integrated Audit Reason: Incomplete Integration Page 327 of 478 Report Date: 07-Nov-2017 13:39:47 Chrom Revision: 2.2 28-Sep-2017 09:29:16 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-07.D Lims ID:ic Client ID: Sample Type:IC Calib Level:3 Inject. Date:06-Nov-2017 20:36:30 ALS Bottle#:7 Worklist Smp#:7 Purge Vol:200.000 mL Dil. Factor:1.0000 Sample Info:200-0027754-007 Misc. Info.:ic Operator ID:vtp Instrument ID:CHB.i Sublist:chrom-TO15_LLNJ_TO3*sub5 Method:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:07-Nov-2017 13:39:46 Calib Date:07-Nov-2017 01:49:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal/External Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: daiglep Date:07-Nov-2017 08:58:36 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 1 Propene 41 3.140 3.135 0.005 96 9005 0.5005 0.6442 2 Dichlorodifluoromethane 85 3.199 3.193 0.006 99 27637 0.5005 0.5178 3 Chlorodifluoromethane 51 3.231 3.225 0.006 97 16962 0.5005 0.5588 4 1,2-Dichloro-1,1,2,2-tetra 85 3.412 3.412 0.000 91 28521 0.5005 0.5088 5 Chloromethane 50 3.540 3.535 0.005 98 10035 0.5005 0.5271 6 Butane 43 3.711 3.711 0.000 98 18787 0.5005 0.5712 7 Vinyl chloride 62 3.748 3.748 0.000 97 11608 0.5005 0.5060 8 Butadiene 54 3.823 3.812 0.011 96 8740 0.5005 0.5200 10 Bromomethane 94 4.479 4.479 0.000 96 10970 0.5005 0.4644 9 BFB 11 Chloroethane 64 4.709 4.709 0.000 96 7142 0.5005 0.5033 12 2-Methylbutane 43 4.794 4.789 0.005 94 15414 0.5005 0.5155 13 Vinyl bromide 106 5.120 5.120 0.000 97 10998 0.5005 0.4566 14 Trichlorofluoromethane 101 5.216 5.216 0.000 98 28350 0.5005 0.4977 15 Pentane 43 5.360 5.355 0.005 97 24884 0.5005 0.5475 16 Ethanol 45 5.675 5.675 0.000 98 78001 5.01 6.26 17 Ethyl ether 59 5.851 5.830 0.021 89 8140 0.5005 0.4647 18 Acrolein 56 6.209 6.198 0.011 65 5099 0.5005 0.6301 19 1,1,2-Trichloro-1,2,2-trif 101 6.241 6.246 -0.005 95 23175 0.5005 0.4842 20 1,1-Dichloroethene 96 6.315 6.321 -0.006 96 11165 0.5005 0.4659 21 Acetone 43 6.481 6.470 0.011 97 39306 0.5005 1.10 22 Isopropyl alcohol 45 6.705 6.684 0.021 99 20154 0.5005 0.5013 23 Carbon disulfide 76 6.748 6.748 0.000 98 32704 0.5005 0.4869 24 3-Chloro-1-propene 41 7.020 7.020 0.000 94 17782 0.5005 0.5317 26 Acetonitrile 41 7.084 7.079 0.005 96 11438 0.5005 0.5537 27 Methylene Chloride 49 7.271 7.276 -0.005 97 15430 0.5005 0.5375 28 2-Methyl-2-propanol 59 7.409 7.388 0.021 94 24805 0.5005 0.4732 29 Methyl tert-butyl ether 73 7.644 7.628 0.016 98 35044 0.5005 0.4907 30 trans-1,2-Dichloroethene 61 7.687 7.687 0.000 99 18104 0.5005 0.4979 31 Acrylonitrile 53 7.767 7.756 0.011 94 9113 0.5005 0.4750 Page 328 of 478 Report Date: 07-Nov-2017 13:39:47 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-07.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 Hexane 57 8.012 8.018 -0.006 95 22455 0.5005 0.5134 33 1,1-Dichloroethane 63 8.423 8.429 -0.006 99 23477 0.5005 0.4829 34 Vinyl acetate 43 8.439 8.434 0.005 100 32250 0.5005 0.4819 36 2-Butanone (MEK) 72 9.331 9.320 0.011 96 7175 0.5005 0.5086 37 cis-1,2-Dichloroethene 96 9.331 9.331 0.000 62 13652 0.5005 0.4929 35 Ethyl acetate 88 9.336 ND ND * 39 Chlorobromomethane 128 9.699 9.699 0.000 97 241003 10.0 10.0 38 Tetrahydrofuran 42 9.726 9.710 0.016 96 16890 0.5005 0.5125 40 Chloroform 83 9.774 9.774 0.000 96 25766 0.5005 0.4961 S 41 1,2-Dichloroethene, Total 61 0 1.00 0.99 42 1,1,1-Trichloroethane 97 10.030 10.035 -0.005 95 24994 0.5005 0.4834 43 Cyclohexane 84 10.041 10.046 -0.005 98 18527 0.5005 0.4764 44 Carbon tetrachloride 117 10.233 10.243 -0.010 96 23344 0.5005 0.4763 45 Isooctane 57 10.521 10.521 0.000 99 69941 0.5005 0.4751 46 Benzene 78 10.564 10.564 0.000 96 43028 0.5005 0.4739 47 1,2-Dichloroethane 62 10.660 10.665 -0.005 95 16172 0.5005 0.5000 48 n-Heptane 43 10.772 10.777 -0.005 95 28219 0.5005 0.5013 A 49 GRO 1 10.865 (4.779-16.951) 0 9755312 0.5005 0 * 50 1,4-Difluorobenzene 114 11.103 11.102 0.001 94 1234746 10.0 10.0 51 n-Butanol 56 11.321 11.289 0.032 92 9644 0.5005 0.5488 53 Trichloroethene 95 11.476 11.476 0.000 98 17501 0.5005 0.4828 54 1,2-Dichloropropane 63 11.839 11.844 -0.005 90 17056 0.5005 0.4881 55 Methyl methacrylate 69 11.882 11.882 0.000 97 14165 0.5005 0.4353 56 1,4-Dioxane 88 11.983 11.967 0.016 97 7977 0.5005 0.4625 57 Dibromomethane 174 12.026 12.031 -0.005 95 16681 0.5005 0.4628 58 Dichlorobromomethane 83 12.202 12.202 0.000 97 29942 0.5005 0.4906 A 59 TVOC as Toluene 1 12.485 (3.125-21.845) 0 13333275 0.5005 0 60 cis-1,3-Dichloropropene 75 12.826 12.832 -0.006 92 23060 0.5005 0.4675 61 4-Methyl-2-pentanone (MIBK 43 12.986 12.976 0.010 97 32590 0.5005 0.4717 63 n-Octane 43 13.243 13.248 -0.005 94 39510 0.5005 0.4980 64 Toluene 92 13.259 13.264 -0.005 93 31753 0.5005 0.4879 66 trans-1,3-Dichloropropene 75 13.622 13.622 0.000 98 21348 0.5005 0.4528 67 1,1,2-Trichloroethane 83 13.894 13.894 0.000 96 15678 0.5005 0.4887 68 Tetrachloroethene 166 14.033 14.038 -0.005 97 24183 0.5005 0.4690 69 2-Hexanone 43 14.161 14.155 0.006 95 31361 0.5005 0.4828 70 Chlorodibromomethane 129 14.449 14.449 0.000 99 27956 0.5005 0.4568 71 Ethylene Dibromide 107 14.646 14.652 -0.006 99 26533 0.5005 0.4667 * 72 Chlorobenzene-d5 117 15.212 15.212 0.000 86 1088970 10.0 10.0 73 Chlorobenzene 112 15.249 15.255 -0.006 96 40862 0.5005 0.4708 74 Ethylbenzene 91 15.319 15.319 0.000 98 68858 0.5005 0.4830 75 n-Nonane 57 15.335 15.340 -0.005 95 34964 0.5005 0.4788 76 m-Xylene & p-Xylene 106 15.463 15.468 -0.005 0 51820 1.00 0.9227 78 o-Xylene 106 15.975 15.981 -0.006 97 26258 0.5005 0.4700 S 77 Xylenes, Total 106 0 1.50 1.39 79 Styrene 104 16.002 16.002 0.000 98 37866 0.5005 0.4498 80 Bromoform 173 16.295 16.295 0.000 97 25278 0.5005 0.4477 81 Isopropylbenzene 105 16.386 16.391 -0.005 96 73623 0.5005 0.4661 85 1,2,3-Trichloropropane 75 16.882 16.647 0.235 97 31857 0.5005 0.4851 83 1,1,2,2-Tetrachloroethane 83 16.797 16.797 0.000 97 41145 0.5005 0.4791 84 N-Propylbenzene 91 16.866 16.872 -0.006 99 90532 0.5005 0.4652 86 n-Decane 57 16.936 16.941 -0.005 89 46234 0.5005 0.4997 87 4-Ethyltoluene 105 16.995 16.995 0.000 98 71488 0.5005 0.4617 Page 329 of 478 Report Date: 07-Nov-2017 13:39:47 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-07.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 88 2-Chlorotoluene 91 17.032 17.037 -0.005 97 60006 0.5005 0.4655 89 1,3,5-Trimethylbenzene 105 17.059 17.064 -0.005 92 59606 0.5005 0.4656 90 Alpha Methyl Styrene 118 17.331 17.336 -0.005 88 28073 0.5005 0.4478 91 tert-Butylbenzene 119 17.432 17.437 -0.005 95 57783 0.5005 0.4667 92 1,2,4-Trimethylbenzene 105 17.502 17.507 -0.005 98 59289 0.5005 0.4688 93 sec-Butylbenzene 105 17.688 17.694 -0.006 99 91707 0.5005 0.4771 94 4-Isopropyltoluene 119 17.843 17.848 -0.005 98 73963 0.5005 0.4682 95 1,3-Dichlorobenzene 146 17.923 17.928 -0.005 98 38771 0.5005 0.4612 96 1,4-Dichlorobenzene 146 18.035 18.035 0.000 96 38663 0.5005 0.4703 97 Benzyl chloride 91 18.185 18.185 0.000 98 42398 0.5005 0.4512 98 Undecane 57 18.318 18.318 0.000 97 48082 0.5005 0.4778 99 n-Butylbenzene 91 18.350 18.355 -0.005 98 69356 0.5005 0.4780 100 1,2-Dichlorobenzene 146 18.521 18.521 0.000 96 37002 0.5005 0.4681 102 Dodecane 57 19.770 19.770 0.000 95 40649 0.5005 0.5225 103 1,2,4-Trichlorobenzene 180 20.880 20.885 -0.005 93 20073 0.5005 0.4090 104 Hexachlorobutadiene 225 21.040 21.051 -0.011 97 24771 0.5005 0.4795 105 Naphthalene 128 21.365 21.360 0.005 99 45302 0.5005 0.4369 106 1,2,3-Trichlorobenzene 180 21.835 21.835 0.000 94 18238 0.5005 0.4287 QC Flag LegendProcessing Flags ND - Not Detected or Marked ND Reagents: ATTO15CAL2w_00245 Amount Added: 200.00 Units: mL ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 330 of 478 Y ( X 1 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 9 . 6 9 4 ) + * 1 , 4 - D i f l u o r o b e n z e n e ( 1 1 . 1 0 3 ) * C h l o r o b e n z e n e - d 5 ( 1 5 . 2 1 2 ) + Report Date: 07-Nov-2017 13:39:54 Chrom Revision: 2.2 28-Sep-2017 09:29:16 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-09.D Lims ID:ic Client ID: Sample Type:IC Calib Level:4 Inject. Date:06-Nov-2017 22:20:30 ALS Bottle#:9 Worklist Smp#:9 Purge Vol:200.000 mL Dil. Factor:1.0000 Sample Info:200-0027754-009 Misc. Info.:ic Operator ID:vtp Instrument ID:CHB.i Sublist:chrom-TO15_LLNJ_TO3*sub5 Method:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:07-Nov-2017 13:39:53 Calib Date:07-Nov-2017 01:49:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal/External Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: daiglep Date:07-Nov-2017 08:59:12 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 1 Propene 41 3.135 3.135 0.000 99 94270 4.99 6.74 2 Dichlorodifluoromethane 85 3.193 3.193 0.000 99 328049 4.99 6.14 3 Chlorodifluoromethane 51 3.231 3.225 0.006 97 192442 4.99 6.34 4 1,2-Dichloro-1,1,2,2-tetra 85 3.412 3.412 0.000 90 329585 4.99 5.88 5 Chloromethane 50 3.540 3.535 0.005 99 119627 4.99 6.28 6 Butane 43 3.711 3.711 0.000 99 207906 4.99 6.32 7 Vinyl chloride 62 3.748 3.748 0.000 98 139669 4.99 6.08 8 Butadiene 54 3.818 3.812 0.006 98 105361 4.99 6.26 9 BFB 10 Bromomethane 94 4.485 4.479 0.006 99 131944 4.99 5.58 11 Chloroethane 64 4.709 4.709 0.000 100 81341 4.99 5.73 12 2-Methylbutane 43 4.794 4.789 0.005 95 179718 4.99 6.01 13 Vinyl bromide 106 5.120 5.120 0.000 99 134098 4.99 5.56 14 Trichlorofluoromethane 101 5.221 5.216 0.005 98 329662 4.99 5.78 15 Pentane 43 5.355 5.355 0.000 96 277962 4.99 6.11 16 Ethanol 45 5.675 5.675 0.000 99 149824 10.0 12.0 17 Ethyl ether 59 5.835 5.830 0.005 94 103447 4.99 5.90 18 Acrolein 56 6.198 6.198 0.000 96 45692 4.99 5.64 19 1,1,2-Trichloro-1,2,2-trif 101 6.246 6.246 0.000 96 269917 4.99 5.64 20 1,1-Dichloroethene 96 6.315 6.321 -0.006 96 135100 4.99 5.63 21 Acetone 43 6.470 6.470 0.000 98 236842 4.99 6.61 22 Isopropyl alcohol 45 6.684 6.684 0.000 100 252112 4.99 6.27 23 Carbon disulfide 76 6.748 6.748 0.000 99 389595 4.99 5.80 24 3-Chloro-1-propene 41 7.015 7.020 -0.006 93 211903 4.99 6.33 26 Acetonitrile 41 7.079 7.079 0.000 99 128629 4.99 6.22 27 Methylene Chloride 49 7.276 7.276 0.000 97 173856 4.99 6.05 28 2-Methyl-2-propanol 59 7.383 7.388 -0.005 94 313150 4.99 5.97 29 Methyl tert-butyl ether 73 7.628 7.628 0.000 98 414586 4.99 5.80 30 trans-1,2-Dichloroethene 61 7.687 7.687 0.000 98 217279 4.99 5.97 31 Acrylonitrile 53 7.756 7.756 0.000 96 115020 4.99 5.99 Page 332 of 478 Report Date: 07-Nov-2017 13:39:54 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-09.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 Hexane 57 8.018 8.018 0.000 95 247350 4.99 5.65 33 1,1-Dichloroethane 63 8.429 8.429 0.000 99 286623 4.99 5.89 34 Vinyl acetate 43 8.434 8.434 0.000 100 415040 4.99 6.20 36 2-Butanone (MEK) 72 9.315 9.320 -0.005 100 80752 4.99 5.72 37 cis-1,2-Dichloroethene 96 9.331 9.331 0.000 95 160947 4.99 5.81 35 Ethyl acetate 88 9.331 9.336 -0.005 92 12961 4.99 5.56 * 39 Chlorobromomethane 128 9.699 9.699 0.000 97 241168 10.0 10.0 38 Tetrahydrofuran 42 9.715 9.710 0.005 97 202420 4.99 6.19 40 Chloroform 83 9.774 9.774 0.000 95 302854 4.99 5.83 S 41 1,2-Dichloroethene, Total 61 0 9.99 11.8 42 1,1,1-Trichloroethane 97 10.035 10.035 0.000 96 296136 4.99 5.77 43 Cyclohexane 84 10.046 10.046 0.000 98 215268 4.99 5.58 44 Carbon tetrachloride 117 10.238 10.243 -0.005 98 296544 4.99 6.10 45 Isooctane 57 10.521 10.521 0.000 99 854191 4.99 5.85 46 Benzene 78 10.564 10.564 0.000 96 493843 4.99 5.48 47 1,2-Dichloroethane 62 10.660 10.665 -0.005 96 193741 4.99 6.04 48 n-Heptane 43 10.772 10.777 -0.005 94 333367 4.99 5.97 A 49 GRO 1 10.865 (4.779-16.951) 0 67780240 4.99 0 * 50 1,4-Difluorobenzene 114 11.103 11.102 0.001 94 1224793 10.0 10.0 51 n-Butanol 56 11.289 11.289 0.000 88 101995 4.99 5.85 53 Trichloroethene 95 11.476 11.476 0.000 98 207050 4.99 5.76 54 1,2-Dichloropropane 63 11.844 11.844 0.000 95 203574 4.99 5.87 55 Methyl methacrylate 69 11.882 11.882 0.000 96 185277 4.99 5.74 56 1,4-Dioxane 88 11.972 11.967 0.005 95 98539 4.99 5.76 57 Dibromomethane 174 12.031 12.031 0.000 98 191845 4.99 5.37 58 Dichlorobromomethane 83 12.202 12.202 0.000 98 352531 4.99 5.82 A 59 TVOC as Toluene 1 12.485 (3.125-21.845) 0 108224039 4.99 0 60 cis-1,3-Dichloropropene 75 12.832 12.832 0.000 92 285608 4.99 5.84 61 4-Methyl-2-pentanone (MIBK 43 12.976 12.976 0.000 97 424306 4.99 6.19 63 n-Octane 43 13.248 13.248 0.000 94 480047 4.99 6.10 64 Toluene 92 13.259 13.264 -0.005 93 362352 4.99 5.47 66 trans-1,3-Dichloropropene 75 13.622 13.622 0.000 97 276675 4.99 5.92 67 1,1,2-Trichloroethane 83 13.894 13.894 0.000 96 185969 4.99 5.70 68 Tetrachloroethene 166 14.033 14.038 -0.005 98 287651 4.99 5.49 69 2-Hexanone 43 14.155 14.155 0.000 94 406329 4.99 6.15 70 Chlorodibromomethane 129 14.449 14.449 0.000 99 358608 4.99 5.76 71 Ethylene Dibromide 107 14.652 14.652 0.000 98 327996 4.99 5.67 * 72 Chlorobenzene-d5 117 15.212 15.212 0.000 86 1107460 10.0 10.0 73 Chlorobenzene 112 15.249 15.255 -0.006 95 486827 4.99 5.52 74 Ethylbenzene 91 15.319 15.319 0.000 98 802931 4.99 5.54 75 n-Nonane 57 15.340 15.340 0.000 95 432179 4.99 5.82 76 m-Xylene & p-Xylene 106 15.468 15.468 0.000 0 628058 9.99 11.0 78 o-Xylene 106 15.981 15.981 0.000 98 312634 4.99 5.50 S 77 Xylenes, Total 106 0 15.0 16.5 79 Styrene 104 16.002 16.002 0.000 99 475931 4.99 5.56 80 Bromoform 173 16.295 16.295 0.000 97 340328 4.99 5.93 81 Isopropylbenzene 105 16.391 16.391 0.000 96 900374 4.99 5.61 85 1,2,3-Trichloropropane 75 16.877 16.647 0.230 98 386627 4.99 5.79 83 1,1,2,2-Tetrachloroethane 83 16.797 16.797 0.000 97 501706 4.99 5.74 84 N-Propylbenzene 91 16.866 16.872 -0.006 99 1137310 4.99 5.75 86 n-Decane 57 16.936 16.941 -0.005 88 567864 4.99 6.04 87 4-Ethyltoluene 105 16.995 16.995 0.000 98 887867 4.99 5.64 Page 333 of 478 Report Date: 07-Nov-2017 13:39:54 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-09.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 88 2-Chlorotoluene 91 17.037 17.037 0.000 96 747078 4.99 5.70 89 1,3,5-Trimethylbenzene 105 17.059 17.064 -0.005 93 738489 4.99 5.67 90 Alpha Methyl Styrene 118 17.331 17.336 -0.005 89 363985 4.99 5.71 91 tert-Butylbenzene 119 17.437 17.437 0.000 96 722005 4.99 5.73 92 1,2,4-Trimethylbenzene 105 17.507 17.507 0.000 97 743964 4.99 5.78 93 sec-Butylbenzene 105 17.694 17.694 0.000 99 1133717 4.99 5.80 94 4-Isopropyltoluene 119 17.843 17.848 -0.005 98 931887 4.99 5.80 95 1,3-Dichlorobenzene 146 17.923 17.928 -0.005 98 482419 4.99 5.64 96 1,4-Dichlorobenzene 146 18.035 18.035 0.000 95 473120 4.99 5.66 97 Benzyl chloride 91 18.185 18.185 0.000 99 581535 4.99 6.09 98 Undecane 57 18.318 18.318 0.000 97 612517 4.99 5.99 99 n-Butylbenzene 91 18.350 18.355 -0.005 98 876363 4.99 5.94 100 1,2-Dichlorobenzene 146 18.521 18.521 0.000 96 459422 4.99 5.71 102 Dodecane 57 19.770 19.770 0.000 96 483798 4.99 6.12 103 1,2,4-Trichlorobenzene 180 20.880 20.885 -0.005 94 240031 4.99 4.81 104 Hexachlorobutadiene 225 21.051 21.051 0.000 98 295106 4.99 5.62 105 Naphthalene 128 21.360 21.360 0.000 99 473935 4.99 4.49 106 1,2,3-Trichlorobenzene 180 21.835 21.835 0.000 95 216879 4.99 5.01 Reagents: ATTO15CAL3w_00188 Amount Added: 200.00 Units: mL ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 334 of 478 Y ( X 1 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 9 . 7 0 4 ) + * 1 , 4 - D i f l u o r o b e n z e n e ( 1 1 . 1 0 3 ) * C h l o r o b e n z e n e - d 5 ( 1 5 . 2 1 2 ) + Report Date: 07-Nov-2017 13:39:56 Chrom Revision: 2.2 28-Sep-2017 09:29:16 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-10.D Lims ID:icis Client ID: Sample Type:ICIS Calib Level:5 Inject. Date:06-Nov-2017 23:12:30 ALS Bottle#:10 Worklist Smp#:10 Purge Vol:200.000 mL Dil. Factor:1.0000 Sample Info:200-0027754-010 Misc. Info.:icis Operator ID:vtp Instrument ID:CHB.i Sublist:chrom-TO15_LLNJ_TO3*sub5 Method:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:07-Nov-2017 13:39:55 Calib Date:07-Nov-2017 01:49:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal/External Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: daiglep Date:07-Nov-2017 08:52:42 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 1 Propene 41 3.135 3.135 0.000 99 178752 10.0 11.4 2 Dichlorodifluoromethane 85 3.193 3.193 0.000 99 669500 10.0 11.2 3 Chlorodifluoromethane 51 3.225 3.225 0.000 97 378485 10.0 11.1 4 1,2-Dichloro-1,1,2,2-tetra 85 3.412 3.412 0.000 89 690355 10.0 11.0 5 Chloromethane 50 3.535 3.535 0.000 99 239308 10.0 11.2 6 Butane 43 3.711 3.711 0.000 99 410042 10.0 11.1 7 Vinyl chloride 62 3.748 3.748 0.000 98 291466 10.0 11.3 8 Butadiene 54 3.812 3.812 0.000 96 219553 10.0 11.6 10 Bromomethane 94 4.479 4.479 0.000 99 290018 10.0 10.9 9 BFB 11 Chloroethane 64 4.709 4.709 0.000 100 172230 10.0 10.8 12 2-Methylbutane 43 4.789 4.789 0.000 95 366461 10.0 10.9 13 Vinyl bromide 106 5.120 5.120 0.000 100 293593 10.0 10.8 14 Trichlorofluoromethane 101 5.216 5.216 0.000 98 687404 10.0 10.7 15 Pentane 43 5.355 5.355 0.000 96 555873 10.0 10.9 16 Ethanol 45 5.675 5.675 0.000 99 218031 15.0 15.6 17 Ethyl ether 59 5.830 5.830 0.000 94 214038 10.0 10.9 18 Acrolein 56 6.198 6.198 0.000 95 96696 10.0 10.6 19 1,1,2-Trichloro-1,2,2-trif 101 6.246 6.246 0.000 97 565202 10.0 10.5 20 1,1-Dichloroethene 96 6.321 6.321 0.000 97 279844 10.0 10.4 21 Acetone 43 6.470 6.470 0.000 97 446021 10.0 11.1 22 Isopropyl alcohol 45 6.684 6.684 0.000 99 511783 10.0 11.3 23 Carbon disulfide 76 6.748 6.748 0.000 99 805496 10.0 10.7 24 3-Chloro-1-propene 41 7.020 7.020 0.000 93 415357 10.0 11.1 26 Acetonitrile 41 7.079 7.079 0.000 99 254873 10.0 11.0 27 Methylene Chloride 49 7.276 7.276 0.000 96 351310 10.0 10.9 28 2-Methyl-2-propanol 59 7.388 7.388 0.000 93 654836 10.0 11.1 29 Methyl tert-butyl ether 73 7.628 7.628 0.000 98 862467 10.0 10.7 30 trans-1,2-Dichloroethene 61 7.687 7.687 0.000 99 441740 10.0 10.8 31 Acrylonitrile 53 7.756 7.756 0.000 96 237313 10.0 11.0 Page 336 of 478 Report Date: 07-Nov-2017 13:39:56 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-10.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 Hexane 57 8.018 8.018 0.000 94 501161 10.0 10.2 33 1,1-Dichloroethane 63 8.429 8.429 0.000 99 583546 10.0 10.7 34 Vinyl acetate 43 8.434 8.434 0.000 100 839222 10.0 11.2 36 2-Butanone (MEK) 72 9.320 9.320 0.000 100 166254 10.0 10.5 37 cis-1,2-Dichloroethene 96 9.331 9.331 0.000 96 336303 10.0 10.8 35 Ethyl acetate 88 9.336 9.336 0.000 92 26960 10.0 10.3 * 39 Chlorobromomethane 128 9.704 9.704 0.000 97 270834 10.0 10.0 38 Tetrahydrofuran 42 9.710 9.710 0.000 96 402366 10.0 11.1 40 Chloroform 83 9.774 9.774 0.000 96 620796 10.0 10.6 S 41 1,2-Dichloroethene, Total 61 0 20.0 21.6 42 1,1,1-Trichloroethane 97 10.035 10.035 0.000 96 602834 10.0 10.6 43 Cyclohexane 84 10.046 10.046 0.000 98 451412 10.0 10.5 44 Carbon tetrachloride 117 10.243 10.243 0.000 98 610969 10.0 11.3 45 Isooctane 57 10.521 10.521 0.000 99 1753387 10.0 10.8 46 Benzene 78 10.564 10.564 0.000 96 1023623 10.0 10.2 47 1,2-Dichloroethane 62 10.665 10.665 0.000 96 384279 10.0 10.8 48 n-Heptane 43 10.777 10.777 0.000 93 663081 10.0 10.7 A 49 GRO 1 10.865 (4.779-16.951) 0 135949929 10.0 0 * 50 1,4-Difluorobenzene 114 11.108 11.108 0.000 94 1363371 10.0 10.0 51 n-Butanol 56 11.289 11.289 0.000 89 207031 10.0 10.7 53 Trichloroethene 95 11.476 11.476 0.000 98 432058 10.0 10.8 54 1,2-Dichloropropane 63 11.844 11.844 0.000 94 415515 10.0 10.8 55 Methyl methacrylate 69 11.882 11.882 0.000 96 384997 10.0 10.7 56 1,4-Dioxane 88 11.967 11.967 0.000 94 206434 10.0 10.8 57 Dibromomethane 174 12.031 12.031 0.000 97 412753 10.0 10.4 58 Dichlorobromomethane 83 12.202 12.202 0.000 97 715566 10.0 10.6 A 59 TVOC as Toluene 1 12.485 (3.125-21.845) 0 221248223 10.0 0 60 cis-1,3-Dichloropropene 75 12.832 12.832 0.000 91 590668 10.0 10.8 61 4-Methyl-2-pentanone (MIBK 43 12.976 12.976 0.000 96 847377 10.0 11.1 63 n-Octane 43 13.248 13.248 0.000 93 959417 10.0 11.0 64 Toluene 92 13.264 13.264 0.000 93 753577 10.0 10.1 66 trans-1,3-Dichloropropene 75 13.622 13.622 0.000 96 575307 10.0 11.1 67 1,1,2-Trichloroethane 83 13.894 13.894 0.000 95 383516 10.0 10.4 68 Tetrachloroethene 166 14.038 14.038 0.000 98 613429 10.0 10.4 69 2-Hexanone 43 14.155 14.155 0.000 94 815397 10.0 11.0 70 Chlorodibromomethane 129 14.449 14.449 0.000 98 734000 10.0 10.5 71 Ethylene Dibromide 107 14.652 14.652 0.000 98 689766 10.0 10.6 * 72 Chlorobenzene-d5 117 15.212 15.212 0.000 87 1246413 10.0 10.0 73 Chlorobenzene 112 15.255 15.255 0.000 95 1028944 10.0 10.4 74 Ethylbenzene 91 15.319 15.319 0.000 98 1694195 10.0 10.4 75 n-Nonane 57 15.340 15.340 0.000 93 886988 10.0 10.6 76 m-Xylene & p-Xylene 106 15.468 15.468 0.000 0 1339356 20.0 20.8 78 o-Xylene 106 15.981 15.981 0.000 98 659664 10.0 10.3 S 77 Xylenes, Total 106 0 30.0 31.2 79 Styrene 104 16.002 16.002 0.000 98 1035340 10.0 10.7 80 Bromoform 173 16.295 16.295 0.000 98 664355 10.0 10.3 81 Isopropylbenzene 105 16.391 16.391 0.000 95 1896589 10.0 10.5 85 1,2,3-Trichloropropane 75 16.882 16.882 0.000 98 801515 10.0 10.7 83 1,1,2,2-Tetrachloroethane 83 16.797 16.797 0.000 97 1054405 10.0 10.7 84 N-Propylbenzene 91 16.872 16.872 0.000 99 2394240 10.0 10.7 86 n-Decane 57 16.941 16.941 0.000 89 1164188 10.0 11.0 87 4-Ethyltoluene 105 16.995 16.995 0.000 98 1896619 10.0 10.7 Page 337 of 478 Report Date: 07-Nov-2017 13:39:56 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-10.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 88 2-Chlorotoluene 91 17.037 17.037 0.000 97 1576394 10.0 10.7 89 1,3,5-Trimethylbenzene 105 17.064 17.064 0.000 93 1575121 10.0 10.8 90 Alpha Methyl Styrene 118 17.336 17.336 0.000 90 792287 10.0 11.0 91 tert-Butylbenzene 119 17.437 17.437 0.000 95 1515083 10.0 10.7 92 1,2,4-Trimethylbenzene 105 17.507 17.507 0.000 97 1580281 10.0 10.9 93 sec-Butylbenzene 105 17.694 17.694 0.000 99 2372305 10.0 10.8 94 4-Isopropyltoluene 119 17.848 17.848 0.000 98 1955482 10.0 10.8 95 1,3-Dichlorobenzene 146 17.928 17.928 0.000 97 1052014 10.0 10.9 96 1,4-Dichlorobenzene 146 18.035 18.035 0.000 96 1038211 10.0 11.0 97 Benzyl chloride 91 18.185 18.185 0.000 99 1273643 10.0 11.8 98 Undecane 57 18.318 18.318 0.000 97 1200999 10.0 10.4 99 n-Butylbenzene 91 18.355 18.355 0.000 98 1781253 10.0 10.7 100 1,2-Dichlorobenzene 146 18.521 18.521 0.000 97 983042 10.0 10.9 102 Dodecane 57 19.770 19.770 0.000 96 994023 10.0 11.2 103 1,2,4-Trichlorobenzene 180 20.885 20.885 0.000 94 577428 10.0 10.3 104 Hexachlorobutadiene 225 21.051 21.051 0.000 99 608010 10.0 10.3 105 Naphthalene 128 21.360 21.360 0.000 99 1190473 10.0 10.0 106 1,2,3-Trichlorobenzene 180 21.835 21.835 0.000 95 513047 10.0 10.5 Reagents: ATTO15CAL4w_00645 Amount Added: 200.00 Units: mL ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 338 of 478 Y ( X 1 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 9 . 7 0 4 ) + * 1 , 4 - D i f l u o r o b e n z e n e ( 1 1 . 1 0 8 ) * C h l o r o b e n z e n e - d 5 ( 1 5 . 2 1 2 ) Report Date: 07-Nov-2017 13:39:58 Chrom Revision: 2.2 28-Sep-2017 09:29:16 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-11.D Lims ID:ic Client ID: Sample Type:IC Calib Level:6 Inject. Date:07-Nov-2017 00:05:30 ALS Bottle#:11 Worklist Smp#:11 Purge Vol:200.000 mL Dil. Factor:1.0000 Sample Info:200-0027754-011 Misc. Info.:ic Operator ID:vtp Instrument ID:CHB.i Sublist:chrom-TO15_LLNJ_TO3*sub5 Method:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:07-Nov-2017 13:39:57 Calib Date:07-Nov-2017 01:49:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal/External Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: daiglep Date:07-Nov-2017 09:06:12 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 1 Propene 41 3.135 3.135 0.000 99 262308 15.0 14.2 2 Dichlorodifluoromethane 85 3.193 3.193 0.000 99 1012917 15.0 14.4 3 Chlorodifluoromethane 51 3.231 3.225 0.006 97 562365 15.0 14.0 4 1,2-Dichloro-1,1,2,2-tetra 85 3.412 3.412 0.000 95 1075928 15.0 14.6 5 Chloromethane 50 3.540 3.535 0.005 99 359553 15.0 14.3 6 Butane 43 3.711 3.711 0.000 99 609191 15.0 14.0 7 Vinyl chloride 62 3.748 3.748 0.000 98 457798 15.0 15.1 8 Butadiene 54 3.812 3.812 0.000 95 335437 15.0 15.1 9 BFB 10 Bromomethane 94 4.479 4.479 0.000 99 466967 15.0 15.0 11 Chloroethane 64 4.709 4.709 0.000 99 274839 15.0 14.7 12 2-Methylbutane 43 4.794 4.789 0.005 94 557524 15.0 14.1 13 Vinyl bromide 106 5.120 5.120 0.000 100 485880 15.0 15.3 14 Trichlorofluoromethane 101 5.221 5.216 0.005 98 1103290 15.0 14.7 15 Pentane 43 5.355 5.355 0.000 96 857492 15.0 14.3 16 Ethanol 45 5.680 5.675 0.005 99 322355 20.0 19.6 17 Ethyl ether 59 5.830 5.830 0.000 95 344829 15.0 14.9 18 Acrolein 56 6.198 6.198 0.000 94 159278 15.0 14.9 19 1,1,2-Trichloro-1,2,2-trif 101 6.251 6.246 0.005 98 931730 15.0 14.8 20 1,1-Dichloroethene 96 6.321 6.321 0.000 98 463386 15.0 14.7 21 Acetone 43 6.470 6.470 0.000 97 679222 15.0 14.4 22 Isopropyl alcohol 45 6.689 6.684 0.005 99 775787 15.0 14.6 23 Carbon disulfide 76 6.753 6.748 0.005 98 1303321 15.0 14.7 24 3-Chloro-1-propene 41 7.020 7.020 0.000 94 630248 15.0 14.3 26 Acetonitrile 41 7.079 7.079 0.000 100 400394 15.0 14.7 27 Methylene Chloride 49 7.281 7.276 0.005 94 543530 15.0 14.4 28 2-Methyl-2-propanol 59 7.388 7.388 0.000 93 1026121 15.0 14.8 29 Methyl tert-butyl ether 73 7.628 7.628 0.000 97 1398096 15.0 14.8 30 trans-1,2-Dichloroethene 61 7.687 7.687 0.000 98 700935 15.0 14.6 31 Acrylonitrile 53 7.756 7.756 0.000 95 374931 15.0 14.8 Page 340 of 478 Report Date: 07-Nov-2017 13:39:58 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-11.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 Hexane 57 8.018 8.018 0.000 93 800225 15.0 13.9 33 1,1-Dichloroethane 63 8.429 8.429 0.000 99 924957 15.0 14.4 34 Vinyl acetate 43 8.434 8.434 0.000 100 1291360 15.0 14.6 36 2-Butanone (MEK) 72 9.320 9.320 0.000 100 274656 15.0 14.8 37 cis-1,2-Dichloroethene 96 9.336 9.331 0.005 95 549204 15.0 15.0 35 Ethyl acetate 88 9.336 9.336 0.000 93 45156 15.0 14.7 * 39 Chlorobromomethane 128 9.704 9.704 0.000 95 317897 10.0 10.0 38 Tetrahydrofuran 42 9.710 9.710 0.000 95 611226 15.0 14.6 40 Chloroform 83 9.774 9.774 0.000 95 998358 15.0 14.6 S 41 1,2-Dichloroethene, Total 61 0 30.0 29.6 42 1,1,1-Trichloroethane 97 10.035 10.035 0.000 95 973905 15.0 14.8 43 Cyclohexane 84 10.051 10.046 0.005 98 744741 15.0 15.1 44 Carbon tetrachloride 117 10.243 10.243 0.000 97 979389 15.0 15.7 45 Isooctane 57 10.521 10.521 0.000 100 2785353 15.0 14.9 46 Benzene 78 10.564 10.564 0.000 95 1663189 15.0 14.4 47 1,2-Dichloroethane 62 10.665 10.665 0.000 96 601835 15.0 14.6 48 n-Heptane 43 10.777 10.777 0.000 92 1018472 15.0 14.2 A 49 GRO 1 10.865 (4.779-16.951) 0 212504719 15.0 0 * 50 1,4-Difluorobenzene 114 11.108 11.108 0.000 94 1568827 10.0 10.0 51 n-Butanol 56 11.289 11.289 0.000 86 330651 15.0 14.8 53 Trichloroethene 95 11.476 11.476 0.000 98 705472 15.0 15.3 54 1,2-Dichloropropane 63 11.844 11.844 0.000 93 660207 15.0 14.9 55 Methyl methacrylate 69 11.882 11.882 0.000 97 626224 15.0 15.1 56 1,4-Dioxane 88 11.972 11.967 0.005 93 320238 15.0 14.6 57 Dibromomethane 174 12.031 12.031 0.000 96 679826 15.0 14.8 58 Dichlorobromomethane 83 12.207 12.202 0.005 98 1139481 15.0 14.7 A 59 TVOC as Toluene 1 12.485 (3.125-21.845) 0 348003400 15.0 0 60 cis-1,3-Dichloropropene 75 12.832 12.832 0.000 90 955016 15.0 15.2 61 4-Methyl-2-pentanone (MIBK 43 12.976 12.976 0.000 95 1302488 15.0 14.8 63 n-Octane 43 13.248 13.248 0.000 91 1452261 15.0 14.4 64 Toluene 92 13.264 13.264 0.000 93 1231696 15.0 14.6 66 trans-1,3-Dichloropropene 75 13.622 13.622 0.000 95 923761 15.0 15.4 67 1,1,2-Trichloroethane 83 13.894 13.894 0.000 95 615856 15.0 14.8 68 Tetrachloroethene 166 14.038 14.038 0.000 98 1013752 15.0 15.1 69 2-Hexanone 43 14.155 14.155 0.000 94 1253699 15.0 14.8 70 Chlorodibromomethane 129 14.449 14.449 0.000 98 1209039 15.0 15.2 71 Ethylene Dibromide 107 14.652 14.652 0.000 98 1119668 15.0 15.1 * 72 Chlorobenzene-d5 117 15.217 15.212 0.005 84 1415692 10.0 10.0 73 Chlorobenzene 112 15.255 15.255 0.000 96 1685338 15.0 14.9 74 Ethylbenzene 91 15.324 15.319 0.005 98 2745535 15.0 14.8 75 n-Nonane 57 15.340 15.340 0.000 94 1397898 15.0 14.7 76 m-Xylene & p-Xylene 106 15.468 15.468 0.000 0 2218882 30.0 30.4 78 o-Xylene 106 15.981 15.981 -0.001 99 1084561 15.0 14.9 S 77 Xylenes, Total 106 0 45.0 45.3 79 Styrene 104 16.002 16.002 0.000 98 1712264 15.0 15.6 80 Bromoform 173 16.295 16.295 0.000 98 1147379 15.0 15.6 81 Isopropylbenzene 105 16.391 16.391 0.000 95 3088484 15.0 15.0 85 1,2,3-Trichloropropane 75 16.882 16.882 0.000 98 1276362 15.0 15.0 83 1,1,2,2-Tetrachloroethane 83 16.797 16.797 0.000 97 1676500 15.0 15.0 84 N-Propylbenzene 91 16.872 16.872 0.000 99 3873668 15.0 15.3 86 n-Decane 57 16.941 16.941 0.000 89 1749982 15.0 14.5 87 4-Ethyltoluene 105 16.995 16.995 0.000 98 3091160 15.0 15.4 Page 341 of 478 Report Date: 07-Nov-2017 13:39:58 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-11.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 88 2-Chlorotoluene 91 17.037 17.037 0.000 97 2537832 15.0 15.1 89 1,3,5-Trimethylbenzene 105 17.064 17.064 0.000 93 2528343 15.0 15.2 90 Alpha Methyl Styrene 118 17.336 17.336 0.000 90 1287536 15.0 15.8 91 tert-Butylbenzene 119 17.437 17.437 0.000 95 2404614 15.0 14.9 92 1,2,4-Trimethylbenzene 105 17.507 17.507 0.000 97 2464062 15.0 15.0 93 sec-Butylbenzene 105 17.694 17.694 0.000 99 3666512 15.0 14.7 94 4-Isopropyltoluene 119 17.848 17.848 0.000 98 2956723 15.0 14.4 95 1,3-Dichlorobenzene 146 17.928 17.928 0.000 97 1696474 15.0 15.5 96 1,4-Dichlorobenzene 146 18.041 18.035 0.006 96 1664444 15.0 15.6 97 Benzyl chloride 91 18.190 18.185 0.005 99 1962790 15.0 16.1 98 Undecane 57 18.318 18.318 0.000 96 1951866 15.0 14.9 99 n-Butylbenzene 91 18.355 18.355 0.000 98 2706883 15.0 14.3 100 1,2-Dichlorobenzene 146 18.521 18.521 0.000 97 1525509 15.0 14.8 102 Dodecane 57 19.770 19.770 0.000 97 1688580 15.0 16.7 103 1,2,4-Trichlorobenzene 180 20.885 20.885 0.000 94 1082245 15.0 17.0 104 Hexachlorobutadiene 225 21.051 21.051 0.000 98 1059150 15.0 15.8 105 Naphthalene 128 21.360 21.360 0.000 100 2354157 15.0 17.5 106 1,2,3-Trichlorobenzene 180 21.835 21.835 0.000 96 951579 15.0 17.2 Reagents: ATTO15CAL5w_00069 Amount Added: 200.00 Units: mL ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 342 of 478 Y ( X 1 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 9 . 7 0 4 ) + * 1 , 4 - D i f l u o r o b e n z e n e ( 1 1 . 1 0 8 ) * C h l o r o b e n z e n e - d 5 ( 1 5 . 2 1 7 ) Report Date: 07-Nov-2017 13:40:00 Chrom Revision: 2.2 28-Sep-2017 09:29:16 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-12.D Lims ID:ic Client ID: Sample Type:IC Calib Level:7 Inject. Date:07-Nov-2017 00:57:30 ALS Bottle#:12 Worklist Smp#:12 Purge Vol:200.000 mL Dil. Factor:1.0000 Sample Info:200-0027754-012 Misc. Info.:ic Operator ID:vtp Instrument ID:CHB.i Sublist:chrom-TO15_LLNJ_TO3*sub5 Method:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:07-Nov-2017 13:40:00 Calib Date:07-Nov-2017 01:49:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal/External Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: daiglep Date:07-Nov-2017 09:06:56 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 1 Propene 41 3.135 3.135 0.000 99 350917 20.0 17.2 2 Dichlorodifluoromethane 85 3.193 3.193 0.000 99 1400515 20.0 18.0 3 Chlorodifluoromethane 51 3.231 3.225 0.006 97 762497 20.0 17.2 4 1,2-Dichloro-1,1,2,2-tetra 85 3.412 3.412 0.000 98 1504994 20.0 18.4 5 Chloromethane 50 3.540 3.535 0.005 99 487565 20.0 17.5 6 Butane 43 3.711 3.711 0.000 98 814735 20.0 17.0 7 Vinyl chloride 62 3.748 3.748 0.000 98 629881 20.0 18.8 8 Butadiene 54 3.812 3.812 0.000 94 460938 20.0 18.8 10 Bromomethane 94 4.479 4.479 0.000 99 682895 20.0 19.8 9 BFB 11 Chloroethane 64 4.709 4.709 0.000 99 395487 20.0 19.1 12 2-Methylbutane 43 4.794 4.789 0.005 93 759706 20.0 17.4 13 Vinyl bromide 106 5.125 5.120 0.005 100 719528 20.0 20.5 14 Trichlorofluoromethane 101 5.221 5.216 0.005 98 1566416 20.0 18.8 15 Pentane 43 5.360 5.355 0.005 96 1183796 20.0 17.8 16 Ethanol 45 5.686 5.675 0.011 98 625643 40.0 34.4 17 Ethyl ether 59 5.830 5.830 0.000 95 489381 20.0 19.1 18 Acrolein 56 6.198 6.198 0.000 95 227859 20.0 19.3 19 1,1,2-Trichloro-1,2,2-trif 101 6.251 6.246 0.005 98 1357192 20.0 19.4 20 1,1-Dichloroethene 96 6.321 6.321 0.000 97 676409 20.0 19.3 21 Acetone 43 6.470 6.470 0.000 96 918444 20.0 17.6 22 Isopropyl alcohol 45 6.694 6.684 0.010 99 1053695 20.0 17.9 23 Carbon disulfide 76 6.753 6.748 0.005 98 1884193 20.0 19.2 24 3-Chloro-1-propene 41 7.020 7.020 0.000 93 907636 20.0 18.6 26 Acetonitrile 41 7.079 7.079 0.000 100 558071 20.0 18.5 27 Methylene Chloride 49 7.281 7.276 0.005 93 758104 20.0 18.1 28 2-Methyl-2-propanol 59 7.393 7.388 0.005 92 1407939 20.0 18.4 29 Methyl tert-butyl ether 73 7.628 7.628 0.000 97 1996655 20.0 19.1 30 trans-1,2-Dichloroethene 61 7.692 7.687 0.005 98 999814 20.0 18.8 31 Acrylonitrile 53 7.756 7.756 0.000 96 528510 20.0 18.9 Page 344 of 478 Report Date: 07-Nov-2017 13:40:00 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-12.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 Hexane 57 8.018 8.018 0.000 91 1144849 20.0 17.9 33 1,1-Dichloroethane 63 8.429 8.429 0.000 99 1313600 20.0 18.5 34 Vinyl acetate 43 8.434 8.434 0.000 100 1782446 20.0 18.2 36 2-Butanone (MEK) 72 9.320 9.320 0.000 99 393924 20.0 19.1 37 cis-1,2-Dichloroethene 96 9.336 9.331 0.005 96 806754 20.0 19.9 35 Ethyl acetate 88 9.336 9.336 0.000 94 66363 20.0 19.5 * 39 Chlorobromomethane 128 9.704 9.704 0.000 93 351888 10.0 10.0 38 Tetrahydrofuran 42 9.715 9.710 0.005 94 842926 20.0 18.2 40 Chloroform 83 9.779 9.774 0.005 95 1425408 20.0 18.8 S 41 1,2-Dichloroethene, Total 61 0 40.0 38.8 42 1,1,1-Trichloroethane 97 10.035 10.035 0.000 95 1386002 20.0 19.1 43 Cyclohexane 84 10.051 10.046 0.005 97 1078684 20.0 19.7 44 Carbon tetrachloride 117 10.243 10.243 0.000 97 1408169 20.0 20.4 45 Isooctane 57 10.526 10.521 0.005 100 3971225 20.0 19.2 46 Benzene 78 10.569 10.564 0.005 95 2412590 20.0 18.9 47 1,2-Dichloroethane 62 10.665 10.665 0.000 96 834386 20.0 18.3 48 n-Heptane 43 10.777 10.777 0.000 91 1411728 20.0 17.8 A 49 GRO 1 10.865 (4.779-16.951) 0 302904769 20.0 0 * 50 1,4-Difluorobenzene 114 11.108 11.108 0.000 94 1736810 10.0 10.0 51 n-Butanol 56 11.289 11.289 0.000 85 462049 20.0 18.7 53 Trichloroethene 95 11.476 11.476 0.000 98 1020053 20.0 20.0 54 1,2-Dichloropropane 63 11.844 11.844 0.000 95 947123 20.0 19.3 55 Methyl methacrylate 69 11.882 11.882 0.000 98 907851 20.0 19.8 56 1,4-Dioxane 88 11.973 11.967 0.005 93 457426 20.0 18.9 57 Dibromomethane 174 12.037 12.031 0.006 96 1002264 20.0 19.8 58 Dichlorobromomethane 83 12.207 12.202 0.005 97 1641881 20.0 19.1 A 59 TVOC as Toluene 1 12.485 (3.125-21.845) 0 492329729 20.0 0 60 cis-1,3-Dichloropropene 75 12.832 12.832 0.000 89 1376724 20.0 19.8 61 4-Methyl-2-pentanone (MIBK 43 12.981 12.976 0.005 94 1803414 20.0 18.6 63 n-Octane 43 13.248 13.248 0.000 90 1990415 20.0 17.8 64 Toluene 92 13.264 13.264 0.000 93 1809158 20.0 19.4 66 trans-1,3-Dichloropropene 75 13.622 13.622 0.000 94 1324222 20.0 20.0 67 1,1,2-Trichloroethane 83 13.894 13.894 0.000 94 895676 20.0 19.5 68 Tetrachloroethene 166 14.038 14.038 0.000 98 1504548 20.0 20.4 69 2-Hexanone 43 14.155 14.155 0.000 95 1722537 20.0 18.5 70 Chlorodibromomethane 129 14.449 14.449 0.000 98 1793665 20.0 20.5 71 Ethylene Dibromide 107 14.652 14.652 0.000 98 1634580 20.0 20.1 * 72 Chlorobenzene-d5 117 15.217 15.212 0.005 85 1559872 10.0 10.0 73 Chlorobenzene 112 15.255 15.255 0.000 97 2491305 20.0 20.0 74 Ethylbenzene 91 15.324 15.319 0.005 97 4014844 20.0 19.7 75 n-Nonane 57 15.345 15.340 0.005 92 1983042 20.0 19.0 76 m-Xylene & p-Xylene 106 15.468 15.468 0.000 0 3293994 40.0 40.9 78 o-Xylene 106 15.981 15.981 0.000 99 1596485 20.0 19.9 S 77 Xylenes, Total 106 0 60.0 60.9 79 Styrene 104 16.007 16.002 0.005 97 2512147 20.0 20.8 80 Bromoform 173 16.295 16.295 0.000 99 1752241 20.0 21.7 81 Isopropylbenzene 105 16.391 16.391 0.000 95 4545305 20.0 20.1 83 1,1,2,2-Tetrachloroethane 83 16.802 16.797 0.005 97 2424642 20.0 19.7 84 N-Propylbenzene 91 16.872 16.872 0.000 100 5568174 20.0 20.0 85 1,2,3-Trichloropropane 75 16.882 16.882 0.000 97 1816466 20.0 19.3 86 n-Decane 57 16.941 16.941 0.000 90 2395755 20.0 18.1 87 4-Ethyltoluene 105 17.000 16.995 0.005 98 4414476 20.0 19.9 Page 345 of 478 Report Date: 07-Nov-2017 13:40:00 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-12.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 88 2-Chlorotoluene 91 17.037 17.037 0.000 96 3605957 20.0 19.5 89 1,3,5-Trimethylbenzene 105 17.064 17.064 0.000 94 3506340 20.0 19.1 90 Alpha Methyl Styrene 118 17.336 17.336 0.000 91 1810300 20.0 20.2 91 tert-Butylbenzene 119 17.438 17.437 0.001 96 3393419 20.0 19.1 92 1,2,4-Trimethylbenzene 105 17.512 17.507 0.005 96 3454778 20.0 19.1 93 sec-Butylbenzene 105 17.699 17.694 0.005 99 5200086 20.0 18.9 94 4-Isopropyltoluene 119 17.848 17.848 0.000 98 4342966 20.0 19.2 95 1,3-Dichlorobenzene 146 17.929 17.928 0.000 96 2362589 20.0 19.6 96 1,4-Dichlorobenzene 146 18.041 18.035 0.006 96 2308042 20.0 19.6 97 Benzyl chloride 91 18.190 18.185 0.005 100 2733690 20.0 20.3 98 Undecane 57 18.318 18.318 0.000 95 2730816 20.0 18.9 99 n-Butylbenzene 91 18.355 18.355 0.000 98 4000789 20.0 19.2 100 1,2-Dichlorobenzene 146 18.526 18.521 0.005 98 2178021 20.0 19.2 102 Dodecane 57 19.775 19.770 0.005 97 2288869 20.0 20.5 103 1,2,4-Trichlorobenzene 180 20.885 20.885 0.000 94 1522402 20.0 21.7 104 Hexachlorobutadiene 225 21.051 21.051 0.000 98 1555025 20.0 21.0 105 Naphthalene 128 21.365 21.360 0.005 100 3182700 20.0 21.4 106 1,2,3-Trichlorobenzene 180 21.840 21.835 0.005 96 1354997 20.0 22.2 Reagents: ATTO15CAL6w_00144 Amount Added: 200.00 Units: mL ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 346 of 478 Y ( X 1 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 9 . 7 1 0 ) + * 1 , 4 - D i f l u o r o b e n z e n e ( 1 1 . 1 0 8 ) * C h l o r o b e n z e n e - d 5 ( 1 5 . 2 1 7 ) Report Date: 07-Nov-2017 13:40:03 Chrom Revision: 2.2 28-Sep-2017 09:29:16 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Lims ID:ic Client ID: Sample Type:IC Calib Level:8 Inject. Date:07-Nov-2017 01:49:30 ALS Bottle#:13 Worklist Smp#:13 Purge Vol:200.000 mL Dil. Factor:1.0000 Sample Info:200-0027754-013 Misc. Info.:ic Operator ID:vtp Instrument ID:CHB.i Sublist:chrom-TO15_LLNJ_TO3*sub5 Method:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:07-Nov-2017 13:40:02 Calib Date:07-Nov-2017 01:49:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal/External Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: daiglep Date:07-Nov-2017 09:07:40 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 1 Propene 41 3.135 3.135 0.000 98 666801 40.0 28.1 2 Dichlorodifluoromethane 85 3.193 3.193 0.000 99 2754680 40.0 30.5 3 Chlorodifluoromethane 51 3.231 3.225 0.006 97 1456389 40.0 28.3 4 1,2-Dichloro-1,1,2,2-tetra 85 3.417 3.412 0.005 97 3017555 40.0 31.8 5 Chloromethane 50 3.540 3.535 0.005 99 953781 40.0 29.6 6 Butane 43 3.716 3.711 0.005 99 1560254 40.0 28.0 7 Vinyl chloride 62 3.748 3.748 0.000 98 1259739 40.0 32.4 8 Butadiene 54 3.818 3.812 0.006 94 907836 40.0 31.9 9 BFB 10 Bromomethane 94 4.485 4.479 0.006 100 1419547 40.0 35.5 11 Chloroethane 64 4.714 4.709 0.005 99 801767 40.0 33.3 12 2-Methylbutane 43 4.800 4.789 0.011 93 1477241 40.0 29.2 13 Vinyl bromide 106 5.125 5.120 0.005 100 1517808 40.0 37.2 14 Trichlorofluoromethane 101 5.227 5.216 0.011 98 3219338 40.0 33.3 15 Pentane 43 5.360 5.355 0.005 96 2305350 40.0 29.9 16 Ethanol 45 5.696 5.675 0.021 98 1415524 100.0 67.1 17 Ethyl ether 59 5.835 5.830 0.005 95 990383 40.0 33.4 18 Acrolein 56 6.198 6.198 0.000 94 464860 40.0 33.9 19 1,1,2-Trichloro-1,2,2-trif 101 6.257 6.246 0.011 99 2870018 40.0 35.4 20 1,1-Dichloroethene 96 6.326 6.321 0.005 95 1431915 40.0 35.3 21 Acetone 43 6.470 6.470 0.000 95 1763733 40.0 29.1 22 Isopropyl alcohol 45 6.710 6.684 0.026 99 2014852 40.0 29.6 23 Carbon disulfide 76 6.753 6.748 0.005 98 3905659 40.0 34.3 24 3-Chloro-1-propene 41 7.025 7.020 0.005 92 1708448 40.0 30.1 26 Acetonitrile 41 7.084 7.079 0.005 99 1051183 40.0 30.0 27 Methylene Chloride 49 7.281 7.276 0.005 90 1485831 40.0 30.5 28 2-Methyl-2-propanol 59 7.410 7.388 0.022 92 2782228 40.0 31.3 29 Methyl tert-butyl ether 73 7.628 7.628 0.000 97 4082553 40.0 33.7 30 trans-1,2-Dichloroethene 61 7.692 7.687 0.005 97 2027160 40.0 32.9 31 Acrylonitrile 53 7.762 7.756 0.006 96 1064673 40.0 32.7 Page 348 of 478 Report Date: 07-Nov-2017 13:40:03 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 Hexane 57 8.023 8.018 0.005 90 2299897 40.0 31.0 33 1,1-Dichloroethane 63 8.434 8.429 0.005 99 2648188 40.0 32.1 34 Vinyl acetate 43 8.440 8.434 0.006 100 3425006 40.0 30.2 36 2-Butanone (MEK) 72 9.325 9.320 0.005 98 811284 40.0 33.9 37 cis-1,2-Dichloroethene 96 9.336 9.331 0.005 95 1716713 40.0 36.6 35 Ethyl acetate 88 9.341 9.336 0.005 94 142076 40.0 36.0 * 39 Chlorobromomethane 128 9.710 9.704 0.006 90 408442 10.0 10.0 38 Tetrahydrofuran 42 9.715 9.710 0.005 93 1611154 40.0 30.8 40 Chloroform 83 9.784 9.774 0.010 94 2922350 40.0 33.2 S 41 1,2-Dichloroethene, Total 61 0 80.0 69.5 42 1,1,1-Trichloroethane 97 10.041 10.035 0.006 95 2851804 40.0 34.8 43 Cyclohexane 84 10.051 10.046 0.005 95 2298205 40.0 37.3 44 Carbon tetrachloride 117 10.243 10.243 0.000 97 2864853 40.0 36.9 45 Isooctane 57 10.526 10.521 0.005 99 8002808 40.0 34.3 46 Benzene 78 10.569 10.564 0.005 94 5046961 40.0 35.1 47 1,2-Dichloroethane 62 10.670 10.665 0.005 96 1634383 40.0 31.9 48 n-Heptane 43 10.782 10.777 0.005 88 2713764 40.0 30.4 A 49 GRO 1 10.865 (4.779-16.951) 0 613108146 40.0 0 * 50 1,4-Difluorobenzene 114 11.113 11.108 0.005 93 1957289 10.0 10.0 51 n-Butanol 56 11.300 11.289 0.011 84 934673 40.0 33.6 53 Trichloroethene 95 11.482 11.476 0.006 96 2163493 40.0 37.7 54 1,2-Dichloropropane 63 11.850 11.844 0.006 95 1921446 40.0 34.7 55 Methyl methacrylate 69 11.887 11.882 0.005 97 1872327 40.0 36.3 56 1,4-Dioxane 88 11.978 11.967 0.011 91 923935 40.0 33.8 57 Dibromomethane 174 12.037 12.031 0.006 95 2204560 40.0 38.6 58 Dichlorobromomethane 83 12.207 12.202 0.005 97 3362489 40.0 34.8 A 59 TVOC as Toluene 1 12.485 (3.125-21.845) 0 1002856430 40.0 0 60 cis-1,3-Dichloropropene 75 12.837 12.832 0.005 88 2838418 40.0 36.3 61 4-Methyl-2-pentanone (MIBK 43 12.987 12.976 0.011 93 3457992 40.0 31.6 63 n-Octane 43 13.253 13.248 0.005 87 3709404 40.0 29.5 64 Toluene 92 13.269 13.264 0.005 93 3852181 40.0 36.6 66 trans-1,3-Dichloropropene 75 13.627 13.622 0.005 94 2695893 40.0 36.1 67 1,1,2-Trichloroethane 83 13.899 13.894 0.005 94 1880575 40.0 36.2 68 Tetrachloroethene 166 14.043 14.038 0.005 96 3391200 40.0 40.7 69 2-Hexanone 43 14.161 14.155 0.006 97 3323450 40.0 31.6 70 Chlorodibromomethane 129 14.454 14.449 0.005 98 3876618 40.0 39.2 71 Ethylene Dibromide 107 14.657 14.652 0.005 98 3507458 40.0 38.1 * 72 Chlorobenzene-d5 117 15.217 15.212 0.005 82 1761738 10.0 10.0 73 Chlorobenzene 112 15.260 15.255 0.005 98 5382503 40.0 38.3 74 Ethylbenzene 91 15.324 15.319 0.005 97 8428186 40.0 36.5 75 n-Nonane 57 15.345 15.340 0.005 86 3919902 40.0 33.2 76 m-Xylene & p-Xylene 106 15.474 15.468 0.006 0 7176091 80.0 79.0 78 o-Xylene 106 15.986 15.981 0.005 98 3448842 40.0 38.2 S 77 Xylenes, Total 106 0 120.0 117.1 79 Styrene 104 16.007 16.002 0.005 97 5480628 40.0 40.2 80 Bromoform 173 16.301 16.295 0.006 99 3907202 40.0 42.8 81 Isopropylbenzene 105 16.397 16.391 0.006 94 9581691 40.0 37.5 83 1,1,2,2-Tetrachloroethane 83 16.802 16.797 0.005 97 4869536 40.0 35.0 84 N-Propylbenzene 91 16.877 16.872 0.005 100 11180756 40.0 35.5 85 1,2,3-Trichloropropane 75 16.888 16.882 0.006 96 3577331 40.0 33.7 86 n-Decane 57 16.947 16.941 0.006 89 4905409 40.0 32.8 87 4-Ethyltoluene 105 17.000 16.995 0.005 98 9273522 40.0 37.0 Page 349 of 478 Report Date: 07-Nov-2017 13:40:03 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 88 2-Chlorotoluene 91 17.043 17.037 0.006 95 7557699 40.0 36.2 89 1,3,5-Trimethylbenzene 105 17.069 17.064 0.005 94 7827219 40.0 37.8 90 Alpha Methyl Styrene 118 17.341 17.336 0.005 92 4081481 40.0 40.2 91 tert-Butylbenzene 119 17.443 17.437 0.006 96 7457439 40.0 37.2 92 1,2,4-Trimethylbenzene 105 17.512 17.507 0.005 96 7714438 40.0 37.7 93 sec-Butylbenzene 105 17.699 17.694 0.005 99 11501603 40.0 37.0 94 4-Isopropyltoluene 119 17.854 17.848 0.006 98 9980594 40.0 39.0 95 1,3-Dichlorobenzene 146 17.934 17.928 0.006 95 5559940 40.0 40.9 96 1,4-Dichlorobenzene 146 18.041 18.035 0.006 97 5573724 40.0 41.9 97 Benzyl chloride 91 18.190 18.185 0.005 100 6135081 40.0 40.4 98 Undecane 57 18.323 18.318 0.005 93 5313148 40.0 32.6 99 n-Butylbenzene 91 18.361 18.355 0.006 98 8834446 40.0 37.6 100 1,2-Dichlorobenzene 146 18.526 18.521 0.005 99 5217884 40.0 40.8 102 Dodecane 57 19.775 19.770 0.005 97 2608958 40.0 20.7 103 1,2,4-Trichlorobenzene 180 20.885 20.885 0.000 93 3106580 40.0 39.1 104 Hexachlorobutadiene 225 21.051 21.051 0.000 96 2733620 40.0 32.7 105 Naphthalene 128 21.366 21.360 0.006 100 6623680 40.0 39.5 106 1,2,3-Trichlorobenzene 180 21.841 21.835 0.005 95 2277299 40.0 33.1 Reagents: ATTO15CAL7w_00071 Amount Added: 200.00 Units: mL ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 350 of 478 Y ( X 1 0 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 9 . 7 1 0 ) + * 1 , 4 - D i f l u o r o b e n z e n e ( 1 1 . 1 1 3 ) * C h l o r o b e n z e n e - d 5 ( 1 5 . 2 2 3 ) Page 352 of 478 Page 353 of 478 Page 354 of 478 Report Date: 07-Nov-2017 13:40:38 Chrom Revision: 2.2 28-Sep-2017 09:29:16 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-24.D Lims ID:icv Client ID: Sample Type:ICV Inject. Date:07-Nov-2017 12:25:30 ALS Bottle#:24 Worklist Smp#:24 Purge Vol:200.000 mL Dil. Factor:1.0000 Sample Info:200-0027754-024 Operator ID:vtp Instrument ID:CHB.i Sublist: Method:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:07-Nov-2017 13:40:02 Calib Date:07-Nov-2017 01:49:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal/External Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: daiglep Date:07-Nov-2017 13:31:22 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 1 Propene 41 3.134 3.135 -0.001 98 181047 10.0 10.0 2 Dichlorodifluoromethane 85 3.193 3.193 0.000 99 700839 10.0 10.2 3 Chlorodifluoromethane 51 3.225 3.225 0.000 97 389211 10.0 9.92 4 1,2-Dichloro-1,1,2,2-tetra 85 3.412 3.412 0.000 97 743392 10.0 10.3 5 Chloromethane 50 3.535 3.535 0.000 99 248889 10.0 10.1 6 Butane 43 3.711 3.711 0.000 99 415119 10.0 9.77 7 Vinyl chloride 62 3.748 3.748 0.000 98 313654 10.0 10.6 8 Butadiene 54 3.812 3.812 0.000 96 229374 10.0 10.6 10 Bromomethane 94 4.479 4.479 0.000 99 322525 10.0 10.6 9 BFB 11 Chloroethane 64 4.709 4.709 0.000 99 189727 10.0 10.3 12 2-Methylbutane 43 4.789 4.789 0.000 94 379181 10.0 9.82 13 Vinyl bromide 106 5.114 5.120 -0.006 100 333420 10.0 10.7 14 Trichlorofluoromethane 101 5.221 5.216 0.005 98 750915 10.0 10.2 15 Pentane 43 5.355 5.355 0.000 96 586259 10.0 9.98 16 Ethanol 45 5.680 5.675 0.005 98 240606 15.0 14.9 17 Ethyl ether 59 5.830 5.830 0.000 94 236123 10.0 10.4 18 Acrolein 56 6.198 6.198 0.000 95 106775 10.0 10.2 19 1,1,2-Trichloro-1,2,2-trif 101 6.246 6.246 0.000 98 638129 10.0 10.3 20 1,1-Dichloroethene 96 6.321 6.321 0.000 98 316913 10.0 10.2 21 Acetone 43 6.470 6.470 0.000 96 469731 10.0 10.2 22 Isopropyl alcohol 45 6.689 6.684 0.005 99 557218 10.0 10.7 23 Carbon disulfide 76 6.748 6.748 0.000 99 906656 10.0 10.4 24 3-Chloro-1-propene 41 7.020 7.020 0.000 93 436296 10.0 10.1 26 Acetonitrile 41 7.078 7.079 -0.001 100 273193 10.0 10.2 27 Methylene Chloride 49 7.276 7.276 0.000 94 379401 10.0 10.2 28 2-Methyl-2-propanol 59 7.388 7.388 0.000 93 724780 10.0 10.7 29 Methyl tert-butyl ether 73 7.628 7.628 0.000 98 945886 10.0 10.3 30 trans-1,2-Dichloroethene 61 7.687 7.687 0.000 99 485306 10.0 10.3 31 Acrylonitrile 53 7.756 7.756 0.000 96 261132 10.0 10.5 32 Hexane 57 8.018 8.018 0.000 93 551026 10.0 9.75 Page 355 of 478 Report Date: 07-Nov-2017 13:40:38 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-24.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 33 1,1-Dichloroethane 63 8.429 8.429 0.000 99 639073 10.0 10.2 34 Vinyl acetate 43 8.434 8.434 0.000 100 882685 10.0 10.2 36 2-Butanone (MEK) 72 9.320 9.320 0.000 99 184699 10.0 10.1 37 cis-1,2-Dichloroethene 96 9.336 9.331 0.005 95 376144 10.0 10.5 35 Ethyl acetate 88 9.331 9.336 -0.005 94 30666 10.0 10.2 * 39 Chlorobromomethane 128 9.704 9.704 0.000 95 311386 10.0 10.0 38 Tetrahydrofuran 42 9.715 9.710 0.005 95 424194 10.0 10.3 40 Chloroform 83 9.779 9.774 0.005 95 683454 10.0 10.2 S 41 1,2-Dichloroethene, Total 61 0 20.0 20.8 42 1,1,1-Trichloroethane 97 10.035 10.035 0.000 95 656205 10.0 10.2 43 Cyclohexane 84 10.046 10.046 0.000 98 503835 10.0 10.4 44 Carbon tetrachloride 117 10.243 10.243 0.000 98 663149 10.0 10.9 45 Isooctane 57 10.526 10.521 0.005 100 1907182 10.0 10.4 46 Benzene 78 10.563 10.564 -0.001 95 1135183 10.0 10.0 47 1,2-Dichloroethane 62 10.665 10.665 0.000 96 411406 10.0 10.2 48 n-Heptane 43 10.777 10.777 0.000 91 698841 10.0 9.96 A 49 GRO 1 10.865 (4.779-16.951) 0 147809696 10.0 0 * 50 1,4-Difluorobenzene 114 11.108 11.108 0.000 94 1538738 10.0 10.0 51 n-Butanol 56 11.289 11.289 0.000 87 237289 10.0 10.8 53 Trichloroethene 95 11.476 11.476 0.000 98 478655 10.0 10.6 54 1,2-Dichloropropane 63 11.844 11.844 0.000 95 458255 10.0 10.5 55 Methyl methacrylate 69 11.882 11.882 0.000 97 424511 10.0 10.5 56 1,4-Dioxane 88 11.972 11.967 0.005 93 235313 10.0 10.9 57 Dibromomethane 174 12.031 12.031 0.000 97 462897 10.0 10.3 58 Dichlorobromomethane 83 12.207 12.202 0.005 98 777693 10.0 10.2 A 59 TVOC as Toluene 1 12.485 (3.125-21.845) 0 240152968 10.0 0 60 cis-1,3-Dichloropropene 75 12.832 12.832 0.000 90 645617 10.0 10.5 61 4-Methyl-2-pentanone (MIBK 43 12.976 12.976 0.000 96 889767 10.0 10.3 63 n-Octane 43 13.248 13.248 0.000 92 1006767 10.0 10.2 64 Toluene 92 13.264 13.264 0.000 93 842860 10.0 10.1 66 trans-1,3-Dichloropropene 75 13.621 13.622 -0.001 95 624877 10.0 10.6 67 1,1,2-Trichloroethane 83 13.894 13.894 0.000 95 423500 10.0 10.3 68 Tetrachloroethene 166 14.038 14.038 0.000 98 687718 10.0 10.4 69 2-Hexanone 43 14.150 14.155 -0.005 95 855318 10.0 10.3 70 Chlorodibromomethane 129 14.449 14.449 0.000 98 810571 10.0 10.3 71 Ethylene Dibromide 107 14.651 14.652 -0.001 98 762974 10.0 10.5 * 72 Chlorobenzene-d5 117 15.217 15.212 0.005 84 1393921 10.0 10.0 73 Chlorobenzene 112 15.255 15.255 0.000 96 1145351 10.0 10.3 74 Ethylbenzene 91 15.319 15.319 0.000 98 1865765 10.0 10.2 75 n-Nonane 57 15.340 15.340 0.000 91 964664 10.0 10.3 76 m-Xylene & p-Xylene 106 15.468 15.468 0.000 0 1489987 20.0 20.7 78 o-Xylene 106 15.980 15.981 -0.001 99 739093 10.0 10.3 S 77 Xylenes, Total 106 0 30.0 31.1 79 Styrene 104 16.002 16.002 0.000 98 1148492 10.0 10.7 80 Bromoform 173 16.295 16.295 0.000 98 734520 10.0 10.2 81 Isopropylbenzene 105 16.391 16.391 0.000 95 2100933 10.0 10.4 83 1,1,2,2-Tetrachloroethane 83 16.797 16.797 0.000 97 1158207 10.0 10.5 84 N-Propylbenzene 91 16.872 16.872 0.000 99 2617083 10.0 10.5 85 1,2,3-Trichloropropane 75 16.882 16.882 0.000 97 872384 10.0 10.4 86 n-Decane 57 16.936 16.941 -0.005 89 1263341 10.0 10.7 87 4-Ethyltoluene 105 16.994 16.995 -0.001 98 2096446 10.0 10.6 88 2-Chlorotoluene 91 17.037 17.037 0.000 96 1719854 10.0 10.4 Page 356 of 478 Report Date: 07-Nov-2017 13:40:38 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-24.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 89 1,3,5-Trimethylbenzene 105 17.064 17.064 0.000 93 1741357 10.0 10.6 90 Alpha Methyl Styrene 118 17.336 17.336 0.000 90 890655 10.0 11.1 91 tert-Butylbenzene 119 17.437 17.437 0.000 96 1686362 10.0 10.6 92 1,2,4-Trimethylbenzene 105 17.507 17.507 0.000 97 1740342 10.0 10.7 93 sec-Butylbenzene 105 17.694 17.694 0.000 99 2633043 10.0 10.7 94 4-Isopropyltoluene 119 17.848 17.848 0.000 98 2185801 10.0 10.8 95 1,3-Dichlorobenzene 146 17.923 17.928 -0.005 97 1176103 10.0 10.9 96 1,4-Dichlorobenzene 146 18.035 18.035 0.000 96 1160442 10.0 11.0 97 Benzyl chloride 91 18.185 18.185 -0.001 99 1386864 10.0 11.5 98 Undecane 57 18.318 18.318 0.000 96 1331224 10.0 10.3 99 n-Butylbenzene 91 18.355 18.355 0.000 98 1999979 10.0 10.8 100 1,2-Dichlorobenzene 146 18.521 18.521 0.000 97 1093389 10.0 10.8 102 Dodecane 57 19.770 19.770 0.000 97 1088353 10.0 10.9 103 1,2,4-Trichlorobenzene 180 20.885 20.885 0.000 94 606261 10.0 9.65 104 Hexachlorobutadiene 225 21.050 21.051 -0.001 98 636865 10.0 9.63 105 Naphthalene 128 21.365 21.360 0.005 100 1242371 10.0 9.36 106 1,2,3-Trichlorobenzene 180 21.840 21.835 0.005 95 532115 10.0 9.77 Reagents: ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent ATTO15LCSW_00712 Amount Added: 200.00 Units: mL Page 357 of 478 Y ( X 1 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 9 . 7 0 4 ) + * 1 , 4 - D i f l u o r o b e n z e n e ( 1 1 . 1 0 8 ) * C h l o r o b e n z e n e - d 5 ( 1 5 . 2 1 7 ) Page 359 of 478 Page 360 of 478 Page 361 of 478 Report Date: 28-Nov-2017 09:01:08 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-02.D Lims ID:ccvis Client ID: Sample Type:CCVIS Inject. Date:24-Nov-2017 10:33:30 ALS Bottle#:2 Worklist Smp#:2 Purge Vol:200.000 mL Dil. Factor:1.0000 Sample Info:200-0028034-002 Operator ID:VTP Instrument ID:CHB.i Sublist:chrom-TO15_LLNJ_TO3*sub5 Method:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:28-Nov-2017 09:01:07 Calib Date:07-Nov-2017 01:49:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal/External Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: puangmaleek Date:28-Nov-2017 09:01:07 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 1 Propene 41 3.134 3.134 0.000 98 217619 10.0 8.99 2 Dichlorodifluoromethane 85 3.193 3.193 0.000 99 818182 10.0 8.85 3 Chlorodifluoromethane 51 3.225 3.225 0.000 97 454638 10.0 8.65 4 1,2-Dichloro-1,1,2,2-tetra 85 3.412 3.412 0.000 88 900550 10.0 9.28 5 Chloromethane 50 3.535 3.535 0.000 99 295281 10.0 8.96 6 Butane 43 3.711 3.711 0.000 99 487463 10.0 8.56 7 Vinyl chloride 62 3.748 3.748 0.000 98 377534 10.0 9.50 8 Butadiene 54 3.812 3.812 0.000 95 276116 10.0 9.49 10 Bromomethane 94 4.479 4.479 0.000 100 404537 10.0 9.89 9 BFB 11 Chloroethane 64 4.709 4.709 0.000 99 236675 10.0 9.63 12 2-Methylbutane 43 4.789 4.789 0.000 94 452442 10.0 8.74 13 Vinyl bromide 106 5.120 5.120 0.000 100 426801 10.0 10.2 14 Trichlorofluoromethane 101 5.216 5.216 0.000 98 888343 10.0 9.01 15 Pentane 43 5.355 5.355 0.000 96 701667 10.0 8.92 16 Ethanol 45 5.669 5.669 0.000 98 276638 15.0 12.8 17 Ethyl ether 59 5.824 5.824 0.000 95 292987 10.0 9.66 18 Acrolein 56 6.198 6.198 0.000 94 138525 10.0 9.89 19 1,1,2-Trichloro-1,2,2-trif 101 6.246 6.246 0.000 98 792090 10.0 9.56 20 1,1-Dichloroethene 96 6.315 6.315 0.000 96 399780 10.0 9.63 21 Acetone 43 6.465 6.465 0.000 95 545969 10.0 8.81 22 Isopropyl alcohol 45 6.683 6.683 0.000 99 638472 10.0 9.17 23 Carbon disulfide 76 6.748 6.748 0.000 98 1122202 10.0 9.65 24 3-Chloro-1-propene 41 7.014 7.014 0.000 93 501714 10.0 8.67 26 Acetonitrile 41 7.073 7.073 0.000 100 305929 10.0 8.55 27 Methylene Chloride 49 7.276 7.276 0.000 92 444440 10.0 8.94 28 2-Methyl-2-propanol 59 7.383 7.383 0.000 92 844235 10.0 9.30 29 Methyl tert-butyl ether 73 7.623 7.623 0.000 97 1150762 10.0 9.31 30 trans-1,2-Dichloroethene 61 7.687 7.687 0.000 98 584785 10.0 9.29 31 Acrylonitrile 53 7.751 7.751 0.000 96 308587 10.0 9.29 32 Hexane 57 8.012 8.012 0.000 91 669483 10.0 8.84 Page 362 of 478 Report Date: 28-Nov-2017 09:01:08 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-02.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 33 1,1-Dichloroethane 63 8.423 8.423 0.000 99 761361 10.0 9.05 34 Vinyl acetate 43 8.429 8.429 0.000 100 1019935 10.0 8.80 36 2-Butanone (MEK) 72 9.315 9.315 0.000 98 229522 10.0 9.40 37 cis-1,2-Dichloroethene 96 9.331 9.331 0.000 95 465569 10.0 9.71 35 Ethyl acetate 88 9.331 9.331 0.000 94 38269 10.0 9.49 * 39 Chlorobromomethane 128 9.699 9.699 0.000 92 417259 10.0 10.0 38 Tetrahydrofuran 42 9.710 9.710 0.000 94 487030 10.0 8.84 40 Chloroform 83 9.774 9.774 0.000 95 809468 10.0 9.00 S 41 1,2-Dichloroethene, Total 61 0 20.0 19.0 42 1,1,1-Trichloroethane 97 10.030 10.030 0.000 95 770232 10.0 8.91 43 Cyclohexane 84 10.046 10.046 0.000 97 625055 10.0 9.62 44 Carbon tetrachloride 117 10.238 10.238 0.000 97 770506 10.0 9.40 45 Isooctane 57 10.521 10.521 0.000 100 2290586 10.0 9.31 46 Benzene 78 10.563 10.563 0.000 94 1401445 10.0 9.23 47 1,2-Dichloroethane 62 10.659 10.659 0.000 95 457670 10.0 8.47 48 n-Heptane 43 10.772 10.772 0.000 90 808924 10.0 8.60 A 49 GRO 1 10.862 (4.779-16.946) 0 172462754 10.0 0 *50 1,4-Difluorobenzene 114 11.102 11.102 0.000 93 2063825 10.0 10.0 51 n-Butanol 56 11.284 11.284 0.000 85 267532 10.0 9.11 53 Trichloroethene 95 11.476 11.476 0.000 97 579391 10.0 9.56 54 1,2-Dichloropropane 63 11.839 11.839 0.000 94 543815 10.0 9.31 55 Methyl methacrylate 69 11.876 11.876 0.000 98 515362 10.0 9.47 56 1,4-Dioxane 88 11.967 11.967 0.000 93 270913 10.0 9.40 57 Dibromomethane 174 12.031 12.031 0.000 96 558730 10.0 9.27 58 Dichlorobromomethane 83 12.202 12.202 0.000 97 906515 10.0 8.89 A 59 TVOC as Toluene 1 12.485 (3.124-21.845) 0 274916572 10.0 0 60 cis-1,3-Dichloropropene 75 12.826 12.826 0.000 89 769550 10.0 9.33 61 4-Methyl-2-pentanone (MIBK 43 12.976 12.976 0.000 94 1006892 10.0 8.72 63 n-Octane 43 13.243 13.243 0.000 90 1140099 10.0 8.60 64 Toluene 92 13.259 13.259 0.000 93 1015268 10.0 9.32 66 trans-1,3-Dichloropropene 75 13.621 13.621 0.000 95 725070 10.0 9.20 67 1,1,2-Trichloroethane 83 13.888 13.888 0.000 94 505620 10.0 9.42 68 Tetrachloroethene 166 14.032 14.032 0.000 97 823613 10.0 9.54 69 2-Hexanone 43 14.150 14.150 0.000 96 955115 10.0 8.78 70 Chlorodibromomethane 129 14.449 14.449 0.000 98 960842 10.0 9.38 71 Ethylene Dibromide 107 14.646 14.646 0.000 98 905054 10.0 9.51 * 72 Chlorobenzene-d5 117 15.212 15.212 0.000 84 1822725 10.0 10.0 73 Chlorobenzene 112 15.249 15.249 0.000 96 1370878 10.0 9.44 74 Ethylbenzene 91 15.319 15.319 0.000 97 2215626 10.0 9.28 75 n-Nonane 57 15.340 15.340 0.000 92 1122013 10.0 9.18 76 m-Xylene & p-Xylene 106 15.468 15.468 0.000 0 1783135 20.0 19.0 78 o-Xylene 106 15.975 15.975 0.000 99 874786 10.0 9.35 S 77 Xylenes, Total 106 0 30.0 28.3 79 Styrene 104 16.002 16.002 0.000 97 1364308 10.0 9.68 80 Bromoform 173 16.295 16.295 0.000 98 911421 10.0 9.64 81 Isopropylbenzene 105 16.391 16.391 0.000 95 2460708 10.0 9.31 83 1,1,2,2-Tetrachloroethane 83 16.797 16.797 0.000 97 1344899 10.0 9.36 84 N-Propylbenzene 91 16.866 16.866 0.000 100 3052363 10.0 9.37 85 1,2,3-Trichloropropane 75 16.877 16.877 0.000 98 997650 10.0 9.08 86 n-Decane 57 16.936 16.936 0.000 89 1435082 10.0 9.27 87 4-Ethyltoluene 105 16.994 16.994 0.000 98 2448395 10.0 9.45 88 2-Chlorotoluene 91 17.037 17.037 0.000 96 1982591 10.0 9.19 Page 363 of 478 Report Date: 28-Nov-2017 09:01:08 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-02.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 89 1,3,5-Trimethylbenzene 105 17.058 17.058 0.000 94 2005805 10.0 9.36 90 Alpha Methyl Styrene 118 17.331 17.331 0.000 91 1024571 10.0 9.76 91 tert-Butylbenzene 119 17.437 17.437 0.000 96 1927181 10.0 9.30 92 1,2,4-Trimethylbenzene 105 17.507 17.507 0.000 96 1985613 10.0 9.38 93 sec-Butylbenzene 105 17.694 17.694 0.000 99 3003213 10.0 9.33 94 4-Isopropyltoluene 119 17.843 17.843 0.000 98 2462193 10.0 9.31 95 1,3-Dichlorobenzene 146 17.923 17.923 0.000 96 1338857 10.0 9.51 96 1,4-Dichlorobenzene 146 18.035 18.035 0.000 96 1325341 10.0 9.63 97 Benzyl chloride 91 18.185 18.185 0.000 100 1526860 10.0 9.71 98 Undecane 57 18.318 18.318 0.000 95 1441640 10.0 8.56 99 n-Butylbenzene 91 18.350 18.350 0.000 98 2208197 10.0 9.09 100 1,2-Dichlorobenzene 146 18.521 18.521 0.000 97 1240430 10.0 9.38 102 Dodecane 57 19.770 19.770 0.000 97 1194550 10.0 9.17 103 1,2,4-Trichlorobenzene 180 20.880 20.880 0.000 90 688167 10.0 8.38 104 Hexachlorobutadiene 225 21.045 21.045 0.000 98 733590 10.0 8.48 105 Naphthalene 128 21.360 21.360 0.000 100 1337300 10.0 7.71 106 1,2,3-Trichlorobenzene 180 21.835 21.835 0.000 95 599212 10.0 8.41 Reagents: ATTO15CAL4w_00655 Amount Added: 200.00 Units: mL ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 364 of 478 Y ( X 1 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 9 . 6 9 9 ) + * 1 , 4 - D i f l u o r o b e n z e n e ( 1 1 . 1 0 2 ) * C h l o r o b e n z e n e - d 5 ( 1 5 . 2 1 2 ) + Report Date: 07-Nov-2017 13:39:32 Chrom Revision: 2.2 28-Sep-2017 09:29:16 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-01.D Lims ID:bfb Client ID: Sample Type:BFB Inject. Date:06-Nov-2017 15:25:30 ALS Bottle#:1 Worklist Smp#:1 Injection Vol:0.0 mL Dil. Factor:1.0000 Sample Info:200-0027754-001 Operator ID:vtp Instrument ID:CHB.i Method:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:07-Nov-2017 13:39:32 Calib Date:07-Nov-2017 01:49:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal/External Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: daiglep Date:07-Nov-2017 09:21:09 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 9 BFB * 39 Chlorobromomethane 128 9.704 10.0 ND * 50 1,4-Difluorobenzene 114 11.108 10.0 ND * 72 Chlorobenzene-d5 117 15.212 10.0 ND Reagents: ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 366 of 478 Report Date: 07-Nov-2017 13:39:32 Chrom Revision: 2.2 28-Sep-2017 09:29:16MS Tune Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-01.D Injection Date:06-Nov-2017 15:25:30 Instrument ID:CHB.i Lims ID:bfb Client ID: Operator ID:vtp ALS Bottle#:1 Worklist Smp#:1 Injection Vol:0.0 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Tune Method: BFB Method TO-15 9 BFB 30 50 70 90 110 130 150 170 190 210 230 250m/z 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 Tune Spec :Average 19-21( 5.68-5.69 ) Bgrd 8( 5.62) 95 174 176 75 50 74 94 96 17751 m/z Ion Abundance Criteria %Relative Abundance 95 Base Peak,100 Percent Relative Abundance 100.0 50 8.0 to 40.0 Percent of m/e 95 16.6 75 30.0 to 66.0 Percent of m/e 95 44.8 96 5.0 to 9.0 Percent of m/e 95 6.6 173 Less than 2.0 Percent of m/e 174 0.0 (0.0) 174 50.0 to 120.0 Percent of m/e 95 88.8 175 4.0 to 9.0 Percent of m/e 174 6.4 (7.2) 176 93.0 to 101.0 Percent of m/e 174 87.0 (98.0) 177 5.0 to 9.0 Percent of m/e 176 5.6 (6.4) Page 367 of 478 Report Date: 07-Nov-2017 13:39:32 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-01.D\TO15_LLNJ_TO3.rslt\spectra.d Injection Date:06-Nov-2017 15:25:30 Spectrum:Tune Spec :Average 19-21( 5.68-5.69 ) Bgrd 8( 5.62) Base Peak:95.00 Minimum % Base Peak:0 Number of Points:118 m/z Y m/z Y m/z Y m/z Y 36.00 1897 69.00 24832 107.00 278 147.00 264 37.00 10894 70.00 1972 111.00 161 148.00 632 38.00 9501 71.00 84 112.00 84 149.00 212 39.00 3822 72.00 1271 113.00 144 150.00 207 40.00 68 73.00 9893 115.00 306 152.00 137 41.00 59 74.00 40448 116.00 685 153.00 198 43.00 52 75.00 129448 117.00 1214 154.00 183 44.00 1026 76.00 11364 118.00 721 155.00 638 45.00 1968 77.00 2026 119.00 1035 156.00 156 46.00 175 78.00 972 120.00 13 157.00 432 47.00 4294 79.00 4591 123.00 77 158.00 52 48.00 1209 80.00 1431 124.00 59 159.00 151 49.00 9161 81.00 4782 125.00 53 161.00 345 50.00 47928 82.00 1023 126.00 153 163.00 47 51.00 14954 83.00 53 127.00 50 169.00 43 52.00 603 86.00 188 128.00 881 170.00 54 55.00 635 87.00 13209 129.00 461 171.00 97 56.00 3240 88.00 13034 130.00 1002 172.00 423 57.00 5914 90.00 36 131.00 408 174.00 256640 58.00 51 91.00 765 135.00 258 175.00 18416 59.00 90 92.00 6637 136.00 39 176.00 251456 60.00 2118 93.00 10403 137.00 284 177.00 16157 61.00 10673 94.00 29984 139.00 35 178.00 580 62.00 10425 95.00 289024 140.00 135 192.00 89 63.00 7610 96.00 19120 141.00 2015 195.00 88 64.00 891 97.00 572 142.00 229 205.00 48 65.00 131 103.00 161 143.00 2080 239.00 41 66.00 76 104.00 959 144.00 142 252.00 33 67.00 488 105.00 398 145.00 203 68.00 25544 106.00 849 146.00 332 Page 368 of 478 Y ( X 1 0 0 0 0 0 ) Report Date: 28-Nov-2017 08:59:56 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-01.D Lims ID:bfb Client ID: Sample Type:BFB Inject. Date:24-Nov-2017 09:42:30 ALS Bottle#:1 Worklist Smp#:1 Injection Vol:0.0 mL Dil. Factor:1.0000 Sample Info:200-0028034-001 Operator ID:VTP Instrument ID:CHB.i Method:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:28-Nov-2017 08:59:55 Calib Date:07-Nov-2017 01:49:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal/External Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: puangmaleek Date:28-Nov-2017 08:59:55 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 9 BFB * 39 Chlorobromomethane 128 9.699 10.0 ND * 50 1,4-Difluorobenzene 114 11.102 10.0 ND * 72 Chlorobenzene-d5 117 15.212 10.0 ND Reagents: ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 370 of 478 Report Date: 28-Nov-2017 08:59:56 Chrom Revision: 2.2 13-Nov-2017 17:19:06MS Tune Report TestAmerica Burlington Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-01.D Injection Date:24-Nov-2017 09:42:30 Instrument ID:CHB.i Lims ID:bfb Client ID: Operator ID:VTP ALS Bottle#:1 Worklist Smp#:1 Injection Vol:0.0 mL Dil. Factor:1.0000 Method:TO15_LLNJ_TO3 Limit Group:AI_TO15_ICAL Tune Method: BFB Method TO-15 9 BFB 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210m/z 0 3 6 9 12 15 18 21 24 27 30 33 36 39 42 45 Tune Spec :Average 18-20( 5.68-5.69 ) Bgrd 8( 5.62) 95 174 176 75 50 74 94 96 177 m/z Ion Abundance Criteria %Relative Abundance 95 Base Peak,100 Percent Relative Abundance 100.0 50 8.0 to 40.0 Percent of m/e 95 14.1 75 30.0 to 66.0 Percent of m/e 95 40.8 96 5.0 to 9.0 Percent of m/e 95 6.6 173 Less than 2.0 Percent of m/e 174 0.0 (0.0) 174 50.0 to 120.0 Percent of m/e 95 91.6 175 4.0 to 9.0 Percent of m/e 174 6.7 (7.3) 176 93.0 to 101.0 Percent of m/e 174 89.5 (97.7) 177 5.0 to 9.0 Percent of m/e 176 5.8 (6.5) Page 371 of 478 Report Date: 28-Nov-2017 08:59:56 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-01.D\TO15_LLNJ_TO3.rslt\spectra.d Injection Date:24-Nov-2017 09:42:30 Spectrum:Tune Spec :Average 18-20( 5.68-5.69 ) Bgrd 8( 5.62) Base Peak:95.00 Minimum % Base Peak:0 Number of Points:121 m/z Y m/z Y m/z Y m/z Y 36.00 2304 69.00 35520 110.00 149 145.00 237 37.00 13501 70.00 2861 111.00 215 146.00 503 38.00 12453 71.00 129 112.00 120 147.00 270 39.00 4984 72.00 1756 113.00 158 148.00 824 40.00 369 73.00 15199 115.00 327 149.00 296 41.00 96 74.00 56592 116.00 1152 150.00 390 43.00 206 75.00 186368 117.00 1820 152.00 140 44.00 1064 76.00 15929 118.00 1178 153.00 289 45.00 2517 77.00 2565 119.00 1396 154.00 237 46.00 232 78.00 1727 120.00 52 155.00 949 47.00 5962 79.00 5674 122.00 54 156.00 202 48.00 1710 80.00 1835 123.00 130 157.00 600 49.00 12409 81.00 6054 124.00 205 158.00 38 50.00 64488 82.00 1486 125.00 100 159.00 368 51.00 19984 83.00 51 126.00 154 160.00 35 52.00 952 86.00 463 127.00 186 161.00 362 53.00 111 87.00 22624 128.00 1368 163.00 34 55.00 671 88.00 22112 129.00 701 170.00 92 56.00 4106 91.00 1089 130.00 1370 171.00 40 57.00 8247 92.00 9590 131.00 560 172.00 118 58.00 263 93.00 15298 133.00 168 174.00 418752 59.00 42 94.00 44632 134.00 34 175.00 30432 60.00 2748 95.00 457088 135.00 496 176.00 409280 61.00 14362 96.00 30048 136.00 145 177.00 26632 62.00 14235 97.00 933 137.00 514 178.00 699 63.00 10513 103.00 251 139.00 72 193.00 35 64.00 1095 104.00 1176 140.00 193 203.00 36 65.00 93 105.00 536 141.00 2479 207.00 50 66.00 37 106.00 1156 142.00 407 67.00 932 107.00 380 143.00 2763 68.00 35448 108.00 48 144.00 176 Page 372 of 478 Y ( X 1 0 0 0 0 0 ) Page 374 of 478 Page 375 of 478 Page 376 of 478 Page 377 of 478 Page 378 of 478 Page 379 of 478 Page 380 of 478 Report Date: 28-Nov-2017 09:04:47 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-04.D Lims ID:mb Client ID: Sample Type:MB Inject. Date:24-Nov-2017 12:18:30 ALS Bottle#:4 Worklist Smp#:4 Purge Vol:200.000 mL Dil. Factor:1.0000 Sample Info:200-0028034-004 Operator ID:VTP Instrument ID:CHB.i Method:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:28-Nov-2017 09:04:47 Calib Date:07-Nov-2017 01:49:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal/External Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: puangmaleek Date:28-Nov-2017 09:04:47 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 1 Propene 41 3.134 ND 2 Dichlorodifluoromethane 85 3.193 ND 3 Chlorodifluoromethane 51 3.225 ND 4 1,2-Dichloro-1,1,2,2-tetra 85 3.412 ND 5 Chloromethane 50 3.535 ND 6 Butane 43 3.716 3.716 0.005 59 2180 0.0379 7 7 Vinyl chloride 62 3.748 ND 8 Butadiene 54 3.812 ND 10 Bromomethane 94 4.479 ND 11 Chloroethane 64 4.709 ND 12 2-Methylbutane 43 4.789 ND 13 Vinyl bromide 106 5.120 ND 14 Trichlorofluoromethane 101 5.216 ND 15 Pentane 43 5.355 ND 16 Ethanol 45 5.669 ND 17 Ethyl ether 59 5.824 ND 18 Acrolein 56 6.198 ND 19 1,1,2-Trichloro-1,2,2-trif 101 6.246 ND 20 1,1-Dichloroethene 96 6.315 ND 21 Acetone 43 6.465 ND 22 Isopropyl alcohol 45 6.683 ND 23 Carbon disulfide 76 6.748 ND 24 3-Chloro-1-propene 41 7.014 ND 26 Acetonitrile 41 7.073 ND T 25 Methyl Acetate TIC 43 7.200 ND 27 Methylene Chloride 49 7.271 7.271 -0.005 33 1346 0.0268 7 28 2-Methyl-2-propanol 59 7.383 ND 29 Methyl tert-butyl ether 73 7.623 ND 30 trans-1,2-Dichloroethene 61 7.687 ND 31 Acrylonitrile 53 7.751 ND 32 Hexane 57 8.012 ND 33 1,1-Dichloroethane 63 8.423 ND Page 381 of 478 Report Date: 28-Nov-2017 09:04:47 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-04.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 34 Vinyl acetate 43 8.429 ND 36 2-Butanone (MEK) 72 9.315 ND 37 cis-1,2-Dichloroethene 96 9.331 ND 35 Ethyl acetate 88 9.331 ND * 39 Chlorobromomethane 128 9.694 9.699 -0.005 90 421652 10.0 10.0 38 Tetrahydrofuran 42 9.710 ND 40 Chloroform 83 9.774 ND S 41 1,2-Dichloroethene, Total 61 10.000 ND 42 1,1,1-Trichloroethane 97 10.030 ND 43 Cyclohexane 84 10.046 ND 44 Carbon tetrachloride 117 10.238 ND 45 Isooctane 57 10.521 ND 46 Benzene 78 10.563 ND 47 1,2-Dichloroethane 62 10.659 ND 48 n-Heptane 43 10.772 ND A 49 GRO 1 10.862 (4.779-16.946) 0 5254272 0 *50 1,4-Difluorobenzene 114 11.103 11.102 0.001 93 2106008 10.0 10.0 51 n-Butanol 56 11.284 ND 53 Trichloroethene 95 11.476 ND T 52 Methyl cyclohexane TIC 55 11.500 ND 54 1,2-Dichloropropane 63 11.839 ND 55 Methyl methacrylate 69 11.876 ND 56 1,4-Dioxane 88 11.967 ND 57 Dibromomethane 174 12.031 12.031 0.000 26 988 0.0161 7 58 Dichlorobromomethane 83 12.202 ND A 59 TVOC as Toluene 1 12.485 (3.124-21.845) 0 5566002 0 60 cis-1,3-Dichloropropene 75 12.826 ND 61 4-Methyl-2-pentanone (MIBK 43 12.976 ND 63 n-Octane 43 13.243 ND 64 Toluene 92 13.259 13.259 0.000 20 1510 0.0144 7 66 trans-1,3-Dichloropropene 75 13.621 ND 67 1,1,2-Trichloroethane 83 13.888 ND 68 Tetrachloroethene 166 14.032 ND 69 2-Hexanone 43 14.150 ND 70 Chlorodibromomethane 129 14.449 ND 71 Ethylene Dibromide 107 14.646 ND * 72 Chlorobenzene-d5 117 15.212 15.212 0.000 83 1754551 10.0 10.0 73 Chlorobenzene 112 15.249 ND 74 Ethylbenzene 91 15.313 15.313 -0.006 15 4926 0.0214 7 75 n-Nonane 57 15.340 ND 76 m-Xylene & p-Xylene 106 15.463 15.463 -0.005 0 673 0.007437 7 78 o-Xylene 106 15.975 15.975 0.000 12 1456 0.0162 7 S 77 Xylenes, Total 106 0 0.0236 7 79 Styrene 104 16.002 ND 80 Bromoform 173 16.295 ND 81 Isopropylbenzene 105 16.391 ND 83 1,1,2,2-Tetrachloroethane 83 16.797 ND 84 N-Propylbenzene 91 16.866 ND 85 1,2,3-Trichloropropane 75 16.877 ND 86 n-Decane 57 16.936 ND 87 4-Ethyltoluene 105 16.994 ND 88 2-Chlorotoluene 91 17.037 ND Page 382 of 478 Report Date: 28-Nov-2017 09:04:47 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-04.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 89 1,3,5-Trimethylbenzene 105 17.058 ND 90 Alpha Methyl Styrene 118 17.331 ND 91 tert-Butylbenzene 119 17.437 ND 92 1,2,4-Trimethylbenzene 105 17.507 ND 93 sec-Butylbenzene 105 17.694 ND 94 4-Isopropyltoluene 119 17.843 ND 95 1,3-Dichlorobenzene 146 17.923 ND 96 1,4-Dichlorobenzene 146 18.035 ND 97 Benzyl chloride 91 18.185 ND 98 Undecane 57 18.318 ND 99 n-Butylbenzene 91 18.350 ND 100 1,2-Dichlorobenzene 146 18.521 ND T 101 1,2-Dibromo-3-Chloropropan 75 19.300 ND 102 Dodecane 57 19.770 ND 103 1,2,4-Trichlorobenzene 180 20.880 ND 104 Hexachlorobutadiene 225 21.045 ND 105 Naphthalene 128 21.360 ND 106 1,2,3-Trichlorobenzene 180 21.835 ND T 107 Methyl acetylene TIC 1 0.000 ND T 108 1,1,1,2-Tetrachloroethane 1 0.000 ND T 117 Chlorotrifluoroethene TIC 1 0.000 ND T 118 Difluoroethane TIC 1 0.000 ND T 119 Freon 115 TIC 1 0.000 ND T 120 1,1,1-Trifluoro-2,2-dichlo 1 0.000 ND T 121 1,3-Dichloropropane TIC 1 0.000 ND QC Flag LegendProcessing Flags 7 - Failed Limit of Detection Reagents: ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 383 of 478 Y ( X 1 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 9 . 6 9 4 ) * 1 , 4 - D i f l u o r o b e n z e n e ( 1 1 . 0 9 7 ) + * C h l o r o b e n z e n e - d 5 ( 1 5 . 2 1 2 ) + Page 385 of 478 Page 386 of 478 Page 387 of 478 Report Date: 28-Nov-2017 09:02:29 Chrom Revision: 2.2 13-Nov-2017 17:19:06 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-03.D Lims ID:lcs Client ID: Sample Type:LCS Inject. Date:24-Nov-2017 11:25:30 ALS Bottle#:3 Worklist Smp#:3 Purge Vol:200.000 mL Dil. Factor:1.0000 Sample Info:200-0028034-003 Operator ID:VTP Instrument ID:CHB.i Method:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\TO15_LLNJ_TO3.m Limit Group:AI_TO15_ICAL Last Update:28-Nov-2017 09:01:07 Calib Date:07-Nov-2017 01:49:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal/External Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHB.i\20171106-27754.b\27754-13.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK022 First Level Reviewer: puangmaleek Date:28-Nov-2017 09:02:27 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 1 Propene 41 3.145 3.134 0.011 98 185903 10.0 7.66 2 Dichlorodifluoromethane 85 3.209 3.193 0.016 99 745317 10.0 8.04 3 Chlorodifluoromethane 51 3.241 3.225 0.016 98 412994 10.0 7.83 4 1,2-Dichloro-1,1,2,2-tetra 85 3.428 3.412 0.016 96 924132 10.0 9.49 5 Chloromethane 50 3.551 3.535 0.016 99 265230 10.0 8.02 6 Butane 43 3.727 3.711 0.016 99 453279 10.0 7.93 7 Vinyl chloride 62 3.764 3.748 0.016 98 350835 10.0 8.80 8 Butadiene 54 3.833 3.812 0.021 94 253078 10.0 8.67 10 Bromomethane 94 4.495 4.479 0.016 100 390988 10.0 9.53 11 Chloroethane 64 4.730 4.709 0.021 99 225870 10.0 9.16 12 2-Methylbutane 43 4.815 4.789 0.026 95 471706 10.0 9.08 13 Vinyl bromide 106 5.141 5.120 0.021 99 408719 10.0 9.77 14 Trichlorofluoromethane 101 5.242 5.216 0.026 98 854811 10.0 8.64 15 Pentane 43 5.381 5.355 0.026 96 749231 10.0 9.49 16 Ethanol 45 5.723 5.669 0.054 98 247635 15.0 11.4 9 BFB 17 Ethyl ether 59 5.856 5.824 0.032 94 309486 10.0 10.2 18 Acrolein 56 6.219 6.198 0.021 95 167589 10.0 11.9 19 1,1,2-Trichloro-1,2,2-trif 101 6.267 6.246 0.021 99 785730 10.0 9.45 20 1,1-Dichloroethene 96 6.336 6.315 0.021 96 390835 10.0 9.39 21 Acetone 43 6.497 6.465 0.032 96 541265 10.0 8.71 22 Isopropyl alcohol 45 6.731 6.683 0.048 99 583325 10.0 8.35 23 Carbon disulfide 76 6.769 6.748 0.021 98 1260861 10.0 10.8 24 3-Chloro-1-propene 41 7.036 7.014 0.022 92 480111 10.0 8.26 26 Acetonitrile 41 7.100 7.073 0.027 100 351717 10.0 9.80 27 Methylene Chloride 49 7.292 7.276 0.016 92 429284 10.0 8.61 28 2-Methyl-2-propanol 59 7.425 7.383 0.042 92 795070 10.0 8.73 29 Methyl tert-butyl ether 73 7.655 7.623 0.032 97 1126798 10.0 9.08 30 trans-1,2-Dichloroethene 61 7.703 7.687 0.016 98 604127 10.0 9.56 31 Acrylonitrile 53 7.777 7.751 0.026 97 324315 10.0 9.73 32 Hexane 57 8.034 8.012 0.022 90 704750 10.0 9.28 33 1,1-Dichloroethane 63 8.445 8.423 0.022 99 757865 10.0 8.97 Page 388 of 478 Report Date: 28-Nov-2017 09:02:29 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-03.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 34 Vinyl acetate 43 8.455 8.429 0.026 100 1046232 10.0 9.00 36 2-Butanone (MEK) 72 9.336 9.315 0.021 97 227784 10.0 9.30 37 cis-1,2-Dichloroethene 96 9.346 9.331 0.015 95 454081 10.0 9.44 35 Ethyl acetate 88 9.352 9.331 0.021 94 40388 10.0 9.98 * 39 Chlorobromomethane 128 9.715 9.699 0.016 90 418664 10.0 10.0 38 Tetrahydrofuran 42 9.731 9.710 0.021 94 484241 10.0 8.89 40 Chloroform 83 9.789 9.774 0.015 95 805445 10.0 8.93 S 41 1,2-Dichloroethene, Total 61 0 20.0 19.0 42 1,1,1-Trichloroethane 97 10.046 10.030 0.016 95 758340 10.0 8.87 43 Cyclohexane 84 10.056 10.046 0.010 96 627732 10.0 9.76 44 Carbon tetrachloride 117 10.254 10.238 0.016 97 769395 10.0 9.50 45 Isooctane 57 10.531 10.521 0.010 100 2231922 10.0 9.17 46 Benzene 78 10.574 10.563 0.011 95 1388855 10.0 9.25 47 1,2-Dichloroethane 62 10.675 10.659 0.016 96 452984 10.0 8.47 48 n-Heptane 43 10.782 10.772 0.010 90 788498 10.0 8.47 A 49 GRO 1 10.862 (4.779-16.946) 0 165796371 10.0 0 * 50 1,4-Difluorobenzene 114 11.118 11.102 0.016 93 2041262 10.0 10.0 51 n-Butanol 56 11.310 11.284 0.026 84 314982 10.0 10.8 53 Trichloroethene 95 11.487 11.476 0.011 97 579150 10.0 9.67 54 1,2-Dichloropropane 63 11.855 11.839 0.016 94 529350 10.0 9.16 55 Methyl methacrylate 69 11.887 11.876 0.011 98 519622 10.0 9.66 56 1,4-Dioxane 88 11.983 11.967 0.016 92 280887 10.0 9.85 57 Dibromomethane 174 12.042 12.031 0.011 96 549097 10.0 9.21 58 Dichlorobromomethane 83 12.212 12.202 0.010 97 886701 10.0 8.79 A 59 TVOC as Toluene 1 12.485 (3.124-21.845) 0 263934958 10.0 0 60 cis-1,3-Dichloropropene 75 12.837 12.826 0.011 88 771995 10.0 9.47 61 4-Methyl-2-pentanone (MIBK 43 12.986 12.976 0.010 94 966479 10.0 8.46 63 n-Octane 43 13.253 13.243 0.010 90 1113484 10.0 8.49 64 Toluene 92 13.264 13.259 0.005 93 1010013 10.0 9.45 66 trans-1,3-Dichloropropene 75 13.627 13.621 0.006 94 738453 10.0 9.47 67 1,1,2-Trichloroethane 83 13.899 13.888 0.011 94 506658 10.0 9.61 68 Tetrachloroethene 166 14.038 14.032 0.006 98 828276 10.0 9.78 69 2-Hexanone 43 14.160 14.150 0.010 96 946600 10.0 8.87 70 Chlorodibromomethane 129 14.449 14.449 0.000 98 939555 10.0 9.35 71 Ethylene Dibromide 107 14.657 14.646 0.011 98 902784 10.0 9.67 * 72 Chlorobenzene-d5 117 15.217 15.212 0.005 84 1788667 10.0 10.0 73 Chlorobenzene 112 15.254 15.249 0.005 97 1375152 10.0 9.65 74 Ethylbenzene 91 15.324 15.319 0.005 97 2179983 10.0 9.31 75 n-Nonane 57 15.345 15.340 0.005 95 1098472 10.0 9.16 76 m-Xylene & p-Xylene 106 15.468 15.468 0.000 0 1751765 20.0 19.0 78 o-Xylene 106 15.980 15.975 0.005 99 846395 10.0 9.22 S 77 Xylenes, Total 106 0 30.0 28.2 79 Styrene 104 16.002 16.002 0.000 97 1341406 10.0 9.70 80 Bromoform 173 16.295 16.295 0.000 98 914698 10.0 9.86 81 Isopropylbenzene 105 16.391 16.391 0.000 95 2388055 10.0 9.20 83 1,1,2,2-Tetrachloroethane 83 16.797 16.797 0.000 97 1344284 10.0 9.53 84 N-Propylbenzene 91 16.872 16.866 0.006 99 2930931 10.0 9.17 85 1,2,3-Trichloropropane 75 16.882 16.877 0.005 98 967662 10.0 8.97 86 n-Decane 57 16.941 16.936 0.005 89 1305150 10.0 8.59 87 4-Ethyltoluene 105 16.994 16.994 0.000 98 2408691 10.0 9.47 88 2-Chlorotoluene 91 17.037 17.037 0.000 96 1914405 10.0 9.04 89 1,3,5-Trimethylbenzene 105 17.064 17.058 0.006 93 1877507 10.0 8.93 Page 389 of 478 Report Date: 28-Nov-2017 09:02:29 Chrom Revision: 2.2 13-Nov-2017 17:19:06 Data File:\\ChromNA\Burlington\ChromData\CHB.i\20171124-28034.b\28034-03.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 90 Alpha Methyl Styrene 118 17.336 17.331 0.005 90 957289 10.0 9.30 91 tert-Butylbenzene 119 17.437 17.437 0.000 96 1765826 10.0 8.68 92 1,2,4-Trimethylbenzene 105 17.507 17.507 0.000 96 1793091 10.0 8.63 93 sec-Butylbenzene 105 17.693 17.694 -0.001 99 2689564 10.0 8.52 94 4-Isopropyltoluene 119 17.848 17.843 0.005 98 2226407 10.0 8.58 95 1,3-Dichlorobenzene 146 17.923 17.923 0.000 97 1244381 10.0 9.01 96 1,4-Dichlorobenzene 146 18.035 18.035 0.000 96 1209031 10.0 8.95 97 Benzyl chloride 91 18.184 18.185 -0.001 100 1393965 10.0 9.03 98 Undecane 57 18.318 18.318 0.000 96 1493920 10.0 9.04 99 n-Butylbenzene 91 18.355 18.350 0.005 98 2080226 10.0 8.73 100 1,2-Dichlorobenzene 146 18.521 18.521 0.000 97 1123377 10.0 8.65 102 Dodecane 57 19.769 19.770 -0.001 97 1152677 10.0 9.02 103 1,2,4-Trichlorobenzene 180 20.880 20.880 0.000 94 714152 10.0 8.86 104 Hexachlorobutadiene 225 21.045 21.045 0.000 98 741181 10.0 8.73 105 Naphthalene 128 21.360 21.360 0.000 100 1418446 10.0 8.33 106 1,2,3-Trichlorobenzene 180 21.835 21.835 0.000 96 599823 10.0 8.58 Reagents: ATTO15LCSW_00723 Amount Added: 200.00 Units: mL ATTO15BISs_00006 Amount Added: 20.00 Units: mL Run Reagent Page 390 of 478 Y ( X 1 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 9 . 7 1 5 ) + * 1 , 4 - D i f l u o r o b e n z e n e ( 1 1 . 1 1 3 ) * C h l o r o b e n z e n e - d 5 ( 1 5 . 2 1 7 ) Page 392 of 478 Page 393 of 478 б-¬óÍ¿³°´·²¹ ß·® Ý¿²·-¬»® Ю»--«®» ݸ»½µ λ½±®¼ ß²¿´§-¬ È È È Ô¿¾ ×Ü Ð®»--«®»ï ß²±³¿´§ øþع÷ øÇñÒ÷ îððóìïïïíóßóï óîòç Ò îððóìïïïíóßóî óîòç Ò îððóìïïïíóßóí óîòê Ò îððóìïïïíóßóì óîòï Ò ×º ®»¬«®² °®»--«®» ·- ²±¬ ©·¬¸·² ½®·¬»®·¿ô ·²·¬·¿¬» Ò±²óݱ²º±®³¿²½» Ó»³±ò í λ½±®¼ ¬¸» ×Ü ±º ¬¸» ÚÝ «-»¼ º±® -¿³°´·²¹ ·º ·²º±®³¿¬·±² ·- °®±ª·¼»¼ô ±¬¸»®©·-» ´»¿ª» ¾´¿²µò ì ¿²¼ п¹» ²«³¾»® ·² ©¸·½¸ ¬¸» ±®·¹·²¿´ ÚÝ Ý¸»½µ ©¿- ®»½±®¼»¼ ï Ý®·¬»®·¿æ 묫®² Ю»--«®» -¸±«´¼ ¾» ¾»¬©»»² óï ¿²¼ óïð øþع÷ ©·¬¸ ¬¸» »¨½»°¬·±² ±º ¹®¿¾ -¿³°´»- ±® ¬¸±-» «-·²¹ ïðð ±® îðð³Ôñ³·²«¬» º´±© ½±²¬®±´´»®-ò ̸»-» -¿³°´»- ³«-¬ ¾» ®»¬«®²»¼ ¿¬ ²± ´±©»® ¬¸¿² óïðþعô ¾«¬ ¸¿ª» ²± -°»½·º·½ ½®·¬»®·¿ ±¬¸»®©·-»ò ëêíîóîééîë íðïð íççí éèìì ìèðí ìïèè éèìì Ç Ç ëêíîóîééîë ììíêóîééîë ëêíîóîééîëîëíéëîðï Çéèìì ìííë íççç ÚÝ ì Çéèìì øÇñÒ÷ ø©ñ Ô±½¿¬·±² ݱ¼»÷ îï øÓ·´·¬¿®§÷ øþع÷ ø’Ý÷ îððóìïïïí Ùóîì б-¬óÍ¿³°´·²¹ 묫®² Ю»--«®» ݸ»½µ øì÷ ×- ª·-·¾´» -·¹² ±º ¼¿³¿¹» ¬± ½¿²·-¬»® ¿²¼ñ±® º´±© ½±²¬®±´´»® øÚÝ÷ °®»-»²¬á ׺ ¼¿³¿¹» ±¾-»®ª»¼ô ´·-¬ »¯«·°³»²¬ ×Ü- ¿²¼ ¼»-½®·¾» ïïñîîñïé ïíæîë Í¿³°´·²¹ ײº±®³¿¬·±² ¿²¼ 묫®² Û¯«·°³»²¬ ݸ»½µ ݱ³³»²¬- ×Üí Ю»--«®» øí÷ Óß ÓÝÐ ú ÒÖ ÜÕÏÐæ ݸ»½µ ®»¬«®² º´±© ®¿¬» º±® º´ Ì·³»Ô¿¾ Ì»³° øï÷ ×- ¿ Ú·»´¼ Ì»-¬ Ü¿¬¿ ͸»»¬ øÚÌÜÍ÷ ±® -·³·´¿® -¿³°´·²¹ ¼±½«³»²¬¿¬·±² °®»-»²¬á Ù¿«¹» ×Ü Ý±³³»²¬- îçòè øî÷ ×- ¬¸» º´±© ½±²¬®±´´»® ×Ü «-»¼ º±® »¿½¸ ½¿²·-¬»® ®»½±®¼»¼á ÚÍÎðîïæðëòïðòïêæï Ì»-¬ß³»®·½¿ Þ«®´·²¹¬±²Page 394 of 478 Page 395 of 478 Page 396 of 478 Page 397 of 478 Page 398 of 478 Page 399 of 478 Page 400 of 478 Page 401 of 478 Page 402 of 478 Page 403 of 478 Page 404 of 478 Report Date: 06-Nov-2017 08:47:53 Chrom Revision: 2.2 28-Sep-2017 09:29:16 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHX.i\20171103-27725.b\27725_06.D Lims ID:mb Client ID: Sample Type:MB Inject. Date:03-Nov-2017 13:47:30 ALS Bottle#:6 Worklist Smp#:6 Purge Vol:200.000 mL Dil. Factor:1.0000 Sample Info:200-0027725-006 Operator ID:pad Instrument ID:CHX.i Method:\\ChromNA\Burlington\ChromData\CHX.i\20171103-27725.b\TO15_MasterMethod_X.m.m Limit Group:AI_TO15_ICAL Last Update:06-Nov-2017 08:47:52 Calib Date:24-Oct-2017 00:08:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHX.i\20171023-27547.b\27547_12.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK013 First Level Reviewer: puangmaleek Date:06-Nov-2017 08:47:52 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 1 Propene 41 3.044 ND 2 Dichlorodifluoromethane 85 3.108 ND 3 Chlorodifluoromethane 51 3.156 ND 4 1,2-Dichloro-1,1,2,2-tetra 85 3.354 ND 5 Chloromethane 50 3.488 ND 6 Butane 43 3.670 ND 7 Vinyl chloride 62 3.712 ND 8 Butadiene 54 3.782 ND 10 Bromomethane 94 4.419 ND 11 Chloroethane 64 4.638 ND 12 2-Methylbutane 43 4.702 ND 13 Vinyl bromide 106 5.007 ND 14 Trichlorofluoromethane 101 5.098 ND 16 Pentane 43 5.226 ND 17 Ethanol 45 5.692 5.654 0.038 98 2996 0.2075 18 Ethyl ether 59 5.729 ND 20 1,1,2-Trichloro-1,2,2-trif 101 6.120 ND 19 Acrolein 56 6.120 ND 21 1,1-Dichloroethene 96 6.173 ND 22 Acetone 43 6.468 6.468 0.043 26 3171 0.0785 7 23 Carbon disulfide 76 6.564 ND 24 Isopropyl alcohol 45 6.762 6.708 0.054 97 4820 0.0999 25 3-Chloro-1-propene 41 6.949 ND 26 Acetonitrile 41 7.104 ND 27 Methylene Chloride 49 7.243 ND 28 2-Methyl-2-propanol 59 7.479 ND 29 Methyl tert-butyl ether 73 7.645 ND 31 trans-1,2-Dichloroethene 61 7.677 ND 32 Acrylonitrile 53 7.853 ND 33 Hexane 57 8.046 ND 34 1,1-Dichloroethane 63 8.565 ND 35 Vinyl acetate 43 8.645 ND Page 405 of 478 Report Date: 06-Nov-2017 08:47:53 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHX.i\20171103-27725.b\27725_06.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags S 30 1,2-Dichloroethene, Total 61 9.665 ND 37 cis-1,2-Dichloroethene 96 9.699 ND 38 2-Butanone (MEK) 72 9.768 ND 39 Ethyl acetate 88 9.806 ND * 40 Chlorobromomethane 128 10.180 10.186 -0.006 97 332462 10.0 10.0 41 Tetrahydrofuran 42 10.202 ND 42 Chloroform 83 10.325 ND 43 Cyclohexane 84 10.560 ND 44 1,1,1-Trichloroethane 97 10.603 ND 45 Carbon tetrachloride 117 10.854 ND 46 Isooctane 57 11.309 ND 47 Benzene 78 11.363 ND 48 1,2-Dichloroethane 62 11.566 ND 49 n-Heptane 43 11.726 ND * 50 1,4-Difluorobenzene 114 12.261 12.267 -0.006 95 1717793 10.0 10.0 52 n-Butanol 56 12.721 ND 53 Trichloroethene 95 12.759 ND A 51 GRO 1 13.211 (4.692-21.730) 0 5483485 0 54 1,2-Dichloropropane 63 13.358 ND 55 Methyl methacrylate 69 13.545 ND 56 1,4-Dioxane 88 13.609 ND 57 Dibromomethane 174 13.625 ND 58 Dichlorobromomethane 83 13.941 ND 60 cis-1,3-Dichloropropene 75 14.920 ND A 59 TVOC as Toluene 92 15.118 (3.034-27.202) 0 5534858 0 61 4-Methyl-2-pentanone (MIBK 43 15.241 ND 65 Toluene 92 15.530 ND 64 n-Octane 43 15.583 ND 66 trans-1,3-Dichloropropene 75 16.177 ND 67 1,1,2-Trichloroethane 83 16.568 ND 68 Tetrachloroethene 166 16.659 ND 69 2-Hexanone 43 17.055 ND 71 Chlorodibromomethane 129 17.365 ND 72 Ethylene Dibromide 107 17.648 ND * 74 Chlorobenzene-d5 117 18.595 18.595 0.000 88 1512641 10.0 10.0 75 Chlorobenzene 112 18.660 ND 76 Ethylbenzene 91 18.820 ND 77 n-Nonane 57 18.954 ND 78 m-Xylene & p-Xylene 106 19.088 ND S 73 Xylenes, Total 106 19.600 ND 79 o-Xylene 106 19.981 ND 80 Styrene 104 20.045 ND 81 Bromoform 173 20.511 ND 82 Isopropylbenzene 105 20.741 ND 84 1,1,2,2-Tetrachloroethane 83 21.468 ND 85 N-Propylbenzene 91 21.527 ND 86 1,2,3-Trichloropropane 75 21.564 ND 87 n-Decane 57 21.720 ND 88 4-Ethyltoluene 105 21.730 ND 89 2-Chlorotoluene 91 21.736 ND 90 1,3,5-Trimethylbenzene 105 21.848 ND 91 Alpha Methyl Styrene 118 22.238 ND Page 406 of 478 Report Date: 06-Nov-2017 08:47:53 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHX.i\20171103-27725.b\27725_06.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 92 tert-Butylbenzene 119 22.367 ND 93 1,2,4-Trimethylbenzene 105 22.469 ND 94 sec-Butylbenzene 105 22.709 ND 95 4-Isopropyltoluene 119 22.923 ND 96 1,3-Dichlorobenzene 146 22.950 ND 97 1,4-Dichlorobenzene 146 23.094 ND 98 Benzyl chloride 91 23.303 ND 100 n-Butylbenzene 91 23.517 ND 99 Undecane 57 23.544 ND 101 1,2-Dichlorobenzene 146 23.645 ND 102 Dodecane 57 25.175 ND 103 1,2,4-Trichlorobenzene 180 26.213 ND 104 Hexachlorobutadiene 225 26.401 ND 105 Naphthalene 128 26.711 ND 106 1,2,3-Trichlorobenzene 180 27.192 ND T 118 Chlorotrifluoroethene TIC 1 0.000 ND T 107 Methyl acetylene TIC 1 0.000 ND T 119 Difluoroethane TIC 1 0.000 ND T 121 1,1,1-Trifluoro-2,2-dichlo 1 0.000 ND T 120 Freon 115 TIC 1 0.000 ND T 36 Methyl cyclohexane TIC 55 0.000 ND T 15 Methyl Acetate TIC 43 0.000 ND T 70 1,2-Dibromo-3-Chloropropan 75 0.000 ND T 108 1,1,1,2-Tetrachloroethane 1 0.000 ND T 109 1,3-Dichloropropane TIC 1 0.000 ND QC Flag LegendProcessing Flags 7 - Failed Limit of Detection Reagents: ATTO15XISs_00002 Amount Added: 20.00 Units: mL Run Reagent Page 407 of 478 Y ( X 1 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 1 0 . 1 8 0 ) * 1 , 4 - D i f l u o r o b e n z e n e ( 1 2 . 2 6 1 ) * C h l o r o b e n z e n e - d 5 ( 1 8 . 5 9 0 ) + Page 409 of 478 Page 410 of 478 Page 411 of 478 Page 412 of 478 Report Date: 06-Nov-2017 08:47:53 Chrom Revision: 2.2 28-Sep-2017 09:29:16 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHX.i\20171103-27725.b\27725_06.D Lims ID:mb Client ID: Sample Type:MB Inject. Date:03-Nov-2017 13:47:30 ALS Bottle#:6 Worklist Smp#:6 Purge Vol:200.000 mL Dil. Factor:1.0000 Sample Info:200-0027725-006 Operator ID:pad Instrument ID:CHX.i Method:\\ChromNA\Burlington\ChromData\CHX.i\20171103-27725.b\TO15_MasterMethod_X.m.m Limit Group:AI_TO15_ICAL Last Update:06-Nov-2017 08:47:52 Calib Date:24-Oct-2017 00:08:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHX.i\20171023-27547.b\27547_12.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK013 First Level Reviewer: puangmaleek Date:06-Nov-2017 08:47:52 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 1 Propene 41 3.044 ND 2 Dichlorodifluoromethane 85 3.108 ND 3 Chlorodifluoromethane 51 3.156 ND 4 1,2-Dichloro-1,1,2,2-tetra 85 3.354 ND 5 Chloromethane 50 3.488 ND 6 Butane 43 3.670 ND 7 Vinyl chloride 62 3.712 ND 8 Butadiene 54 3.782 ND 10 Bromomethane 94 4.419 ND 11 Chloroethane 64 4.638 ND 12 2-Methylbutane 43 4.702 ND 13 Vinyl bromide 106 5.007 ND 14 Trichlorofluoromethane 101 5.098 ND 16 Pentane 43 5.226 ND 17 Ethanol 45 5.692 5.654 0.038 98 2996 0.2075 18 Ethyl ether 59 5.729 ND 20 1,1,2-Trichloro-1,2,2-trif 101 6.120 ND 19 Acrolein 56 6.120 ND 21 1,1-Dichloroethene 96 6.173 ND 22 Acetone 43 6.468 6.468 0.043 26 3171 0.0785 7 23 Carbon disulfide 76 6.564 ND 24 Isopropyl alcohol 45 6.762 6.708 0.054 97 4820 0.0999 25 3-Chloro-1-propene 41 6.949 ND 26 Acetonitrile 41 7.104 ND 27 Methylene Chloride 49 7.243 ND 28 2-Methyl-2-propanol 59 7.479 ND 29 Methyl tert-butyl ether 73 7.645 ND 31 trans-1,2-Dichloroethene 61 7.677 ND 32 Acrylonitrile 53 7.853 ND 33 Hexane 57 8.046 ND 34 1,1-Dichloroethane 63 8.565 ND 35 Vinyl acetate 43 8.645 ND Page 413 of 478 Report Date: 06-Nov-2017 08:47:53 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHX.i\20171103-27725.b\27725_06.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags S 30 1,2-Dichloroethene, Total 61 9.665 ND 37 cis-1,2-Dichloroethene 96 9.699 ND 38 2-Butanone (MEK) 72 9.768 ND 39 Ethyl acetate 88 9.806 ND * 40 Chlorobromomethane 128 10.180 10.186 -0.006 97 332462 10.0 10.0 41 Tetrahydrofuran 42 10.202 ND 42 Chloroform 83 10.325 ND 43 Cyclohexane 84 10.560 ND 44 1,1,1-Trichloroethane 97 10.603 ND 45 Carbon tetrachloride 117 10.854 ND 46 Isooctane 57 11.309 ND 47 Benzene 78 11.363 ND 48 1,2-Dichloroethane 62 11.566 ND 49 n-Heptane 43 11.726 ND * 50 1,4-Difluorobenzene 114 12.261 12.267 -0.006 95 1717793 10.0 10.0 52 n-Butanol 56 12.721 ND 53 Trichloroethene 95 12.759 ND A 51 GRO 1 13.211 (4.692-21.730) 0 5483485 0 54 1,2-Dichloropropane 63 13.358 ND 55 Methyl methacrylate 69 13.545 ND 56 1,4-Dioxane 88 13.609 ND 57 Dibromomethane 174 13.625 ND 58 Dichlorobromomethane 83 13.941 ND 60 cis-1,3-Dichloropropene 75 14.920 ND A 59 TVOC as Toluene 92 15.118 (3.034-27.202) 0 5534858 0 61 4-Methyl-2-pentanone (MIBK 43 15.241 ND 65 Toluene 92 15.530 ND 64 n-Octane 43 15.583 ND 66 trans-1,3-Dichloropropene 75 16.177 ND 67 1,1,2-Trichloroethane 83 16.568 ND 68 Tetrachloroethene 166 16.659 ND 69 2-Hexanone 43 17.055 ND 71 Chlorodibromomethane 129 17.365 ND 72 Ethylene Dibromide 107 17.648 ND * 74 Chlorobenzene-d5 117 18.595 18.595 0.000 88 1512641 10.0 10.0 75 Chlorobenzene 112 18.660 ND 76 Ethylbenzene 91 18.820 ND 77 n-Nonane 57 18.954 ND 78 m-Xylene & p-Xylene 106 19.088 ND S 73 Xylenes, Total 106 19.600 ND 79 o-Xylene 106 19.981 ND 80 Styrene 104 20.045 ND 81 Bromoform 173 20.511 ND 82 Isopropylbenzene 105 20.741 ND 84 1,1,2,2-Tetrachloroethane 83 21.468 ND 85 N-Propylbenzene 91 21.527 ND 86 1,2,3-Trichloropropane 75 21.564 ND 87 n-Decane 57 21.720 ND 88 4-Ethyltoluene 105 21.730 ND 89 2-Chlorotoluene 91 21.736 ND 90 1,3,5-Trimethylbenzene 105 21.848 ND 91 Alpha Methyl Styrene 118 22.238 ND Page 414 of 478 Report Date: 06-Nov-2017 08:47:53 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHX.i\20171103-27725.b\27725_06.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 92 tert-Butylbenzene 119 22.367 ND 93 1,2,4-Trimethylbenzene 105 22.469 ND 94 sec-Butylbenzene 105 22.709 ND 95 4-Isopropyltoluene 119 22.923 ND 96 1,3-Dichlorobenzene 146 22.950 ND 97 1,4-Dichlorobenzene 146 23.094 ND 98 Benzyl chloride 91 23.303 ND 100 n-Butylbenzene 91 23.517 ND 99 Undecane 57 23.544 ND 101 1,2-Dichlorobenzene 146 23.645 ND 102 Dodecane 57 25.175 ND 103 1,2,4-Trichlorobenzene 180 26.213 ND 104 Hexachlorobutadiene 225 26.401 ND 105 Naphthalene 128 26.711 ND 106 1,2,3-Trichlorobenzene 180 27.192 ND T 118 Chlorotrifluoroethene TIC 1 0.000 ND T 107 Methyl acetylene TIC 1 0.000 ND T 119 Difluoroethane TIC 1 0.000 ND T 121 1,1,1-Trifluoro-2,2-dichlo 1 0.000 ND T 120 Freon 115 TIC 1 0.000 ND T 36 Methyl cyclohexane TIC 55 0.000 ND T 15 Methyl Acetate TIC 43 0.000 ND T 70 1,2-Dibromo-3-Chloropropan 75 0.000 ND T 108 1,1,1,2-Tetrachloroethane 1 0.000 ND T 109 1,3-Dichloropropane TIC 1 0.000 ND QC Flag LegendProcessing Flags 7 - Failed Limit of Detection Reagents: ATTO15XISs_00002 Amount Added: 20.00 Units: mL Run Reagent Page 415 of 478 Y ( X 1 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 1 0 . 1 8 0 ) * 1 , 4 - D i f l u o r o b e n z e n e ( 1 2 . 2 6 1 ) * C h l o r o b e n z e n e - d 5 ( 1 8 . 5 9 0 ) + Page 417 of 478 Page 418 of 478 Page 419 of 478 Page 420 of 478 Page 421 of 478 Page 422 of 478 Page 423 of 478 Page 424 of 478 Page 425 of 478 Page 426 of 478 Page 427 of 478 Report Date: 06-Nov-2017 09:07:15 Chrom Revision: 2.2 28-Sep-2017 09:29:16 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHX.i\20171103-27725.b\27725_08.D Lims ID:200-40706-A-6 Client ID:5632 Sample Type:Client Inject. Date:03-Nov-2017 15:43:30 ALS Bottle#:8 Worklist Smp#:8 Purge Vol:200.000 mL Dil. Factor:0.2000 Sample Info:200-0027725-008 Misc. Info.:40706-06 Operator ID:pad Instrument ID:CHX.i Method:\\ChromNA\Burlington\ChromData\CHX.i\20171103-27725.b\TO15_MasterMethod_X.m.m Limit Group:AI_TO15_ICAL Last Update:06-Nov-2017 09:07:14 Calib Date:24-Oct-2017 00:08:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHX.i\20171023-27547.b\27547_12.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK013 First Level Reviewer: puangmaleek Date:06-Nov-2017 09:07:14 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags 1 Propene 41 3.044 ND 2 Dichlorodifluoromethane 85 3.108 ND 3 Chlorodifluoromethane 51 3.156 ND 4 1,2-Dichloro-1,1,2,2-tetra 85 3.354 ND 5 Chloromethane 50 3.493 3.488 0.005 94 1208 0.0489 6 Butane 43 3.670 ND 7 Vinyl chloride 62 3.712 ND 8 Butadiene 54 3.782 ND 10 Bromomethane 94 4.419 ND 11 Chloroethane 64 4.638 ND 13 Vinyl bromide 106 5.007 ND 14 Trichlorofluoromethane 101 5.098 ND 17 Ethanol 45 5.697 5.654 0.043 97 2999 0.2201 20 1,1,2-Trichloro-1,2,2-trif 101 6.120 ND 21 1,1-Dichloroethene 96 6.173 ND 22 Acetone 43 6.425 ND 23 Carbon disulfide 76 6.564 ND 24 Isopropyl alcohol 45 6.762 6.708 0.054 97 3558 0.0782 25 3-Chloro-1-propene 41 6.949 ND 27 Methylene Chloride 49 7.243 ND 28 2-Methyl-2-propanol 59 7.479 ND 29 Methyl tert-butyl ether 73 7.645 ND 31 trans-1,2-Dichloroethene 61 7.677 ND 33 Hexane 57 8.046 ND 34 1,1-Dichloroethane 63 8.565 ND 35 Vinyl acetate 43 8.645 ND S 30 1,2-Dichloroethene, Total 61 9.665 ND 37 cis-1,2-Dichloroethene 96 9.699 ND 38 2-Butanone (MEK) 72 9.768 ND 39 Ethyl acetate 88 9.806 ND * 40 Chlorobromomethane 128 10.186 10.186 0.000 98 313748 10.0 Page 428 of 478 Report Date: 06-Nov-2017 09:07:15 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHX.i\20171103-27725.b\27725_08.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags 41 Tetrahydrofuran 42 10.202 ND 42 Chloroform 83 10.325 ND 43 Cyclohexane 84 10.560 ND 44 1,1,1-Trichloroethane 97 10.603 ND 45 Carbon tetrachloride 117 10.854 ND 46 Isooctane 57 11.309 ND 47 Benzene 78 11.363 ND 48 1,2-Dichloroethane 62 11.566 ND 49 n-Heptane 43 11.726 ND * 50 1,4-Difluorobenzene 114 12.267 12.267 0.000 95 1594194 10.0 53 Trichloroethene 95 12.759 ND 54 1,2-Dichloropropane 63 13.358 ND 55 Methyl methacrylate 69 13.545 ND 56 1,4-Dioxane 88 13.609 ND 57 Dibromomethane 174 13.625 ND 58 Dichlorobromomethane 83 13.941 ND 60 cis-1,3-Dichloropropene 75 14.920 ND 61 4-Methyl-2-pentanone (MIBK 43 15.241 ND 65 Toluene 92 15.530 ND 66 trans-1,3-Dichloropropene 75 16.177 ND 67 1,1,2-Trichloroethane 83 16.568 ND 68 Tetrachloroethene 166 16.659 ND 69 2-Hexanone 43 17.055 ND 71 Chlorodibromomethane 129 17.365 ND 72 Ethylene Dibromide 107 17.648 ND * 74 Chlorobenzene-d5 117 18.595 18.595 0.000 89 1382833 10.0 75 Chlorobenzene 112 18.660 ND 76 Ethylbenzene 91 18.820 ND 78 m-Xylene & p-Xylene 106 19.088 ND S 73 Xylenes, Total 106 19.600 ND 79 o-Xylene 106 19.981 ND 80 Styrene 104 20.045 ND 81 Bromoform 173 20.511 ND 82 Isopropylbenzene 105 20.741 ND 84 1,1,2,2-Tetrachloroethane 83 21.468 ND 85 N-Propylbenzene 91 21.527 ND 88 4-Ethyltoluene 105 21.730 ND 89 2-Chlorotoluene 91 21.736 ND 90 1,3,5-Trimethylbenzene 105 21.848 ND 92 tert-Butylbenzene 119 22.367 ND 93 1,2,4-Trimethylbenzene 105 22.469 ND 94 sec-Butylbenzene 105 22.709 ND 95 4-Isopropyltoluene 119 22.923 ND 96 1,3-Dichlorobenzene 146 22.950 ND 97 1,4-Dichlorobenzene 146 23.094 ND 98 Benzyl chloride 91 23.303 ND 100 n-Butylbenzene 91 23.517 ND 101 1,2-Dichlorobenzene 146 23.645 ND 103 1,2,4-Trichlorobenzene 180 26.213 ND 104 Hexachlorobutadiene 225 26.401 ND 105 Naphthalene 128 26.711 ND Page 429 of 478 Report Date: 06-Nov-2017 09:07:15 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Reagents: ATTO15XISs_00002 Amount Added: 20.00 Units: mL Run Reagent Page 430 of 478 Y ( X 1 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 1 0 . 1 8 6 ) * 1 , 4 - D i f l u o r o b e n z e n e ( 1 2 . 2 6 7 ) * C h l o r o b e n z e n e - d 5 ( 1 8 . 5 9 5 ) Page 432 of 478 Page 433 of 478 Page 434 of 478 Report Date: 06-Nov-2017 09:16:48 Chrom Revision: 2.2 28-Sep-2017 09:29:16 TestAmerica Burlington Target Compound Quantitation Report Data File:\\ChromNA\Burlington\ChromData\CHX.i\20171103-27725.b\27725_10.D Lims ID:200-40725-A-2 Client ID:4436 Sample Type:Client Inject. Date:03-Nov-2017 17:38:30 ALS Bottle#:10 Worklist Smp#:10 Purge Vol:200.000 mL Dil. Factor:0.2000 Sample Info:200-0027725-010 Misc. Info.:40725-02 Operator ID:pad Instrument ID:CHX.i Method:\\ChromNA\Burlington\ChromData\CHX.i\20171103-27725.b\TO15_MasterMethod_X.m.m Limit Group:AI_TO15_ICAL Last Update:06-Nov-2017 09:16:46 Calib Date:24-Oct-2017 00:08:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Burlington\ChromData\CHX.i\20171023-27547.b\27547_12.D Column 1 :RTX-624 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK013 First Level Reviewer: puangmaleek Date:06-Nov-2017 09:16:46 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags 1 Propene 41 3.044 ND 2 Dichlorodifluoromethane 85 3.108 ND 3 Chlorodifluoromethane 51 3.156 ND 4 1,2-Dichloro-1,1,2,2-tetra 85 3.354 ND 5 Chloromethane 50 3.488 ND 6 Butane 43 3.670 ND 7 Vinyl chloride 62 3.712 ND 8 Butadiene 54 3.782 ND 10 Bromomethane 94 4.419 ND 11 Chloroethane 64 4.638 ND 13 Vinyl bromide 106 5.007 ND 14 Trichlorofluoromethane 101 5.098 ND 17 Ethanol 45 5.686 5.654 0.032 99 3286 0.2518 20 1,1,2-Trichloro-1,2,2-trif 101 6.120 ND 21 1,1-Dichloroethene 96 6.173 ND 22 Acetone 43 6.473 6.473 0.048 67 4346 0.1190 7 23 Carbon disulfide 76 6.574 6.564 0.010 98 2797 0.0386 24 Isopropyl alcohol 45 6.762 6.708 0.054 97 3985 0.0914 25 3-Chloro-1-propene 41 6.949 ND 27 Methylene Chloride 49 7.243 ND 28 2-Methyl-2-propanol 59 7.479 ND 29 Methyl tert-butyl ether 73 7.645 ND 31 trans-1,2-Dichloroethene 61 7.677 ND 33 Hexane 57 8.046 ND 34 1,1-Dichloroethane 63 8.565 ND 35 Vinyl acetate 43 8.645 ND S 30 1,2-Dichloroethene, Total 61 9.665 ND 37 cis-1,2-Dichloroethene 96 9.699 ND 38 2-Butanone (MEK) 72 9.768 ND 39 Ethyl acetate 88 9.806 ND * 40 Chlorobromomethane 128 10.186 10.186 0.000 98 300504 10.0 Page 435 of 478 Report Date: 06-Nov-2017 09:16:48 Chrom Revision: 2.2 28-Sep-2017 09:29:16 Data File:\\ChromNA\Burlington\ChromData\CHX.i\20171103-27725.b\27725_10.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags 41 Tetrahydrofuran 42 10.202 ND 42 Chloroform 83 10.325 ND 43 Cyclohexane 84 10.560 ND 44 1,1,1-Trichloroethane 97 10.603 ND 45 Carbon tetrachloride 117 10.854 ND 46 Isooctane 57 11.309 ND 47 Benzene 78 11.363 ND 48 1,2-Dichloroethane 62 11.566 ND 49 n-Heptane 43 11.726 ND * 50 1,4-Difluorobenzene 114 12.267 12.267 0.000 95 1525189 10.0 53 Trichloroethene 95 12.759 ND 54 1,2-Dichloropropane 63 13.358 ND 55 Methyl methacrylate 69 13.545 ND 56 1,4-Dioxane 88 13.609 ND 57 Dibromomethane 174 13.625 ND 58 Dichlorobromomethane 83 13.941 ND 60 cis-1,3-Dichloropropene 75 14.920 ND 61 4-Methyl-2-pentanone (MIBK 43 15.241 ND 65 Toluene 92 15.541 15.530 0.011 89 1498 0.0224 66 trans-1,3-Dichloropropene 75 16.177 ND 67 1,1,2-Trichloroethane 83 16.568 ND 68 Tetrachloroethene 166 16.659 ND 69 2-Hexanone 43 17.055 ND 71 Chlorodibromomethane 129 17.365 ND 72 Ethylene Dibromide 107 17.648 ND * 74 Chlorobenzene-d5 117 18.595 18.595 0.000 92 1315337 10.0 75 Chlorobenzene 112 18.660 ND 76 Ethylbenzene 91 18.825 18.820 0.005 88 1848 0.0122 78 m-Xylene & p-Xylene 106 19.087 19.088 -0.001 0 1152 0.0193 S 73 Xylenes, Total 106 0 0.0193 7 79 o-Xylene 106 19.981 ND 80 Styrene 104 20.045 ND 81 Bromoform 173 20.511 ND 82 Isopropylbenzene 105 20.741 ND 84 1,1,2,2-Tetrachloroethane 83 21.468 ND 85 N-Propylbenzene 91 21.527 ND 88 4-Ethyltoluene 105 21.730 ND 89 2-Chlorotoluene 91 21.736 ND 90 1,3,5-Trimethylbenzene 105 21.848 ND 92 tert-Butylbenzene 119 22.367 ND 93 1,2,4-Trimethylbenzene 105 22.469 ND 94 sec-Butylbenzene 105 22.709 ND 95 4-Isopropyltoluene 119 22.923 ND 96 1,3-Dichlorobenzene 146 22.950 ND 97 1,4-Dichlorobenzene 146 23.094 ND 98 Benzyl chloride 91 23.303 ND 100 n-Butylbenzene 91 23.517 ND 101 1,2-Dichlorobenzene 146 23.645 ND 103 1,2,4-Trichlorobenzene 180 26.213 ND 104 Hexachlorobutadiene 225 26.401 ND 105 Naphthalene 128 26.711 ND Page 436 of 478 Report Date: 06-Nov-2017 09:16:48 Chrom Revision: 2.2 28-Sep-2017 09:29:16 QC Flag Legend Processing Flags 7 - Failed Limit of Detection Reagents: ATTO15XISs_00002 Amount Added: 20.00 Units: mL Run Reagent Page 437 of 478 Y ( X 1 0 0 0 0 0 ) * C h l o r o b r o m o m e t h a n e ( 1 0 . 1 8 6 ) * 1 , 4 - D i f l u o r o b e n z e n e ( 1 2 . 2 6 7 ) * C h l o r o b e n z e n e - d 5 ( 1 8 . 5 9 5 ) Pa g e 4 3 9 o f 4 7 8 Pa g e 4 4 0 o f 4 7 8 Pa g e 4 4 1 o f 4 7 8 Pa g e 4 4 2 o f 4 7 8 Pa g e 4 4 3 o f 4 7 8 Pa g e 4 4 4 o f 4 7 8 Pa g e 4 4 5 o f 4 7 8 Pa g e 4 4 6 o f 4 7 8 Pa g e 4 4 7 o f 4 7 8 Pa g e 4 4 8 o f 4 7 8 Pa g e 4 4 9 o f 4 7 8 Pa g e 4 5 0 o f 4 7 8 Pa g e 4 5 1 o f 4 7 8 Pa g e 4 5 2 o f 4 7 8 Pa g e 4 5 3 o f 4 7 8 Pa g e 4 5 4 o f 4 7 8 Pa g e 4 5 5 o f 4 7 8 Pa g e 4 5 6 o f 4 7 8 Pa g e 4 5 7 o f 4 7 8 Pa g e 4 5 8 o f 4 7 8 Page 459 of 478 Page 460 of 478 Page 461 of 478 Page 462 of 478 Page 463 of 478 Page 464 of 478 Page 465 of 478 Page 466 of 478 Page 467 of 478 Page 468 of 478 Page 469 of 478 Page 470 of 478 Page 471 of 478 Page 472 of 478 Page 473 of 478 Page 474 of 478 Page 475 of 478 Page 476 of 478 Page 477 of 478 Page 478 of 478 900 King Street VILLAGE OF RYE BROOK, NEW YORK Preliminary Geotechnical Engineering Report AKRF Project Number: 170073 Prepared for: 900 King Street Owner, LLC c/o George Comfort & Sons, Inc. 200 Madison Avenue New York, NY 10016 Prepared by: AKRF, Inc. 34 South Broadway White Plains, NY 10601 914-949-7336 NOVEMBER 9, 2017 AKRF, Inc.Preliminary Geotechnical Engineering Report 900 King Street, Village of Rye Brook,NY Project No. 170073 i TABLE OF CONTENTS 1.0 INTRODUCTION ...........................................................................................................................1 2.0 SITE DESCRIPTION ......................................................................................................................1 3.0 PROPOSED DEVELOPMENT.......................................................................................................1 4.0 REVIEW OF AVAILABLE INFORMATION...............................................................................2 4.1 Geologic Setting ..........................................................................................................................2 4.2 Historical Land Use.....................................................................................................................2 5.0 SUBSURFACE EXPLORATION...................................................................................................2 5.1 Geotechnical Boring Program.....................................................................................................2 5.2 Temporary Groundwater Observation Wells...............................................................................3 5.3 Geotechnical Laboratory Testing ................................................................................................3 5.4 Infiltration Testing.......................................................................................................................3 6.0 GENERALIZED SUBSURFACE CONDITIONS..........................................................................4 6.1 Topsoil.........................................................................................................................................4 6.2 Asphalt.........................................................................................................................................4 6.3 Fill................................................................................................................................................4 6.4 Sand (Classes 4)..........................................................................................................................5 6.5 Soft Rock.....................................................................................................................................5 6.6 Foliated Rock (Class 2)...............................................................................................................5 6.7 Groundwater Level ......................................................................................................................5 6.7.1 Observation Well OW-1..........................................................................................................5 6.7.2 Observation Well OW-2..........................................................................................................6 6.7.3 Observation Well Discussion..................................................................................................6 6.8 Infiltration Test Results ...............................................................................................................6 7.0 PRELIMINARY GEOTECHNICAL EVALUATION AND DESIGN RECOMMENDATIONS.6 7.1 Seismic Evaluation ......................................................................................................................6 7.2 Liquefaction Potential..................................................................................................................7 7.3 Shallow Foundation Recommendations ......................................................................................7 7.3.1 Lowest Floor Slab Support......................................................................................................7 7.4 Lateral Earth Pressures................................................................................................................7 7.5 Permanent Groundwater Control.................................................................................................8 7.5.1 Design Groundwater Level .....................................................................................................8 7.5.2 Foundation Waterproofing ......................................................................................................8 8.0 FOUNDATION CONSTRUCTION RECOMMENDATIONS......................................................8 8.1 Excavation ...................................................................................................................................8 8.2 Construction Dewatering.............................................................................................................8 8.3 Subgrade Preparation...................................................................................................................9 8.4 Fill Material and Compaction Criteria.........................................................................................9 8.5 Construction Documents, Special Inspections, and Quality Assurance......................................9 9.0 ADDITIONAL EXPLORATIONS ...............................................................................................10 10.0 LIMITATIONS..............................................................................................................................10 11.0 REFERENCES ..............................................................................................................................11 AKRF, Inc.Preliminary Geotechnical Engineering Report 900 King Street, Village of Rye Brook,NY Project No. 170073 ii FIGURES Figure 1 Site Location Map Figure 2 Surficial Geologic Map Figure 3 Bedrock Map Figure 4 1947 Aerial Figure 5 1976 Aerial Figure 6 1990 Aerial Figure 7 Boring Location Plan Figure 8 Liquefaction Potential APPENDICES Appendix A Soil Boring Logs Appendix B Groundwater Observation Well Logs Appendix C Geotechnical Laboratory Results AKRF, Inc.Preliminary Geotechnical Engineering Report 900 King Street, Village of Rye Brook,NY Project No. 170073 1 1.0 INTRODUCTION AKRF, Inc. (AKRF) has prepared this preliminary geotechnical engineering report to summarize the results of our recent geotechnical field exploration for the proposed new buildings located at 900 King Street in the Village of Rye Brook,New York herein after referred to as “the site.”The preliminary geotechnical evaluations and recommendations presented herein are in accordance with the 2016 New York State Uniform Code (NYUSC)1. The preliminary exploration work described in this report was performed by AKRF in accordance with our August 23, 2017 proposal, and authorized by 900 King Street Owner, LLC on September 19, 2017. AKRF used the following information in preparation of this report: A draft site survey titled “900 King Street Development”,prepared by John Meyer Consulting, Inc (JMC), dated July 12, 2017. Concept Plans (SK01A through SK03), prepared by Perkins Eastman, dated September 9, 2017. Proposed boring location plan, prepared by JMC, dated September 26, 2017. PUD Concept Plan and Preliminary Site Plans, prepared by JMC, dated October 26, 2017. All elevations (el.) cited in this report are based on the draft site survey, measured in feet. The vertical datum referenced is not known at the time of preparing this report. 2.0 SITE DESCRIPTION The site is located at 900 King Street in the Village of Rye Brook, NY. The site is roughly rectangular in shape and is currently occupied by a 2-story office building, with the remainder of the site utilized as parking and landscaped areas (see Figure 1). The site is bounded to the north by a property occupied by the Village of Rye Brook police department, Village Hall and firehouse. The site is bounded to the east by Arbor Drive (a private driveway owned by the Arbors Homeowners’ Association for which the Owner has an access easement), and is bounded to the south by The Arbors residential community. The site is bounded to the west by a forested area,with the Hutchinson River parkway beyond. The site has varying topography and generally slopes down from west to east. The forested wetland area at the western corner of the site is about el. +275 and slopes down to the west side of the existing 2-story building at about el. +262. The existing parking lot varies between about el. +254 at the west side of the lot and slopes down to about el. +244 at the north east corner of the lot. Arbor Drive fronts the site and slopes down from about el. +250 at the south side of the site to about el. +220 at the intersection with King Street. 3.0 PROPOSED DEVELOPMENT The proposed development involves the construction of a 4-story senior living building, a 4-story assisted living building, and 24 townhouse units located in 12 buildings. The remainder of the site will be 1 The New York State Uniform Code incorporates the third printing of the 2015 International Building Code (from October 2015) and the second printing of the 2015 International Residential Code (from January 2016). AKRF, Inc.Preliminary Geotechnical Engineering Report 900 King Street, Village of Rye Brook,NY Project No. 170073 2 developed with new access roads, parking lots, and recreational areas.One below grade level is proposed for a parking garage below the senior living building.. A portion of the new building footprint appears to overlap with the footprint of the existing 2-story office building.We discuss the potential for possible conflict between remnant foundation elements of the existing office building,with the new foundation elements of the proposed building,in a subsequent section of this report. 4.0 REVIEW OF AVAILABLE INFORMATION 4.1 Geologic Setting The Surficial Geologic Map of New York (see Figure 2) shows that the site is located in an area of Rye Brook where surficial soils are composed predominantly of till. These soils are variable in texture and composition and include a variety of gravels, sands, and fine grained materials (silt/clays). The presence of cobbles and boulders within the soil matrix is common. The Geologic Map of New York (see Figure 3) shows that the bedrock underlying the site is comprised of the Harrison Gneiss Formation. 4.2 Historical Land Use We have reviewed available historical aerials from the Westchester County Geographic Systems to determine previous land use at the site.We have also reviewed an article titled, “The Arbors –Historical Perspective” by Joel Mitchell. The 1947 through 1976 aerials (Figures 4 and 5)show structures located towards the southern corner of the site and the north eastern side of the site respectively.Based off of the article by Joel Mitchells, it is possible that the structure on the north eastern side of the site was called the Harkness Pavillion, a colonial building and property. During the early 1980s, the Harkness Pavillion was demolished and the current commercial office building was constructed (see figure 6 for a 1990 historic aerial). There have been no significant changes to the site since the early 1980s. 5.0 SUBSURFACE EXPLORATION 5.1 Geotechnical Boring Program A total of 13 geotechnical borings, designated PB-1 through PB-13, were drilled at the site between October 2, 2017 and October 10, 2017, under the full-time oversight of an AKRF geotechnical engineer. The boring locations were prescribed by JMC. The borings were advanced to depths of between about 32 feet and 55 feet below the existing ground surface.The boring locations are shown in Figure 7. Drilling was performed by Craig Geotechnical Drilling Company, Inc. of Mays Landing, NJ, using a truck-mounted CME 75 drill rig equipped with an automatic hammer. The borings were advanced using the mud rotary technique with a 3-7/8-inch diameter tri-cone roller bit. Soil samples were obtained in all borings in accordance with the American Society for Testing and Materials (ASTM) Standard Specification D1586. The Standard Penetration Test (SPT) consists of driving a 2-inch outside diameter split spoon sampler for a depth of 24 inches with repeated blows of a 140-pound hammer free-falling 30 inches. The standard penetration, or N-value, is defined as the number of blows required to drive the sampler for a 12-inch interval after an initial 6 inches of sampler penetration and is measured in blows per foot (bpf). All soil samples obtained from the borings were visually classified in the field using the AKRF, Inc.Preliminary Geotechnical Engineering Report 900 King Street, Village of Rye Brook,NY Project No. 170073 3 Unified Soil Classification System. Rock cores were obtained in 8 of the 13 borings using a 5-foot long NQ2 core barrel in accordance with ASTM Standard Specification D2113. The top of bedrock was estimated based on drilling operations (e.g. excessive rig chatter or difficult penetration) and practical split spoon refusal, as indicated by blow counts greater than 100 for a 6-inch interval on the split spoon sampler. Rock coring was performed to confirm the presence of bedrock, and to assess its relative quality as indicated by Core Recovery2 and the Rock Quality Designation (RQD)3. The RQD was determined in accordance with ASTM Standard Specification D6032. The soil boring logs are included in Appendix A. 5.2 Temporary Groundwater Observation Wells Two temporary groundwater observation wells, designated OW-1 and OW-2, were installed in completed boreholes PB-8 and PB-4, respectively. The wells were constructed of 2-inch nominal diameter Schedule 40 PVC pipe. Both wells were installed to a depth of about 20 feet, with a 10-foot long slotted screen at the bottom and a 10 foot long solid riser pipe extending to about 6 inches below ground surface. The annulus between the pipe and the wall of the boreholes was backfilled with clean filter sand to about 2 feet above section of pipe. A two-foot thick bentonite seal was installed at the top of the filter sand. The remainder of the annulus was backfilled with bentonite and soil cuttings generated from drilling the borings. The groundwater observation well logs are included in Appendix B 5.3 Geotechnical Laboratory Testing Geotechnical laboratory testing was performed on selected samples collected during the subsurface exploration. The purpose of the geotechnical laboratory testing was to confirm field soil classifications and to define the mechanical and physical soil properties for use in the foundation design and construction recommendations. The geotechnical laboratory testing consisted of 17 sieve analyses performed in accordance with ASTM Standard Specification D422. The geotechnical laboratory results are included in Appendix C. 5.4 Infiltration Testing JMC specified that two infiltration tests, designated PB-12 and PB-13,were to be performed following the guidelines of the New York State Stormwater Management Design Manual (January, 2015), Appendix D –Infiltration Testing Requirements. The proposed test locations, along with the depth of the proposed bottom of practice, were specified by JMC as shown on drawing No. BL-1 “Boring Location Plan”, dated May 18, 2017. The infiltration test borings were drilled at the site on October 3, 2017 and the infiltration tests were performed on October 6, 2017. 2 The Core Recovery is defined as the ratio (expressed as a percentage) of the total length of the recovered core to the total length of the rock cored. 3 The RQD is defined as the ratio (expressed as a percentage) of the total length of recovered core samples having a length of at least 4 inches to the total length of the rock cored. AKRF, Inc.Preliminary Geotechnical Engineering Report 900 King Street, Village of Rye Brook,NY Project No. 170073 4 Two borings were advanced at each infiltration test location. Both borings were advanced to a depth of at least 4 feet below the proposed bottom of facility. Soil samples were retrieved at 2 foot intervals using SPT methods. Soil samples corresponding to the depth of the proposed facility bottom, and 4 feet below the proposed facility bottom, were sent for further geotechnical laboratory testing to confirm field soil classifications and to define the mechanical and physical soil properties of the soil. The geotechnical laboratory testing of disturbed samples consisted of four sieve analyses performed in accordance with ASTM Standard Specification D422. Both borings were offset about 5 feet from the first boring and were advanced using steel casing with an outside diameter of 4.5 inches. A 2-inch-thick layer of coarse sand was placed at the bottom of the borings and clean potable water was filled to a height of 2 feet above the bottom of the borehole. The water was allowed to “pre-soak” for a minimum of 24 hours. After the pre-soak period was complete, the borehole was filled with clean water to a height of 2 feet above the bottom of the borehole. The drop in water level was measured 1 hour after filling. The infiltration rate is reported as the drop in height over the 1 hour period in units of inches per hour. This procedure was repeated an additional three times, for a total of four tests (Tests 1 through 4). The summary of the observations and test results are provided in a subsequent section. 6.0 GENERALIZED SUBSURFACE CONDITIONS Based on our review of the logs, we present our preliminary interpretation of the generalized subsurface conditions with the following strata and groundwater descriptions. 6.1 Topsoil A surficial layer of topsoil consisting of sand and silt was encountered in borings PB-1 through PB-3, PB- 6 and PB-11. The topsoil is characterized by the presence of roots and ranged in thickness from about 4 inches to about 5 inches. The thickness of the topsoil was measured at the boring locations only and may vary throughout the site. 6.2 Asphalt Asphalt was encountered in borings PB-4, PB-5, and PB-7 through PB-13. The asphalt was measured to be about 4 inches thick at each boring location. 6.3 Fill Uncontrolled fill was encountered beneath the topsoil at discrete locations. The fill generally consists of brown to gray sand with varying amounts of gravel, silt, and other miscellaneous fill including brick, asphalt, concrete, and pieces of tile. The fill ranged in thickness between about 4 feet and about 9 feet. Uncorrected SPT N-values ranged from 2 bpf to 73 bpf. The fill is characterized as very loose to very dense in terms of relative density. AKRF, Inc.Preliminary Geotechnical Engineering Report 900 King Street, Village of Rye Brook,NY Project No. 170073 5 6.4 Sand (Classes 4)4 Brown sand was encountered in all borings below the topsoil, asphalt, and fill layers. The sand ranged in thickness from about 9 feet and 31 feet. Uncorrected SPT N-values ranged between about 3 bpf and 94 blows over 10 inches (practical refusal).The average SPT N-value (not including practical refusal) is about 29 bpf. The material is classified as very loose to very dense in terms of relative density and is classified as Class 4 material in accordance with NYSUC. 6.5 Soft Rock Soft rock was encountered in all borings, except boring PB-1, and consisted of brownish, orange and black, fine to medium grained sand with varying amounts of silt and mica. The top of the soft rock was encountered at depths ranging from 9 feet below existing grade in boring PB-13 to 35 feet below existing grade in boring PB-2, corresponding to an elevation of about el +227 and el. +234 respectively. The soft rock extended to the boring termination depths except in borings PB-1, PB-4,PB-6, PB-8, and PB-13.The soft rock was characterized by drilling operations, practical sampler refusal, split spoon samples, or by rock cores. Uncorrected SPT N-values ranged from 50 blows over 1 inch to 100 blows over 5 inches. The core recoveries ranged from 33 percent to 58 percent, and the RQD ranged from 10 percent to 23 percent. 6.6 Foliated Rock (Class 2) Foliated rock was encountered in 5 of the borings to boring termination depths. The foliated rock generally consisted of gray to black schistic gneiss of the Harrison Gneiss Formation and is intensely to moderately fractured and fresh to slightly weathered. The foliated rock was characterized by rock core recoveries. The depths to the top of foliated rock ranged from about 11 feet below existing grade in boring PB-13 and 44 feet below existing grade in boring PB-6,corresponding to about elevation el. +232 and el. +211 respectively. The rock core recoveries ranged from 58 percent and 93 percent and the RQD ranged from 40 percent and 87 percent. 6.7 Groundwater Level The depth to groundwater was measured in two observation wells (OW-1 and OW-2) during our time on site between October 5, 2017 and October 14, 2017. 6.7.1 Observation Well OW-1 Observation well OW-1 was installed in completed borehole PB-8 near the northern side of the site. The top of the well was set at about el. +245. The well was installed on October 5, 2017 and was constructed of a 10-foot long slotted screen and a 10-foot long solid riser section. The screened section is within the sand, soft rock, and competent rock layers encountered in the boring. The well was pumped twice to a depth of about 14.5 feet and 7 feet below existing grade on October 5, 2017 and October 6, 2017 respectively. The well was then bailed to a depth of about 9 feet below existing grade on October 10,2017. Measurements were taken during the recharge times until a consistent groundwater depth was measured. 4 Class numbers indicate material class in accordance with NYSUC. NYSUC does not classify topsoil, fill, or soft rock material. AKRF, Inc.Preliminary Geotechnical Engineering Report 900 King Street, Village of Rye Brook,NY Project No. 170073 6 During our time on site, the groundwater within the well stabilized at a depth of about 6 feet below existing ground surface, corresponding to an elevation of about el. +239. 6.7.2 Observation Well OW-2 Observation well OW-2 was installed in completed borehole PB-4 near the western side of the site. The top of the well was set at about el. +247. The well was installed on October 10, 2017 and was constructed of a 10-foot long slotted screen and a 10-foot long solid riser section. The screened section is within the sand and soft rock layers encountered within the boring. The well was pumped once to a depth of 11 feet. Measurements were taken during the recharge time after pumping. The well was then bailed to a depth of about 10 feet below existing grade and measurements were taken again during the recharge time. On October 11 and 12, 2017, the well was bailed again to depths 6 feet and 15 feet below existing ground surface, and on October 14, 2017, the well was bailed to a depth of about 19.5 feet below existing ground surface. Measurements were taken during each recharge time until the water level was observed to stabilize at a depth of 2 feet below ground surface,corresponding to an elevation of about el. +245. 6.7.3 Observation Well Discussion Considering the high water level in OW-2 with respect to OW-1, it is likely that there is a possibility of perched water flowing beneath the asphalt into OW-2, causing water level readings to be erroneous in OW-2.We recommend that additional field work, discussed in a subsequent section, is completed to confirm the depth of ground water in this area. 6.8 Infiltration Test Results The following table presents a summary of the infiltration testing. Location ID Test Depth (ft) Test 1 (inch/hr) Test 2 (inch/hr) Test 3 (inch/hr) Test 4 (inch/hr) Average (inch/hr)** PB-12 6 1.0 0.5 0.25 1.0 0.69 PB-13 7 1.0 0.25 0.875 0.375 0.63 **Average infiltration rate is average of four tests (Test 1 through Test 4). 7.0 PRELIMINARY GEOTECHNICAL EVALUATION AND DESIGN RECOMMENDATIONS This section presents our preliminary engineering evaluations and recommendations for the design of the foundations. The evaluations and recommendations are based on the results of the subsurface exploration, our experience on other projects, and the information we have been provided to date on the design requirements for the proposed building. 7.1 Seismic Evaluation The seismic design recommendations presented in this section are in accordance with NYSUC Section 1613. The mapped acceleration parameters for the site location outlined in the NYSUC are as follows: for a short period, SS = 0..264g and for a 1-second period, S1 = 0.071g. The subsurface exploration revealed a profile consisting of loose to very dense soil based on an evaluation of SPT N-values, with a weighted average of the corrected N60 values of about 25 bpf.Therefore, we recommend a “stiff soil” profile be assigned with a corresponding Site Class D. AKRF, Inc.Preliminary Geotechnical Engineering Report 900 King Street, Village of Rye Brook,NY Project No. 170073 7 We assume the building will be assigned to Structural Occupancy/Risk Category (SO/RC) II. The appropriate SO/RC should be confirmed by the Architect or Structural Engineer. Based on the assumed Site Class and SO/RC the recommended Seismic Design Category is B. 7.2 Liquefaction Potential Liquefaction is the full or partial loss of shear strength of granular or cohesionless soils during an earthquake. The potential consequences of liquefaction could include loss of bearing capacity causing collapse or excessive settlement of ground. Potentially liquefiable soil types include loose clean sands and silty sands below the groundwater table to a depth of 50 feet. While the NYSUC does not provide guidance on evaluating sites for the potential of liquefaction, Section 1813 of the 2014 New York City Building Code (NYCBC)provides a basic screening chart that indicates whether liquefaction potential should be considered. The N605 values are plotted on the NYCBC screening chart as shown in Figure 8.Based on this evaluation and considering that the seismic criteria used for evaluating liquefaction potential in New York City is likely more stringent for a larger earthquake than would be expected at the site location in Rye Brook, liquefaction is not considered a concern for the site. 7.3 Shallow Foundation Recommendations Due to the presence of the medium dense to dense sands, we recommend supporting the buildings on shallow foundations. The bearing stratum should be a minimum of 4-feet below the finished ground surface for frost protection. The recommended allowable bearing pressure is 2 tons per square foot (tsf). Estimated elastic settlements for shallow foundations bearing on dense sand of the sand stratum are estimated to be less than one inch. 7.3.1 Lowest Floor Slab Support The lowest floor slab of the proposed buildings can be designed as a slab-on-grade bearing on a 12-inch thick layer of ¾-inch gravel. We recommend the top 2-feet of existing soil is excavated and removed before the placement of controlled structural fill and the proposed slab. The exposed existing soil should be proof rolled and controlled structural fill should be placed and compacted to subgrade elevation in accordance with the construction recommendations provided in subsequent sections of this report. 7.4 Lateral Earth Pressures Permanent below grade walls will be subject to lateral pressures from soil and vehicular surcharges. In the static loading condition, lateral pressures from soil and surcharge loads should be considered. Backfill should not be placed against below-grade walls for at least 7 days,until the concrete has reached its 28- day compressive design strength, and after adequate lateral bracing has been provided to prevent rotation of the walls, or as directed by the structural engineer. We recommend the following design parameters: For backfill soils behind braced walls (no rotation), a unit weight of 130 pounds per cubic foot with an angle of friction of 30 degrees. The at rest lateral earth pressure coefficient is 0.5. For braced walls, a triangular earth pressure distribution with an equivalent fluid weight of 65 pounds per square foot (psf) per foot of depth (starting from ground surface) for unsaturated soil above the static ground water level. 5 Field SPT N-values corrected for rod length and hammer efficiency. AKRF, Inc.Preliminary Geotechnical Engineering Report 900 King Street, Village of Rye Brook,NY Project No. 170073 8 In addition to lateral earth pressures, lateral pressures due to any surcharge loads adjacent to the foundation walls should be considered. Surcharge loads should have a uniform distribution based on a pressure equal to 0.5 times the vertical surcharge for the entire depth of the walls. The magnitude of the vertical surcharge loads should be determined by the structural engineer. 7.5 Permanent Groundwater Control 7.5.1 Design Groundwater Level Considering the difference of ground water level readings observed between OW-1 and OW-2,and the possibility of perched water flowing into OW-2, the design ground water level should be decided after additional field work is completed as discussed in a subsequent section. 7.5.2 Foundation Waterproofing To limit groundwater seepage and water vapor infiltration (through the concrete, cold joints, shrinkage cracks, and/or utility penetrations) and associated dampness, we recommend that the lowest floor slab be fully waterproofed. We recommend a membrane type waterproofing be used, such as products by GCP Applied Technologies. For horizontal applications, we recommend that the waterproofing membrane be installed on a 2-inch- thick concrete substrate (mud-slab). The installation of all foundation waterproofing elements should be performed by a certified installer and be inspected on a full-time basis to confirm that the waterproofing is being installed as per the manufacturer's specifications and details. 8.0 FOUNDATION CONSTRUCTION RECOMMENDATIONS This section presents a discussion of our recommendations regarding foundation construction aspects of the proposed development. Based on the most recent floor plans provided by Perkins Eastman, no below-grade levels are planned for the proposed building.The foundation construction recommendations should be re-evaluated if a lower level is proposed. 8.1 Excavation The bottom of foundations should be at least 4 feet below the proposed finished grade, and grade beams should be at least 18 inches below the proposed finished grade for frost protection. The general excavation will primarily involve the removal of fill material and sand, and can be performed with conventional earth-moving equipment such as backhoes, excavators, and dozers. Over-excavation may be required in areas where remnant foundation elements are present and excavation equipment with demolition capabilities may be required to remove these obstructions. All excavation should be performed in accordance with OSHA requirements including, but not limited to, temporary shoring, use of trench boxes, and proper benching, where necessary. 8.2 Construction Dewatering All foundation work should be conducted “in the dry.” Groundwater may be encountered during site excavation and foundation construction. Any water encountered during construction can likely be handled by localized sump pits and pumps. Groundwater must be discharged in accordance with New York State Department of Environmental Conservation (DEC) regulations. AKRF, Inc.Preliminary Geotechnical Engineering Report 900 King Street, Village of Rye Brook,NY Project No. 170073 9 8.3 Subgrade Preparation The excavation will be conducted in the existing sand material to reach the proposed finished floor elevation. Care should be taken to prevent the disturbance and softening of the foundation bearing stratum. We recommend the contractor excavate the last 12 inches of soil above the proposed foundation bearing elevation using an excavator equipped with a straight-edged bucket, or by hand excavation. We do not recommend using a standard bucket with teeth as the teeth will likely disturb and loosen the subgrade soil. Upon excavating to the proposed footing and slab-on-grade subgrade elevations, the subgrade material should be inspected and approved by the Special Inspector. A proof-roll inspection should be conducted in the presence of the Special Inspector to confirm that the bearing material is stable and firm. Areas of soft, rutted, or “pumping” subgrade material should be over-excavated and replaced with controlled structural fill. We recommend areas of subgrade for slab-on-grade construction, new pavement, and footings are proof-rolled with about five to six passes of a heavy smooth-drum vibratory roller. Smaller compaction equipment such as a walk-behind roller may be used in areas of limited access such as trenches or localized areas of excavation. The exposed subgrade surface should be level and free of debris and/or other unsatisfactory material. Foundation concrete should be placed as soon as possible on the prepared subgrade to prevent disturbance. The approved subgrade surface must be protected at all times from precipitation, freezing weather, and construction traffic until concrete is placed. Methods of protection include sealing with lean concrete (mud-slab). The contractor shall not place any concrete for foundations on frozen ground, or where snow or standing water is present. We note the soil is susceptible to exposure to moisture. The contractor must use appropriate means and methods to maintain the stability of the subgrade at all times during construction. 8.4 Fill Material and Compaction Criteria The fill material should be well-graded, have less than 10 percent passing the No. 200 sieve (based on dry weight), and should be free of organics, clay, and other deleterious or compressible materials and should have a maximum particle size of 3 inches. We note that the existing uncontrolled fill material at the site is unlikely suitable for re-use as controlled fill.Soils meeting these requirements may be used as controlled fill material. Any fill material placed in restricted areas where only hand-operated compactors can be used should be placed in maximum lifts of 8 inches thick. We recommend using a 0.5-ton maximum walk-behind roller or other equipment capable of effecting the necessary compaction. The appropriate water content at the time of compaction should be plus or minus 2 percentage points of optimum as determined by the laboratory compaction tests of proposed fill material, performed in accordance with ASTM Standard Specification D1557. No backfill material should be placed on areas where free water is standing or on frozen subsoil areas. Compaction of all fill material should be verified by the Special Inspector using visual inspection and the performance of in-place density tests. 8.5 Construction Documents, Special Inspections, and Quality Assurance Design specifications and drawings should incorporate our findings and recommendations discussed in this report, so that subsurface conditions and other geotechnical issues at the site are adequately addressed in the construction documents. AKRF should assist the design team in preparing specification sections related to geotechnical issues such as subgrade preparation. AKRF should also review foundation design drawings and details, and all contractor submittals and construction procedures related to geotechnical work. AKRF, Inc.Preliminary Geotechnical Engineering Report 900 King Street, Village of Rye Brook,NY Project No. 170073 10 A geotechnical engineer familiar with the site subsurface conditions and design intent should perform the quality assurance observations and testing of geotechnical-related work during construction. Per the requirements of NYSUC, the construction of foundations (foundation subgrade preparation, earthwork,pile driving,etc.) requires Special Inspection by a Professional Engineer currently registered in the State of New York and retained by the Owner. We recommend that AKRF provide the required Special Inspections to verify that the foundation design is implemented during construction and to provide appropriate responses to field questions and changes. 9.0 ADDITIONAL EXPLORATIONS We recommend additional explorations be completed at the site consisting of additional borings and/or test pits to confirm the depth of groundwater in the area of OW-2. 10.0 LIMITATIONS The conclusions and recommendations provided by AKRF in this preliminary report have been prepared based on professional judgment of the subsurface conditions inferred from borings made at the site, as well as plans and/or drawings provided by Perkins Eastman. The recommendations provided herein are solely for the conditions encountered at the site, and should not be used independently at other sites where other subsurface conditions are presumed to exist. In the event that the proposed building is changed, modified, or its location moved, AKRF should be informed to determine whether such modification would change AKRF’s recommendations as presented herein. Geological and groundwater conditions presented herein represent conditions encountered at the time and specific locations where exploration work was performed. In the event that conditions during construction differ from those presented in this report, they should be brought to AKRF’s immediate attention for evaluation, as recommendations in this report may be affected. AKRF has prepared this preliminary geotechnical engineering report for the site for use by the Owner, the Project Architect and Project Structural Engineer in the design process and is only applicable for this specific site and the planned design work. The information in this report should not be relied upon by engineers or contractors involved in other unrelated aspects of design or construction work at the site without first verifying from AKRF whether the information contained herein is applicable for such use. Special Inspections have been recommended as part of the foundation construction. When authorized, AKRF can provide the Owner with the appropriate Special Inspection and quality assurance observations during foundation construction. By providing this service, AKRF will be able to continue its responsibility on this project to verify geotechnical-related foundation construction, and quality assurance follows our recommendations provided in this report. If the Owner opts to retain another entity to perform these services, the other entity will be responsible for final geotechnical design,along with the required Special Inspection, and quality assurance observations. This entity will also serve as the geotechnical engineer of record. Environmental issues (such as potentially contaminated soil and groundwater) are outside the scope of this study and should be addressed in a separate study. AKRF, Inc.Preliminary Geotechnical Engineering Report 900 King Street, Village of Rye Brook,NY Project No. 170073 11 11.0 REFERENCES American Society for Testing and Materials (ASTM). ASTM Standard D422. “Standard Test Method for Particle-Size Analysis of Soils.” West Conshohocken, PA: ASTM International, 2007. ---. ASTM Standard D1557. “Standard Test Methods for Laboratory Compaction Characteristics of Soil Using Modified Effort.” West Conshohocken, PA: ASTM International, 2012. ---. ASTM Standard D1586. “Standard Test Method for Standard Penetration Test (SPT) and Split- Barrel Sampling of Soils.” West Conshohocken, PA: ASTM International, 2011. ---. ASTM Standard D2113. “Standard Practice for Rock Core Drilling and Sampling of Rock for Site Investigation.” West Conshohocken, PA: ASTM International, 2008. ---. ASTM Standard D6032. “Standard Test Method for Determining Rock Quality Designation of Rock Core.” West Conshohocken, PA: ASTM International, 2008. Cadwell, Donald H. “Surficial Geologic Map of New York –Lower Hudson Sheet.” N.Y.S. Geological Survey, 1989. International Code Council. “2015 International Building Code”. Country Club Hills, IL. October 2015. John Meyer Consulting, Inc. (JMC). “900 King Street Redevelopment.”October 26, 2017. New York State Museum and Science Service. “Geologic Map of New York –Lower Hudson Sheet.” 1970. Westchester County Geographic Information System. “Municipal Tax Parcel Viewer.” White Plains, NY: Westchester County. https://giswww.westchestergov.com/taxmaps/default.aspx?sMun=WhitePlains 2015 Building Code of New York State, New York Department of State –Division of Code Enforcement and Administration. "NYS Orthos Online." New York State. October 10, 2017.http://www.orthos.dhses.ny.gov/ FIGURES Source: http://www.orthos.dhses.ny.gov/ Project Site (on Key Map) Approximate Location of Site Environmental, Planning, and Engineering Consultants AKRF Engineering, Inc. 440 Park Avenue South, New York, N.Y. 10016 900 King Street Rye Brook, NY Project Location DATE 170073 Legend Site Location Map 11/8/2017 PROJECT No. 1 FIGURE 900 King Steet Rye Brook, NY 10573 KEY MAP Source:Surficial Geologic Map of New York - Lower Hudson Sheet. © 1989 by NYSGS. -Approximate Location of Site -Till Soils -Bedrock exposed or within about 3 feet of surface -Fluvial sand and gravel Environmental, Planning, and Engineering Consultants AKRF Engineering, Inc. 440 Park Avenue South, New York, N.Y. 10016 Rye Brook, NY 10573 900 King Street Rye Brook, NY Project Location 900 King Steet DATE 11/8/2017 Legend PROJECT No. 2 Surficial Geologic Map 170073 FIGURE Till (t) SITE Source:New York State Museum and Science Service. "Geologic Map of New York." 1970. -Approximate Location of Site -Manhattan Formation -Harrison Gneiss -Hartland Formation Environmental, Planning, and Engineering Consultants AKRF Engineering, Inc. 440 Park Avenue South, New York, N.Y. 10016 PROJECT No. Rye Brook, NY 10573 Legend Project Location 900 King Steet 900 King Street Rye Brook, NY Bedrock Map 170073 FIGURE 3 DATE 11/8/2017 SITE Approximate Location of Site Environmental, Planning, and Engineering Consultants AKRF Engineering, Inc. 440 Park Avenue South, New York, N.Y. 10016 DATE 11/8/2017 Source: Westchester County Geographic Information Systems Project Location 900 King Steet Rye Brook, NY 10573 PROJECT No. 1947 Aerial 170073 FIGURE 4 900 King Street Rye Brook, NY Legend Source: Westchester County Geographic Information Systems Approximate Location of Site Environmental, Planning, and Engineering Consultants AKRF Engineering, Inc. 440 Park Avenue South, New York, N.Y. 10016 1976 Aerial 170073 FIGURE Rye Brook, NY 10573 5 DATE 11/8/2017 PROJECT No. 900 King Steet Project Location 900 King Street Rye Brook, NY Legend Source: Westchester County Geographic Information Systems Approximate Location of Site Environmental, Planning, and Engineering Consultants AKRF Engineering, Inc. 440 Park Avenue South, New York, N.Y. 10016 PROJECT No. 11/8/2017900 King Street Rye Brook, NY Project Location 900 King Steet Rye Brook, NY 10573 1990 Aerial FIGURE DATE Legend 170073 6 Environmental, Planning, and Engineering Consultants 900 King Street Rye Brook, NY APPENDIX A SOIL BORING LOGS AKRF, Inc.Reference Tables for Soil Boring Log Table A-1: Unified Soil Classification System Table A-2: Particle Sizesof Geologic Material Material Size Size Range Passing Sieve Size Retained Sieve Size Boulder Greater than 12 in.–– Cobble 3 in. to 12 in.–– Coarse Gravel ¾ in. to 3 in.3-inch ¾-inch Fine Gravel 19.1 mm (¾ in.) to 4.76 mm ¾-inch No. 4 Coarse Sand 4.75 mm to 2.00 mm No. 4 No. 10 Medium Sand 2.00 mm to 0.425 mm No. 10 No. 40 Fine Sand 0.425 mm to 0.074 mm No. 40 No. 200 Silt 0.074 mm to 0.005 mm Requires Hydrometer AnalysisClayLess than 0.005 mm AKRF, Inc.Reference Tables for Soil Boring Log Table A-3: Quantity Descriptors Descriptor Percentage of Sample (by weight)Examples “CAPITALIZED”> 50%Brown SAND and 35 to 50%and silt some 20 to 35%some gravel little 10 to 20%little clay trace < 10%trace silt APPENDIX B GROUNDWATER OBSERVATION WELL LOGS APPENDIX C GEOTECHNICAL LABORATORY RESULTS Tested By: DB, AB Checked By:VRS SKYLANDS TESTING,LLC Sparta, NJ 10-27-2017 (no specification provided) PL=LL=PI= D90=D85=D60=D50=D30=D15=D10=Cu=Cc= USCS=AASHTO= * Gray silty sand .75.375 #4#10 #20 #40#60 #140#200 100.098.9 97.594.9 88.8 79.369.4 47.741.5 0.9520 0.6237 0.17300.1175 SM Sample washed on #200 sieve AKRF 900 King Street Rye Brook,NY 17-056 Material Description Atterberg Limits Coefficients Classification Remarks Source ofSample: PB-1 Depth:15-17 ft.Sample Number: S-7 Date: Client: Project: Project No:Figure SIEVE PERCENT SPEC.*PASS? SIZE FINER PERCENT (X=NO) PE R C E N T F I N E R 0 10 20 30 40 50 60 70 80 90 100 GRAIN SIZE - mm. 0.0010.010.1110100 % +3"Coarse % Gravel Fine Coarse Medium %Sand Fine Silt % Fines Clay 0.0 0.0 2.5 2.6 15.6 37.8 41.5 6 i n . 3 i n . 2 i n . 1 ½ in . 1 i n . ¾ i n . ½ i n . 3/ 8 i n . #4 #1 0 #2 0 #3 0 #4 0 #6 0 #1 0 0 #1 4 0 #2 0 0 GRAIN SIZE DISTRIBUTION REPORT Tested By: DB, AB Checked By:VRS SKYLANDS TESTING,LLC Sparta, NJ 10-27-2017 (no specification provided) PL=LL=PI= D90=D85=D60=D50=D30=D15=D10=Cu=Cc= USCS=AASHTO= * Gray-orange-brown silty sand .75.375 #4#10 #20 #40#60 #140#200 100.093.1 89.085.3 79.7 71.561.6 43.637.8 5.8318 1.8722 0.23130.1461 SM Sample washed on #200 sieve AKRF 900 King Street Rye Brook,NY 17-056 Material Description Atterberg Limits Coefficients Classification Remarks Source ofSample: PB-2 Depth:6-8 ft.Sample Number: S-4 Date: Client: Project: Project No:Figure SIEVE PERCENT SPEC.*PASS? SIZE FINER PERCENT (X=NO) PE R C E N T F I N E R 0 10 20 30 40 50 60 70 80 90 100 GRAIN SIZE - mm. 0.0010.010.1110100 % +3"Coarse % Gravel Fine Coarse Medium %Sand Fine Silt % Fines Clay 0.0 0.0 11.0 3.7 13.8 33.7 37.8 6 i n . 3 i n . 2 i n . 1 ½ in . 1 i n . ¾ i n . ½ i n . 3/ 8 i n . #4 #1 0 #2 0 #3 0 #4 0 #6 0 #1 0 0 #1 4 0 #2 0 0 GRAIN SIZE DISTRIBUTION REPORT Tested By: DB, AB Checked By:VRS SKYLANDS TESTING,LLC Sparta, NJ 10-27-2017 (no specification provided) PL=LL=PI= D90=D85=D60=D50=D30=D15=D10=Cu=Cc= USCS=AASHTO= * Gray-orange-brown silty sand .375#4 #10#20 #40 #60#140 #200 100.099.4 96.890.9 80.7 69.049.0 41.7 0.7820 0.5422 0.17160.1112 SM Sample washed on #200 sieve AKRF 900 King Street Rye Brook,NY 17-056 Material Description Atterberg Limits Coefficients Classification Remarks Source ofSample: PB-3 Depth:4-6 ft.Sample Number: S-3 Date: Client: Project: Project No:Figure SIEVE PERCENT SPEC.*PASS? SIZE FINER PERCENT (X=NO) PE R C E N T F I N E R 0 10 20 30 40 50 60 70 80 90 100 GRAIN SIZE - mm. 0.0010.010.1110100 % +3"Coarse % Gravel Fine Coarse Medium %Sand Fine Silt % Fines Clay 0.0 0.0 0.6 2.6 16.1 39.0 41.7 6 i n . 3 i n . 2 i n . 1 ½ in . 1 i n . ¾ i n . ½ i n . 3/ 8 i n . #4 #1 0 #2 0 #3 0 #4 0 #6 0 #1 0 0 #1 4 0 #2 0 0 GRAIN SIZE DISTRIBUTION REPORT Tested By: DB, AB Checked By:VRS SKYLANDS TESTING,LLC Sparta, NJ 10-27-2017 (no specification provided) PL=LL=PI= D90=D85=D60=D50=D30=D15=D10=Cu=Cc= USCS=AASHTO= * Gray silty sand .75.375 #4#10 #20 #40#60 #140#200 100.098.7 96.692.5 85.9 77.569.2 44.938.3 1.3689 0.7848 0.17840.1285 SM Sample washed on #200 sieve AKRF 900 King Street Rye Brook,NY 17-056 Material Description Atterberg Limits Coefficients Classification Remarks Source ofSample: PB-3 Depth:15-17 ft.Sample Number: S-7 Date: Client: Project: Project No:Figure SIEVE PERCENT SPEC.*PASS? SIZE FINER PERCENT (X=NO) PE R C E N T F I N E R 0 10 20 30 40 50 60 70 80 90 100 GRAIN SIZE - mm. 0.0010.010.1110100 % +3"Coarse % Gravel Fine Coarse Medium %Sand Fine Silt % Fines Clay 0.0 0.0 3.4 4.1 15.0 39.2 38.3 6 i n . 3 i n . 2 i n . 1 ½ in . 1 i n . ¾ i n . ½ i n . 3/ 8 i n . #4 #1 0 #2 0 #3 0 #4 0 #6 0 #1 0 0 #1 4 0 #2 0 0 GRAIN SIZE DISTRIBUTION REPORT Tested By: DB, AB Checked By:VRS SKYLANDS TESTING,LLC Sparta, NJ 10-27-2017 (no specification provided) PL=LL=PI= D90=D85=D60=D50=D30=D15=D10=Cu=Cc= USCS=AASHTO= * Gray and white silty sand .75.375 #4#10 #20 #40#60 #140#200 100.089.9 88.184.0 78.0 69.559.4 41.535.4 9.6867 2.3667 0.25730.1614 SM Sample washed on #200 sieve AKRF 900 King Street Rye Brook,NY 17-056 Material Description Atterberg Limits Coefficients Classification Remarks Source ofSample: PB-4 Depth:3-5 ft.Sample Number: S-2 Date: Client: Project: Project No:Figure SIEVE PERCENT SPEC.*PASS? SIZE FINER PERCENT (X=NO) PE R C E N T F I N E R 0 10 20 30 40 50 60 70 80 90 100 GRAIN SIZE - mm. 0.0010.010.1110100 % +3"Coarse % Gravel Fine Coarse Medium %Sand Fine Silt % Fines Clay 0.0 0.0 11.9 4.1 14.5 34.1 35.4 6 i n . 3 i n . 2 i n . 1 ½ in . 1 i n . ¾ i n . ½ i n . 3/ 8 i n . #4 #1 0 #2 0 #3 0 #4 0 #6 0 #1 0 0 #1 4 0 #2 0 0 GRAIN SIZE DISTRIBUTION REPORT Tested By: DB, AB Checked By:VRS SKYLANDS TESTING,LLC Sparta, NJ 10-27-2017 (no specification provided) PL=LL=PI= D90=D85=D60=D50=D30=D15=D10=Cu=Cc= USCS=AASHTO= * Gray and black silty sand with gravel 1.75 .375#4 #10 #20#40 #60#140 #200 100.077.2 71.266.8 58.4 46.635.4 27.819.5 16.9 22.6951 21.3531 2.32681.0558 0.2957 SM Sample washed on #200 sieve AKRF 900 King Street Rye Brook,NY 17-056 Material Description Atterberg Limits Coefficients Classification Remarks Source ofSample: PB-5 Depth:7-9 ft.Sample Number: S-4 Date: Client: Project: Project No:Figure SIEVE PERCENT SPEC.*PASS? SIZE FINER PERCENT (X=NO) PE R C E N T F I N E R 0 10 20 30 40 50 60 70 80 90 100 GRAIN SIZE - mm. 0.0010.010.1110100 % +3"Coarse % Gravel Fine Coarse Medium %Sand Fine Silt % Fines Clay 0.0 22.8 10.4 8.4 23.0 18.5 16.9 6 i n . 3 i n . 2 i n . 1 ½ in . 1 i n . ¾ i n . ½ i n . 3/ 8 i n . #4 #1 0 #2 0 #3 0 #4 0 #6 0 #1 0 0 #1 4 0 #2 0 0 GRAIN SIZE DISTRIBUTION REPORT Tested By: DB, AB Checked By:VRS SKYLANDS TESTING,LLC Sparta, NJ 10-27-2017 (no specification provided) PL=LL=PI= D90=D85=D60=D50=D30=D15=D10=Cu=Cc= USCS=AASHTO= * Gray-orange-brown silty sand .75.375 #4#10 #20 #40#60 #140#200 100.094.5 89.283.3 76.2 68.762.5 45.841.1 5.3069 2.5557 0.21650.1327 SM Sample washed on #200 sieve AKRF 900 King Street Rye Brook,NY 17-056 Material Description Atterberg Limits Coefficients Classification Remarks Source ofSample: PB-6 Depth:4-6 ft.Sample Number: S-3 Date: Client: Project: Project No:Figure SIEVE PERCENT SPEC.*PASS? SIZE FINER PERCENT (X=NO) PE R C E N T F I N E R 0 10 20 30 40 50 60 70 80 90 100 GRAIN SIZE - mm. 0.0010.010.1110100 % +3"Coarse % Gravel Fine Coarse Medium %Sand Fine Silt % Fines Clay 0.0 0.0 10.8 5.9 14.6 27.6 41.1 6 i n . 3 i n . 2 i n . 1 ½ in . 1 i n . ¾ i n . ½ i n . 3/ 8 i n . #4 #1 0 #2 0 #3 0 #4 0 #6 0 #1 0 0 #1 4 0 #2 0 0 GRAIN SIZE DISTRIBUTION REPORT Tested By: DB, AB Checked By:VRS SKYLANDS TESTING,LLC Sparta, NJ 10-27-2017 (no specification provided) PL=LL=PI= D90=D85=D60=D50=D30=D15=D10=Cu=Cc= USCS=AASHTO= * Gray-orange-brown silty sand .75.375 #4#10 #20 #40#60 #140#200 100.095.3 92.887.2 78.0 66.352.9 32.927.3 2.8738 1.5751 0.32770.2242 0.0892 SM Sample washed on #200 sieve AKRF 900 King Street Rye Brook,NY 17-056 Material Description Atterberg Limits Coefficients Classification Remarks Source ofSample: PB-6 Depth:20-22 FT.Sample Number: S-8 Date: Client: Project: Project No:Figure SIEVE PERCENT SPEC.*PASS? SIZE FINER PERCENT (X=NO) PE R C E N T F I N E R 0 10 20 30 40 50 60 70 80 90 100 GRAIN SIZE - mm. 0.0010.010.1110100 % +3"Coarse % Gravel Fine Coarse Medium %Sand Fine Silt % Fines Clay 0.0 0.0 7.2 5.6 20.9 39.0 27.3 6 i n . 3 i n . 2 i n . 1 ½ in . 1 i n . ¾ i n . ½ i n . 3/ 8 i n . #4 #1 0 #2 0 #3 0 #4 0 #6 0 #1 0 0 #1 4 0 #2 0 0 GRAIN SIZE DISTRIBUTION REPORT Tested By: DB, AB Checked By:VRS SKYLANDS TESTING,LLC Sparta, NJ 10-27-2017 (no specification provided) PL=LL=PI= D90=D85=D60=D50=D30=D15=D10=Cu=Cc= USCS=AASHTO= * Gray-orange-brown silty sand with gravel .75.375 #4#10 #20 #40#60 #140#200 100.081.6 72.061.5 51.0 39.429.1 16.212.9 13.5003 11.1202 1.75660.7941 0.2629 0.0938 SM Sample washed on #200 sieve AKRF 900 King Street Rye Brook,NY 17-056 Material Description Atterberg Limits Coefficients Classification Remarks Source ofSample: PB-8 Depth:3-5 ft.Sample Number: S-2 Date: Client: Project: Project No:Figure SIEVE PERCENT SPEC.*PASS? SIZE FINER PERCENT (X=NO) PE R C E N T F I N E R 0 10 20 30 40 50 60 70 80 90 100 GRAIN SIZE - mm. 0.0010.010.1110100 % +3"Coarse % Gravel Fine Coarse Medium %Sand Fine Silt % Fines Clay 0.0 0.0 28.0 10.5 22.1 26.5 12.9 6 i n . 3 i n . 2 i n . 1 ½ in . 1 i n . ¾ i n . ½ i n . 3/ 8 i n . #4 #1 0 #2 0 #3 0 #4 0 #6 0 #1 0 0 #1 4 0 #2 0 0 GRAIN SIZE DISTRIBUTION REPORT Tested By: DB, AB Checked By:VRS SKYLANDS TESTING,LLC Sparta, NJ 10-27-2017 (no specification provided) PL=LL=PI= D90=D85=D60=D50=D30=D15=D10=Cu=Cc= USCS=AASHTO= * Gray-orange-brown and black silty sand with gravel .75.375 #4#10 #20 #40#60 #140#200 100.088.2 83.979.4 72.6 63.255.3 38.233.7 10.9665 6.2250 0.33690.1914 SM Sample washed on #200 sieve AKRF 900 King Street Rye Brook,NY 17-056 Material Description Atterberg Limits Coefficients Classification Remarks Source ofSample: PB-9 Depth:7-9 ft.Sample Number: S-4 Date: Client: Project: Project No:Figure SIEVE PERCENT SPEC.*PASS? SIZE FINER PERCENT (X=NO) PE R C E N T F I N E R 0 10 20 30 40 50 60 70 80 90 100 GRAIN SIZE - mm. 0.0010.010.1110100 % +3"Coarse % Gravel Fine Coarse Medium %Sand Fine Silt % Fines Clay 0.0 0.0 16.1 4.5 16.2 29.5 33.7 6 i n . 3 i n . 2 i n . 1 ½ in . 1 i n . ¾ i n . ½ i n . 3/ 8 i n . #4 #1 0 #2 0 #3 0 #4 0 #6 0 #1 0 0 #1 4 0 #2 0 0 GRAIN SIZE DISTRIBUTION REPORT Tested By: DB, AB Checked By:VRS SKYLANDS TESTING,LLC Sparta, NJ 10-27-2017 (no specification provided) PL=LL=PI= D90=D85=D60=D50=D30=D15=D10=Cu=Cc= USCS=AASHTO= * Gray-brown silty sand .75.375 #4#10 #20 #40#60 #140#200 100.091.7 88.582.7 74.8 65.857.3 44.240.0 7.0395 2.6746 0.29390.1588 SM Sample washed on #200 sieve AKRF 900 King Street Rye Brook,NY 17-056 Material Description Atterberg Limits Coefficients Classification Remarks Source ofSample: PB-10 Depth:1-3 ft.Sample Number: S-1 Date: Client: Project: Project No:Figure SIEVE PERCENT SPEC.*PASS? SIZE FINER PERCENT (X=NO) PE R C E N T F I N E R 0 10 20 30 40 50 60 70 80 90 100 GRAIN SIZE - mm. 0.0010.010.1110100 % +3"Coarse % Gravel Fine Coarse Medium %Sand Fine Silt % Fines Clay 0.0 0.0 11.5 5.8 16.9 25.8 40.0 6 i n . 3 i n . 2 i n . 1 ½ in . 1 i n . ¾ i n . ½ i n . 3/ 8 i n . #4 #1 0 #2 0 #3 0 #4 0 #6 0 #1 0 0 #1 4 0 #2 0 0 GRAIN SIZE DISTRIBUTION REPORT Tested By: DB, AB Checked By:VRS SKYLANDS TESTING,LLC Sparta, NJ 10-27-2017 (no specification provided) PL=LL=PI= D90=D85=D60=D50=D30=D15=D10=Cu=Cc= USCS=AASHTO= * Gray-orange-brown sandy silt .75.375 #4#10 #20 #40#60 #140#200 100.098.3 95.691.1 84.9 77.669.7 56.251.0 1.6758 0.8642 0.1359 ML Sample washed on #200 sieve AKRF 900 King Street Rye Brook,NY 17-056 Material Description Atterberg Limits Coefficients Classification Remarks Source ofSample: PB-10 Depth:5-7 ft.Sample Number: S-3 Date: Client: Project: Project No:Figure SIEVE PERCENT SPEC.*PASS? SIZE FINER PERCENT (X=NO) PE R C E N T F I N E R 0 10 20 30 40 50 60 70 80 90 100 GRAIN SIZE - mm. 0.0010.010.1110100 % +3"Coarse % Gravel Fine Coarse Medium %Sand Fine Silt % Fines Clay 0.0 0.0 4.4 4.5 13.5 26.6 51.0 6 i n . 3 i n . 2 i n . 1 ½ in . 1 i n . ¾ i n . ½ i n . 3/ 8 i n . #4 #1 0 #2 0 #3 0 #4 0 #6 0 #1 0 0 #1 4 0 #2 0 0 GRAIN SIZE DISTRIBUTION REPORT Tested By: DB, AB Checked By:VRS SKYLANDS TESTING,LLC Sparta, NJ 10-27-2017 (no specification provided) PL=LL=PI= D90=D85=D60=D50=D30=D15=D10=Cu=Cc= USCS=AASHTO= * Orange-brown and black silty sand 1.75 .375#4 #10 #20#40 #60#140 #200 100.094.4 89.385.6 80.2 71.961.7 51.234.0 30.1 11.4231 4.3158 0.38630.2368 SM Sample washed on #200 sieve AKRF 900 King Street Rye Brook,NY 17-056 Material Description Atterberg Limits Coefficients Classification Remarks Source ofSample: PB-11 Depth:2-4 ft.Sample Number: S-2 Date: Client: Project: Project No:Figure SIEVE PERCENT SPEC.*PASS? SIZE FINER PERCENT (X=NO) PE R C E N T F I N E R 0 10 20 30 40 50 60 70 80 90 100 GRAIN SIZE - mm. 0.0010.010.1110100 % +3"Coarse % Gravel Fine Coarse Medium %Sand Fine Silt % Fines Clay 0.0 5.6 8.8 5.4 18.5 31.6 30.1 6 i n . 3 i n . 2 i n . 1 ½ in . 1 i n . ¾ i n . ½ i n . 3/ 8 i n . #4 #1 0 #2 0 #3 0 #4 0 #6 0 #1 0 0 #1 4 0 #2 0 0 GRAIN SIZE DISTRIBUTION REPORT Tested By: DB, AB Checked By:VRS SKYLANDS TESTING,LLC Sparta, NJ 10-27-2017 (no specification provided) PL=LL=PI= D90=D85=D60=D50=D30=D15=D10=Cu=Cc= USCS=AASHTO= * Brown silty sand .75.375 #4#10 #20 #40#60 #140#200 100.094.2 87.676.4 62.0 47.836.8 22.618.5 6.0011 3.7765 0.76780.4707 0.1728 SM Sample washed on #200 sieve AKRF 900 King Street Rye Brook,NY 17-056 Material Description Atterberg Limits Coefficients Classification Remarks Source ofSample: PB-12 Depth:7-9 ft.Sample Number: S-4 Date: Client: Project: Project No:Figure SIEVE PERCENT SPEC.*PASS? SIZE FINER PERCENT (X=NO) PE R C E N T F I N E R 0 10 20 30 40 50 60 70 80 90 100 GRAIN SIZE - mm. 0.0010.010.1110100 % +3"Coarse % Gravel Fine Coarse Medium %Sand Fine Silt % Fines Clay 0.0 0.0 12.4 11.2 28.6 29.3 18.5 6 i n . 3 i n . 2 i n . 1 ½ in . 1 i n . ¾ i n . ½ i n . 3/ 8 i n . #4 #1 0 #2 0 #3 0 #4 0 #6 0 #1 0 0 #1 4 0 #2 0 0 GRAIN SIZE DISTRIBUTION REPORT Tested By: DB, AB Checked By:VRS SKYLANDS TESTING,LLC Sparta, NJ 10-27-2017 (no specification provided) PL=LL=PI= D90=D85=D60=D50=D30=D15=D10=Cu=Cc= USCS=AASHTO= * Brown silty sand .75.375 #4#10 #20 #40#60 #140#200 100.097.1 91.674.1 54.8 37.426.2 15.112.6 4.2689 3.2618 1.06120.7013 0.3047 0.1048 SM Sample washed on #200 sieve AKRF 900 King Street Rye Brook,NY 17-056 Material Description Atterberg Limits Coefficients Classification Remarks Source ofSample: PB-12 Depth:9-11 ft.Sample Number: S-5 Date: Client: Project: Project No:Figure SIEVE PERCENT SPEC.*PASS? SIZE FINER PERCENT (X=NO) PE R C E N T F I N E R 0 10 20 30 40 50 60 70 80 90 100 GRAIN SIZE - mm. 0.0010.010.1110100 % +3"Coarse % Gravel Fine Coarse Medium %Sand Fine Silt % Fines Clay 0.0 0.0 8.4 17.5 36.7 24.8 12.6 6 i n . 3 i n . 2 i n . 1 ½ in . 1 i n . ¾ i n . ½ i n . 3/ 8 i n . #4 #1 0 #2 0 #3 0 #4 0 #6 0 #1 0 0 #1 4 0 #2 0 0 GRAIN SIZE DISTRIBUTION REPORT Tested By: DB, AB Checked By:VRS SKYLANDS TESTING,LLC Sparta, NJ 10-27-2017 (no specification provided) PL=LL=PI= D90=D85=D60=D50=D30=D15=D10=Cu=Cc= USCS=AASHTO= * Gray-brown silty sand with gravel .75.375 #4#10 #20 #40#60 #140#200 100.087.3 83.774.9 60.5 48.038.4 25.221.5 11.5678 6.7804 0.82450.4754 0.1504 SM Sample washed on #200 sieve AKRF 900 King Street Rye Brook,NY 17-056 Material Description Atterberg Limits Coefficients Classification Remarks Source ofSample: PB-13 Depth:7-9 ft.Sample Number: S-4 Date: Client: Project: Project No:Figure SIEVE PERCENT SPEC.*PASS? SIZE FINER PERCENT (X=NO) PE R C E N T F I N E R 0 10 20 30 40 50 60 70 80 90 100 GRAIN SIZE - mm. 0.0010.010.1110100 % +3"Coarse % Gravel Fine Coarse Medium %Sand Fine Silt % Fines Clay 0.0 0.0 16.3 8.8 26.9 26.5 21.5 6 i n . 3 i n . 2 i n . 1 ½ in . 1 i n . ¾ i n . ½ i n . 3/ 8 i n . #4 #1 0 #2 0 #3 0 #4 0 #6 0 #1 0 0 #1 4 0 #2 0 0 GRAIN SIZE DISTRIBUTION REPORT Tested By: DB, AB Checked By:VRS SKYLANDS TESTING,LLC Sparta, NJ 10-27-2017 (no specification provided) PL=LL=PI= D90=D85=D60=D50=D30=D15=D10=Cu=Cc= USCS=AASHTO= * Dark brown poorly graded sand with silt .375#4 #10#20 #40 #60#140 #200 100.097.6 84.665.4 44.1 29.614.7 11.3 2.6889 2.0417 0.70690.5140 0.2539 0.1091 SP-SM Sample washed on #200 sieve AKRF 900 King Street Rye Brook,NY 17-056 Material Description Atterberg Limits Coefficients Classification Remarks Source ofSample: PB-13 Depth:9-11 ft.Sample Number: S-5 Date: Client: Project: Project No:Figure SIEVE PERCENT SPEC.*PASS? SIZE FINER PERCENT (X=NO) PE R C E N T F I N E R 0 10 20 30 40 50 60 70 80 90 100 GRAIN SIZE - mm. 0.0010.010.1110100 % +3"Coarse % Gravel Fine Coarse Medium %Sand Fine Silt % Fines Clay 0.0 0.0 2.4 13.0 40.5 32.8 11.3 6 i n . 3 i n . 2 i n . 1 ½ in . 1 i n . ¾ i n . ½ i n . 3/ 8 i n . #4 #1 0 #2 0 #3 0 #4 0 #6 0 #1 0 0 #1 4 0 #2 0 0 GRAIN SIZE DISTRIBUTION REPORT APPENDIX I SWPPP INSPECTORS & SWPPP PREPARERS CERTIFICATION SWPPP Preparer Certification Form SPDES General Permit for Stormwater Discharges From Construction Activity (GP-0-15-002) Project Site Information Project/Site Name Owner/Operator Information Owner/Operator (Company Name/Private Owner/Municipality Name) Certification Statement SWPPP Preparer I hereby certify that the Stormwater Pollution Prevention Plan (SWPPP)for this project has been prepared in accordance with the terms and conditions of the GP-0-1 -00 .Furthermore, I understand that certifying false, incorrect or inaccurate information is a violation of this permit and the laws of the State of New York and could subject me to criminal, civil and/or administrative proceedings. First name MI Last Name Signature Date Revised: April 2015 P:\2016\16222\Report\2018-03-08_RB\SWPPP PREP-CERT.pdf 900 in S r D m n 900 in S r O n r, LLC. APPENDIX J CONTRACTOR S AND OWNER S CERTIFICATION JMC Project 16222 900 King Street Development 900 King Street Rye Brook, NY CONTRACTOR'S CERTIFICATION I hereby certify that I understand and agree to comply with the terms and conditions of the SWPPP and agree to implement any corrective actions identified by the qualified inspector during a site inspection. I also understand that the owner or operator must comply with the terms and conditions of the most current version of the New York State Pollutant Discharge Elimination System (SPDES ) general permit for stormwater discharges from construction activities and that it is unlawful for any person to cause or contribute to a violation of water quality standards. Furthermore, I am aware there are significant penalties for submitting false information that I do not believe to be true, including the possibility of time and imprisonment for knowing violations. Company Name: Address: Telephone Number: Name and Title: Signature: Date: Permit Identification No.: Name and Title of Trained Contractor: Elements of the SWPPP Contractor is responsible for: p:\2016\16222\drainage\report\nys contractors certification.docx Owner/Operator Certification Form SPDES General Permit For Stormwater Discharges From Construction Activity (GP-0-1 -00 ) Project/Site Name:________________________________________________________ eNOI Submission Number:_________________________________________________ eNOI Submitted by:Owner/Operator SWPPP Preparer Other Certification Statement - Owner/Operator I have read or been advised of the permit conditions and believe that I understand them. I also understand that, under the terms of the permit, there may be reporting requirements. I hereby certify that this document and the corresponding documents were prepared under my direction or supervision. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. I further understand that coverage under the general permit will be identified in the acknowledgment that I will receive as a result of submitting this NOI and can be as long as sixty (60) business days as provided for in the general permit. I also understand that, by submitting this NOI, I am acknowledging that the SWPPP has been developed and will be implemented as the first element of construction, and agreeing to comply with all the terms and conditions of the general permit for which this NOI is being submitted. Owner/Operator First Name M.I. Last Name ___________________________________________________________ Signature ________________________________ Date 900 King Street Owner, LLC. ???-????-???? X P:\2016\16222\2018-03-08_RB\Owner-Oper Certification Form.pdf APPENDIX K HYDRAULIC CALCULATIONS From (Inlet) To (Outlet) Length Inlet Outlet Average Pipe Pipe Manning's Peak Max Design MaxFlow/ Node Node Invert Invert Slope Diameter Width Roughness Flow Flow Flow Design Flow Elevation Elevation orHeight Velocity Capacity Ratio (ft) (ft) (ft) (%) (inches) (inches) (cfs) (ft/sec) (cfs) DMH 4 1 Infil 1A 3 South 5.00 239.70 239.60 2.0000 24.000 24.00 0.0120 30.75 10.44 34.66 0.89 DMH 1 10 Infil 1A 3 North 5.00 241.70 241.60 2.0000 24.000 24.00 0.0120 12.77 6.11 34.66 0.37 CI 2 2 1 CI 2 2 38.00 245.50 245.00 1.3200 18.000 18.00 0.0120 1.23 4.17 13.05 0.09 DMH 1 14 CI 1 13 83.00 250.75 247.75 3.6100 18.000 18.00 0.0120 1.77 5.67 21.63 0.08 CI 1 13 CI 1 12 26.00 247.75 246.75 3.8500 18.000 18.00 0.0120 2.23 6.78 22.32 0.10 CI 4 3 1 CI 4 3 25.00 243.75 243.50 1.0000 18.000 18.00 0.0120 1.95 2.16 11.38 0.17 DI 2 7 2 DMH 2 7 156.89 246.75 245.00 1.1200 24.000 24.00 0.0120 2.73 5.09 25.88 0.11 CI 2 4 DMH 2 3 179.58 236.35 235.15 0.6700 30.000 30.00 0.0120 22.68 5.66 36.32 0.62 DMH 2 3 CI 2 2 84.23 235.15 234.60 0.6500 30.000 30.00 0.0120 22.59 5.58 35.91 0.63 CI 2 2 ES 2 1 66.70 234.60 234.00 0.9000 30.000 30.00 0.0120 24.24 7.38 42.15 0.58 CI 2 6 DMH 2 5 112.29 237.75 237.00 0.6700 24.000 24.00 0.0120 17.83 5.68 20.03 0.89 DMH 2 5 CI 2 4 96.11 237.00 236.35 0.6800 24.000 24.00 0.0120 17.76 5.76 20.15 0.88 CI 1 6 CI 1 5 109.39 236.55 235.15 1.2800 24.000 24.00 0.0120 15.94 6.94 27.73 0.57 CI 1 4 DMH 1 3 79.96 234.50 234.30 0.2500 30.000 30.00 0.0120 20.71 4.22 22.22 0.93 CI 3 5 CI 3 4 43.58 238.00 237.50 1.1500 18.000 18.00 0.0130 2.67 4.37 11.25 0.24 LI 1 15 DMH 1 14 62.51 251.50 250.75 1.2000 18.000 18.00 0.0120 1.77 5.26 12.47 0.14 CI 3 2 CI 3 1 35.94 234.85 234.65 0.5600 18.000 18.00 0.0130 4.11 3.15 7.84 0.53 CI 3 1 CI 1 4 72.27 234.65 234.50 0.2100 24.000 24.00 0.0130 5.27 2.93 10.31 0.51 CI 2 4 3 CI 2 4 1 76.27 248.50 247.70 1.0500 18.000 18.00 0.0120 4.45 4.68 11.65 0.38 LI 2 7 1 DMH 2 7 33.27 249.75 249.00 2.2500 15.000 15.00 0.0120 5.85 7.06 10.51 0.56 DMH 1 11 DMH 1 10 69.38 242.00 241.70 0.4300 24.000 24.00 0.0120 5.98 2.98 16.12 0.37 DMH 1 2 ES 1 1 47.87 234.15 234.00 0.3100 30.000 30.00 0.0120 23.17 5.61 24.87 0.93 DMH 1 3 DMH 1 2 16.89 234.30 234.15 0.8900 30.000 30.00 0.0120 23.18 4.79 41.88 0.55 CI 2 4 1 CI 2 4 65.30 247.70 247.00 1.0700 18.000 18.00 0.0120 4.92 5.60 11.78 0.42 CI 2 8 DMH 2 7 49.98 238.80 238.45 0.7000 24.000 24.00 0.0120 6.90 3.11 20.51 0.34 CI 1 8 1 CI 1 8 26.08 238.70 238.45 0.9600 15.000 15.00 0.0120 2.98 2.84 6.85 0.44 CI 1 5 CI 1 4 42.27 235.15 234.65 1.1800 24.000 24.00 0.0120 17.35 5.86 26.65 0.65 CI 1 7 CI 1 6 89.96 237.70 236.55 1.2800 24.000 24.00 0.0120 12.93 6.91 27.71 0.47 TD 2 10 2 DMH 2 10 1 35.99 240.50 240.20 0.8300 18.000 18.00 0.0120 1.20 2.88 10.39 0.12 DMH 2 10 1 DMH 2 10 62.48 240.20 239.75 0.7200 18.000 18.00 0.0120 1.33 1.33 9.66 0.14 DMH 2 10 CI 2 9 37.70 239.75 239.55 0.5300 18.000 18.00 0.0120 6.89 4.52 8.29 0.83 CI 2 9 CI 2 8 114.92 239.55 238.80 0.6500 24.000 24.00 0.0120 7.74 3.86 19.80 0.39 LI 2 11 DMH 2 10 72.25 242.00 240.75 1.7300 18.000 18.00 0.0120 6.11 7.04 14.97 0.41 CI 1 11 1 DMH 1 11 36.70 252.00 251.00 2.7200 18.000 18.00 0.0120 1.00 5.15 18.78 0.05 CI 2 9 2 CI 2 9 1 25.54 250.00 249.50 1.9600 15.000 15.00 0.0120 1.30 4.77 9.79 0.13 CI 1 12 DMH 1 11 42.18 246.25 245.00 2.9600 18.000 18.00 0.0120 2.20 6.48 19.59 0.11 LI 2 8 1 CI 2 8 67.67 246.25 244.90 1.9900 15.000 15.00 0.0120 0.81 4.62 9.88 0.08 DMH 1 16 LI 1 15 34.21 255.75 252.50 9.5000 15.000 15.00 0.0120 0.32 6.09 21.57 0.01 CI 1 3 1 DMH 1 3 26.82 240.30 239.20 4.1000 24.000 24.00 0.0120 3.13 7.30 49.63 0.06 CI 4 4 CI 4 3 125.99 248.00 243.50 3.5700 18.000 18.00 0.0120 2.29 3.29 21.51 0.11 LI 3 6 1 DMH 3 6 109.68 247.00 242.00 4.5600 15.000 15.00 0.0120 0.76 6.22 14.94 0.05 LI 3 8 DMH 3 7 54.42 247.00 246.25 1.3800 15.000 15.00 0.0120 1.23 4.43 8.22 0.15 DMH 3 7 DMH 3 6 111.22 244.25 242.00 2.0200 15.000 15.00 0.0120 1.21 5.25 9.95 0.12 CI 1 12 1 CI 1 12 43.48 246.50 246.25 0.5800 15.000 15.00 0.0120 0.50 1.97 5.31 0.09 DMH 3 6 CI 3 5 60.33 240.00 238.00 3.3200 18.000 18.00 0.0120 1.60 3.79 20.72 0.08 CI 4 3 CI 4 2 21.73 243.50 243.00 2.3000 18.000 18.00 0.0120 6.33 6.86 17.26 0.37 CI 4 2 DMH 4 1 29.35 240.00 239.70 1.0200 24.000 24.00 0.0120 19.81 6.46 24.78 0.80 OCS 1 9 CI 1 8 87.28 239.60 238.45 1.3200 18.000 18.00 0.0120 11.09 7.64 13.06 0.85 CI 2 9 1 CI 2 9 18.18 246.50 246.00 2.7500 18.000 18.00 0.0120 1.30 5.10 18.87 0.07 CI 1 11 2 CI 1 11 1 24.37 253.00 252.00 4.1000 18.000 18.00 0.0120 0.56 3.56 23.05 0.02 CI 4 2 1 CI 4 2 28.64 243.00 242.50 1.7500 18.000 18.00 0.0120 2.43 3.10 15.03 0.16 CI 1 8 CI 1 7 58.64 238.45 237.70 1.2800 18.000 18.00 0.0120 10.05 6.83 12.87 0.78 CI 3 4 DMH 3 3 109.24 237.50 236.40 1.0100 18.000 18.00 0.0120 3.39 4.67 11.42 0.30 DMH 3 3 CI 3 2 160.28 236.40 234.85 0.9700 18.000 18.00 0.0120 3.76 2.60 11.19 0.34 DMH 2 7 CI 2 6 102.88 238.45 237.75 0.6800 24.000 24.00 0.0120 14.20 4.76 20.22 0.70 25YearStorm Event Proposed Drainage Analysis